Development of Materials Science for Polymer Ionics based on Ionic Liquids as Key Materials

2008 Fiscal Year Final Research Report

• Project/Area Number: 17205020
• Research Category: Grant-in-Aid for Scientific Research (A)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Polymer/Textile materials
• Research Institution: Tokyo University of Agriculture and Technology
• Principal Investigator: HIROYUKI Ohno Tokyo University of Agriculture and Technology, 大学院・共生科学技術研究院, 教授 (00176968)
• Co-Investigator(Kenkyū-buntansha): NAKAMURA Nobuhumi 東京農工大学, 大学院・共生科学技術研究院, 准教授 (60313293) ; MATSUMI Noriyoshi 東京農工大学, 大学院・共生科学技術研究院, 助手 (40323745) ; MIZUMO Tomonobu 東京農工大学, 大学院・共生科学技術研究院, 助教 (90436676)
• Project Period (FY): 2005 – 2008
• Keywords: イオン液体 / 固体電解質 / イオン伝導 / 機能液体 / フィルム

Research Abstract

様々な構造のイオン液体を合成し、イオン構造と特性の相関を解析し、これを高分子化、あるいはコンポジット化して固体フィルムとし、目的イオンを伝導できる新規イオン伝導性高分子フィルムを作製した。また、タンパク質などを高分子中に埋め込み、耐熱性を賦与し、しかも変性を抑止するのに必要な高分子の要件を整理し、生物固相電気化学の基礎知見を集積した。これらの知見を併せ、高分子イオニクスの新展開に重要な材料を提案した。

Research Products

• [Journal Article] Immobilization of heptyl viologens in DNA strands both to inhibit dimerization and to accelerate quasi-reversible electron transfer reaction (2008)
  • Author(s): T. Kakibe and H. Ohno
  • Journal Title: Chem. Commun. Pages: 377-379
• [Journal Article] Thermally stable polymer gel electrolytes composed of branched polyimide and ionic liquid/zwitterion mixture prepared by in situ polycondensation (2008)
  • Author(s): M. Tamada, S. Ueda, T. Hayashi, and H. Ohno
  • Journal Title: Chem. Lett. 37 Pages: 86-87
• [Journal Article] Preparation of ion conductive inorganic-organic composite systems by in-situ sol-gel reaction of polymerizable ionic liquids (2008)
  • Author(s): T. Mizumo, T. Watanabe, N. Matsumi, and H. Ohno
  • Journal Title: Polym. Adv. Technol. 19 Pages: 1445-1450
• [Journal Article] Improved solubilization of pyromellitic dianhydride and 4,4'-oxydianiline in ionic liquid by the addition of zwitterion and their polycondensation (2007)
  • Author(s): M. Tamada, T. Hayashi, and H. Ohno
  • Journal Title: Tetrahedron Letters 48 Pages: 1553-1557
• [Journal Article] LCST type phase control of ionic liquid/water systems (2007)
  • Author(s): K. Fukumoto and H. Ohno
  • Journal Title: Angew. Chem. Int. Ed. 46 Pages: 1852-1855
• [Journal Article] Improved ionic conductivity of nitrile rubber/LiN(SO_2CF_3)_2 composite by adding imidazolium-type zwitterion (2007)
  • Author(s): E. Marwanta, T. Mizumo, and H. Ohno
  • Journal Title: Solid State Ionics 178 Pages: 227-232
• [Journal Article] Solubility and stability of cytochrome c in hydrated ionic liquids: Effect of oxo acid residues and kosmotropicity (2007)
  • Author(s): MacFarlane, M. Forsyth, M. Yoshizawa-Fujita, K. Murata, N. Nakamura, and H. Ohno
  • Journal Title: Biomacro- molecules 8 Pages: 2080-2086
• [Journal Article] Control of ionic conductivity of ionic liquid/photoresponsible poly(amide acid)gels by photoirradiation (2007)
  • Author(s): M. Tamada, T. Watanabe, K. Horie, and H. Ohno
