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2007 Fiscal Year Final Research Report Summary

Development of Cu Interconnects for 20nm Technology Node LSI

Research Project

Project/Area Number 17206071
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Structural/Functional materials
Research InstitutionIbaraki University

Principal Investigator

ONUKI Jin  Ibaraki University, College of Engineering, Professor (70315612)

Co-Investigator(Kenkyū-buntansha) TOMOTA Yo  Ibaraki University, College of Engineering, Professor (90007782)
SASAJIMA Yasushi  Ibaraki University, College of Engineering, Associate Professor (80187137)
AOYAMA Takasi  Akita Prefectural University, システム科学技術学部, Professor (80363737)
Project Period (FY) 2005 – 2007
KeywordsLSI / Low Resistivity / Grain Size / Cu Interconnects / High-purity Plating Material / Cu Plating / Oxygen / 酸素濃度
Research Abstract

Copper (Cu) has long been used as the wire material for high performance ultra large-scale integrated circuits (ULSIs). However, the significant increase in the resistivity of Cu wire with line widths less than 100 nm is a critical issue^< (1-3)>. In order to lower resistivity, both the coarsening of the grain sizes and the reduction in the thickness of high-resistivity barrier metals in Cu wires are crucial. However, a powerful grain size coarsening process to reduce electron scattering has not yet been developed up to now. It was recently reported that contamination in Cu films depress their grain growth during annealing^< (6)>.
This implies that low resistivity Cu wires could be created if high-purity very narrow wires can be formed. Hence, we have focused our attention on the purification of Cu wires and the investigation of a forming process using ultra-high purity 9N-Cu anode and high purity 6N-CuSO_4・5H_2O electrolyte.
Using the above high purity process, we have realized 50 nm wide Cu wires with about 21% lower resistivity than those made with the conventional process. It was also found that the low resistivity Cu wires formed with the new process have large grain sizes with a lower spread, and a much smaller amount of oxygen than those made with the conventional process.

  • Research Products

    (33 results)

All 2008 2007 2006

All Journal Article (28 results) (of which Peer Reviewed: 11 results) Presentation (4 results) Patent(Industrial Property Rights) (1 results) (of which Overseas: 1 results)

  • [Journal Article] Phase Field Simulation of Heat Treatment Process of Cu Wiring2008

    • Author(s)
      J., Kageyama・Y., Sasajima・J., Onuki
    • Journal Title

      Trans. Mater.Research Soc. Of Japan 33(印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] MD Simulation of Defect Generation During Annealing Process of Copper wiring2008

    • Author(s)
      T., Akabane・Y., sasajima・J., Onuki
    • Journal Title

      Trans.Mater.Research Soc. Of Japan 33(印刷中)

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] MD Simulation of Defect Generation During Annealing Process of Copper Wiring2008

    • Author(s)
      T. Akabane, Y. Sasajima and J. Onuki
    • Journal Title

      Trans. Mater. Research Soc. of Japan Vol.33(in printing)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Phase Field Simulation of Heat Treatment Process of Cu Wiring2008

    • Author(s)
      J. Kageyama, Y. Sasajima and J. Onuki
    • Journal Title

      Trans. Mater. Research Soc. Of Japan Vol.33(in printing)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Aspect Ratio Dependence of the Resistivity of Fine Line Cu lnterconnects2007

    • Author(s)
      K.P., Khoo・J., Onuki・T., Nagano・Y., Chonan
    • Journal Title

      Jpn.J.Appl.Phys. 46

      Pages: 4070-4073

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Microstructure of 50nm Cu lnterconnects along the Longitudinal Direction2007

    • Author(s)
      K.P., Khoo・J., Onuki・T., Nagano・S., Tashiro・Y., Chonan・H., Akahoshi・T., Haba・T., Tobita・M., Chiba・K., lshikawa
    • Journal Title

      Material.Trans. 48

      Pages: 2703-2707

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Determination of the Phase-Field Parameters for Computer Simulation of Heat Treatment Process of Ultra Thin Al Film2007