  • Journal Title: Chem. Commun. Pages: 4050-4052
• [Journal Article] Amino acid ionic liquids (2007)
  • Author(s): H. Ohno and K. Fukumoto
  • Journal Title: Accounts of Chemical Research 40 Pages: 1122-1129
• [Journal Article] Effect of cation structure on the electrochemical and thermal properties of ion conductive polymers obtained from polymerizable ionic liquids (2006)
  • Author(s): W. Ogihara, S. Washiro, H.Nakajima, and H. Ohno
  • Journal Title: Electrochim. Acta 51 Pages: 2614-2619
• [Journal Article] Electrochemical and spectroscopic characterization of lithium ion conductive polymers prepared by the copolymerization of ionic liquid monomers (2006)
  • Author(s): W. Ogihara, N. Suzuki, N.Nakamura and H. Ohno
  • Journal Title: Polymer J. 38 Pages: 117-121
• [Journal Article] Structural factors to improve physico-chemical properties of zwitterions as ion conductive matrices (2006)
  • Author(s): A. Narita, W. Shibayama, and H. Ohno
  • Journal Title: J.Materials Chem 16 Pages: 1475-1482
• [Journal Article] Lithium ion conduction in an organoborate zwitterion / LiTFSI mixture (2006)
  • Author(s): A. Narita, W. Shibayama, K. Sakamoto, T. Mizumo, N. Matsumi, and H. Ohno
  • Journal Title: Chem. Commun. Pages: 1926-1928
• [Journal Article] Importance of poly(ethylene oxide)modification and chloride anion for the electron transfer reaction of cytochrome c in 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide (2006)
  • Author(s): H. Ohno, C. Suzuki, and K. Fujita
  • Journal Title: Electrochim. Acta. 51 Pages: 3685-3691
• [Journal Article] Novel ion conductive matrix via dehydrocoupling polymerization of imidazolium-type ionic liquid and lithium 9-borabicyclo[3,3,1]nonane hydride (2006)
  • Author(s): A. Narita, W. Shibayama, M. Tamada, and H. Ohno
  • Journal Title: Polym. Bull. 57 Pages: 109-114
• [Journal Article] Thermally stable ion conductive polymer composites containing imideaniontype zwitterions (2006)
  • Author(s): A. Narita, W. Shibayama, M. Tamada, H. Ohno
  • Journal Title: Polym. Bull. 57 Pages: 115-120
• [Journal Article] Effect of tetrabutyl phosphonium cation on the physico-chemical properties of amino acid ionic liquids (2006)
  • Author(s): J. Kagimoto, K. Fukumoto, and H. Ohno
  • Journal Title: Chem. Commun. Pages: 2254-2256
• [Journal Article] Design and synthesis of hydrophobic and chiral anions from amino acids as precursor to functional ionic liquids (2006)
  • Author(s): K. Fukumoto and H. Ohno
  • Journal Title: Chem. Commun. Pages: 3081-3083
• [Journal Article] Proton-conducting ionic liquids based upon multivalent anions and alkylimidazolium cations (2006)
  • Author(s): W. Ogihara, H. Kosukegawa, and H. Ohno
  • Journal Title: Chem. Commun. Pages: 3637-3639
• [Journal Article] Polymerized ionic liquids via hydroboration polymerization as single ion conductive polymer electrolytes (2006)
  • Author(s): N. Matsumi, K. Sugai, M. Miyake, and H. Ohno
  • Journal Title: Macromolecules 39 Pages: 6924-6927
• [Journal Article] Functional design of ionic liquids (2006)
  • Author(s): H. Ohno
  • Journal Title: Bull. Chem. Soc. Jpn. 79 Pages: 1665-1680
• [Journal Article] Ionic conductivity of highly deprotonated natural rubber having various amount of epoxy group mixed with lithium salt (2006)
  • Author(s): W. Klinklai, S. Kawahara, E. Marwanta, T. Mizumo, Y. Isono, and H. Ohno
  • Journal Title: Solid State Ionics 177 Pages: 3251-3257
• [Presentation] Physicochemical properties of amino acid ionic liquids composed of phospho- nium cations(P-B23) (2008)
  • Author(s): J. Kagimoto, K. Fukumoto, and H. Ohno
  • Organizer: EUCHEM 2008 Conference on Molten Salts and Ionic Liquids
  • Place of Presentation: Copenhagen, Denmark
  • Year and Date: 20080824-29
• [Presentation] Design of ionic liquids for nonaqueous bio fuel cells (2008)
  • Author(s): H. Ohno
  • Organizer: International conference on ionic liquids for electrochemical devices (ILED-2008)
  • Place of Presentation: Rome, Italy
  • Year and Date: 20080609-11
• [Presentation] 含水イオン液体中でのセルロースの分解(1Pe167) (2008)
  • Author(s): 林 賢作、深谷幸信、大野弘幸
  • Organizer: 第57回高分子学会年次大会
  • Place of Presentation: 横浜
  • Year and Date: 20080528-30
• [Presentation] Thermally Stable Proton Conductive Liquids based on Zwitterionic Liquid HTFSI mixtures (2008)
  • Author(s): S. Ueda, M. Tamada, K. Fukumoto and H. Ohno
  • Organizer: 2008 Pacific Rim Meeting on Electrochemical and Solid State Science
  • Place of Presentation: Honolulu, Hawaii, USA
  • Year and Date: 2008-10-12
• [Presentation] 電気化学分野でイオン液体とバイオはつながるか?(3L31) (2008)
  • Author(s): 大野弘幸
  • Organizer: 電気化学会第75回大会
  • Place of Presentation: 山梨
  • Year and Date: 2008-03-31
• [Presentation] イオン液体型DNAを用いた色素分散固定膜のエレクトロクロミック挙動(4L6-42) (2008)
  • Author(s): 柿部剛史, 大野弘幸
  • Organizer: 日本化学会第88春季年会
  • Place of Presentation: 立教大学池袋
  • Year and Date: 2008-03-29
• [Presentation] Synthesis and properties of ion conductive polymers based on room temperature ionic liquids (2007)
  • Author(s): H. Ohno
  • Organizer: 9th International Symposium on Polymers for Advanced Technologies
  • Place of Presentation: Shanghai, China
  • Year and Date: 20071022-25
• [Presentation] Is ionic liquid excellent partner to prepare thin film batteries? (2007)
  • Author(s): H. Ohno
  • Organizer: IUPAC and ACS Conference
  • Place of Presentation: New York, USA
  • Year and Date: 20070610-13
• [Presentation] ホウ素-イミダゾール錯体を利用した目的イオン輸送材料の分子設計(3C01) (2007)
  • Author(s): 松見紀佳、大野弘幸
  • Organizer: 第56回高分子討論会
  • Place of Presentation: 名古屋工業大学
  • Year and Date: 2007-09-21
• [Presentation] イオン液体に溶解したチトクロムc の光導波路分光法を用いた酸化還元応答の解析(Y1054) (2007)
  • Author(s): 田村薫、大野弘幸
  • Organizer: 日本分析化学会第56年会
  • Place of Presentation: 徳島大学
  • Year and Date: 2007-09-20
• [Presentation] Miscibility and Phase Behavior of Water/Dicarboxylic Acid Type Ionic Liquid Mixed Systems (1P03-044) (2007)
  • Author(s): Y. Fukaya, K. Sekikawa, K. Murata, N. Nakamura, and H. Ohno
  • Organizer: 2nd International Congress on Ionic Liquids (COIL-2)
  • Place of Presentation: 横浜
  • Year and Date: 2007-08-07
• [Presentation] イオン液体を用いたイオン伝導性ポリイミドゲルの作成 -重合溶媒およびイオン伝導場としてのアルキルスルホン酸型イオン液体の利用-(1Pb52) (2007)
  • Author(s): 玉田政宏、上田沙織、林 隆宏、大野弘幸
  • Organizer: 平成19年度繊維学会年次大会
  • Place of Presentation: 東京
  • Year and Date: 2007-06-20
• [Presentation] イオン液体中でのセルロースとボロン酸との縮合を利用したリチウムボレートを有するイオン性ゲルの合成(1Pa135) (2007)
  • Author(s): 中村祐介、松見紀佳、青井啓悟、渡辺武志、水雲智信、大野弘幸
  • Organizer: 第56回高分子学会年次大会
  • Place of Presentation: 京都
  • Year and Date: 2007-05-27
• [Presentation] イオン液体の電気化学分野への利用(特1P17) (2007)
  • Author(s): 大野弘幸
  • Organizer: 電気化学会第74回大会
  • Place of Presentation: 東京理科大野田
  • Year and Date: 2007-03-29
• [Presentation] 機能性イオン液体の設計(1A4-27) (2007)
  • Author(s): 大野弘幸
  • Organizer: 日本化学会第87春季年会
  • Place of Presentation: 大阪、関西大学
  • Year and Date: 2007-03-25
• [Presentation] Design and Evaluation of Ion Conductive Polymers Based on Ionic Liquids (2006)
  • Author(s): H. Ohno
  • Organizer: 10th International Symposium on Polymer Electrolytes
  • Place of Presentation: Iguasu, Brasil
  • Year and Date: 2006-10-16
• [Presentation] Design of ion conductive polymers based on ionic liquids (2006)
  • Author(s): H. Ohno
  • Organizer: IUPAC International Symposium on Advanced Polymers for Emerging Technologies
  • Place of Presentation: Busan, Korea
  • Year and Date: 2006-10-11
• [Presentation] イオン液体型高分子を用いたDNA-色素複合膜の作成とエレクトロクロミック特性の評価(1Pd076) (2006)
  • Author(s): 柿部剛史、大野弘幸
  • Organizer: 第55回高分子討論会
  • Place of Presentation: 神戸
  • Year and Date: 2006-09-20
• [Presentation] アミノ酸を出発物質とする新規疎水性イオン液体の構造と物性の相関(2D20) (2006)
  • Author(s): 福元健太、大野弘幸
  • Organizer: 2006年電気化学会秋期大会
  • Place of Presentation: 同志社大学、京都
  • Year and Date: 2006-09-15
• [Presentation] Target cation transport in organoboron polymer electrolyte(INOR 582) (2006)
  • Author(s): N. Matsumi, H. Ohno
  • Organizer: 232nd ACS National Meeting, San Francisco, CA
  • Place of Presentation: San Francisco USA
  • Year and Date: 2006-09-12
• [Presentation] In-situゾル-ゲル法によるイオン液体ポリマー/ケイホウ酸ガラスハイブリッドの合成(1Pc147) (2006)
  • Author(s): 渡辺武志、松見紀佳、大野弘幸
  • Organizer: 第55回高分子学会年次大会
  • Place of Presentation: 名古屋
  • Year and Date: 2006-05-24
• [Presentation] グリーンの可能性が高いイオン液体の設計と機能(特2F-10) (2006)
  • Author(s): 大野弘幸
  • Organizer: 電気化学会第73回大会
  • Place of Presentation: 東京
  • Year and Date: 2006-04-02
• [Presentation] New class of ionic liquids synthesized from amino acid and other bio-derived materials (IEC 219) (2006)
  • Author(s): H. Ohno
  • Organizer: The 231st American Chemical Society National Meetings
  • Place of Presentation: Atlanta, Georgia, U.S.A.
  • Year and Date: 2006-03-29
• [Presentation] プロトン性ホウ素-イミダゾール錯体の合成および伝導特性評価(1D3-46) (2006)
  • Author(s): 芝岸 紗緒莉、松見紀佳、大野弘幸
  • Organizer: 日本化学会第86春季年会
  • Place of Presentation: 千葉
  • Year and Date: 2006-03-27
• [Book] Physical properties of ionic liquids for electrochemical applications(Ed. by F. Endres, et al., Wiley VCH) (2008)
  • Author(s): H. Ohno
  • Total Pages: 47-82
  • Publisher: Chapter 3 in "Electrodeposition from ionic liquids"
• [Remarks]
  • URL: http://www.tuat.ac.jp/~ohno/index.html