    • Author(s)
      J., Kageyama・Y., Sasajima・M., lchimura・J., Onuki
    • Journal Title

      Mater.Trans. 48

      Pages: 1998-2001

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Nanoscratching of Metallic Thin Film on Silicon Substrate2007

    • Author(s)
      K., Akabane・Y., Sasajima・J., Onuki
    • Journal Title

      J. of Electronic Materials 36

      Pages: 1174-1180

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Coatings Adhesion Evaluation by Nanoscratching Simulation Using the Molecular Dynamic Method2007

    • Author(s)
      T., Akabane・Y., Sasajima・J., Onuki
    • Journal Title

      Jpn. J. Appl. Phys. 46

      Pages: 3024-3028

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] これだけは知っておきたい最新の配線・実装技術、特集にあたって2007

    • Author(s)
      大貫 仁
    • Journal Title

      金属 77

      Pages: 835-836

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] これだけは知っておきたい最新の配線・実装技術、Cu配線の現状と将来2007

    • Author(s)
      大貫 仁・田代 優・K.P., Khoo
    • Journal Title

      金属 77

      Pages: 837-841

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] これだけは知っておきたい最新の配線・実装技術、配線設計のための計算機実験2007

    • Author(s)
      赤羽智明・影山順平・篠嶋妥
    • Journal Title

      金属 77

      Pages: 879-884

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Coatings Adhesion Evaluation by Nanoscaratching Simulation Using the Molecular Dynamic Method2007

    • Author(s)
      T. Akabane. Y. Sasajima and J. Onuki
    • Journal Title

      Jpn. J. Appl. Phys. Vol.46

      Pages: 3024-3028

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Nanoscratching of Metallic ThinFilm on Silicon Substrate : A Molecular Dynamic Study2007

    • Author(s)
      K. Akabane, Y. Sasajima and J. Onuki
    • Journal Title

      J. of Electronic Materials Vol.36

      Pages: 1174-1180

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Determination of the Phase-Field Parameters for Computer Simulation of Heat Treatment Process of Ultra Thin Al Film2007

    • Author(s)
      J. Kageyama, Y. Sasajima, M. Ichimura and J. Onuki
    • Journal Title

      Mater. Trans. Vol.48

      Pages: 1998-2001

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Microstructure of 50nm Cu Interconnects along the Longitudinal Direction2007

    • Author(s)
      K. P. Khoo, J. Onuki, T. Nagano, S. Tashiro, Y. Chonan, H. Akahoshi, T. Haba, T. Tobita, M. Chiba and K. Ishikawa
    • Journal Title

      Mater. Trans. Vol.48

      Pages: 2703-2707

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Aspect Ratio Dependence of the Resistivity of Fine Line Cu Interconnects2007

    • Author(s)
      K. P. Khoo, J. Onuki, T. Nagano and Y. Chonan
    • Journal Title

      Jpn. J. Appl. Phys. Vol.46

      Pages: 4070-4073

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Special Issue on Cu Metallization, Summary2007

    • Author(s)
      J. Onuki
    • Journal Title

      Kinzoku Vol.77

      Pages: 835-836

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Special Issue on Cu Metallization, Current Status and Future Prospect of Cu Interconnects2007

    • Author(s)
      J. Onuki, S. Tashiro and K. P. Khoo
    • Journal Title

      Kinzoku Vol.77

      Pages: 837-841

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Special Issue on Cu Metallization, Experiments using Computer Simulation for ULSI Interconnects Designing2007

    • Author(s)
      T. Akabane, J. Kageyama and Y. Sasajima
    • Journal Title

      Kinzoku Vol.77

      Pages: 879-884

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Computer Simulation of Silicon Manoscratch Test2006

    • Author(s)
      T., Akabane・Y., Sasajima・J., Onuki
    • Journal Title

      Mater. Trans. 47

      Pages: 1090-1097

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Filling a narrow and High Aspect-Ratio Trench with Electro-Cu Plating2006

    • Author(s)
      Y., Chonan・J., Onuki・T., Nagano・H., Akahoshi・T., ltabashi・T., Saitou・K.P., Khoo
    • Journal Title

      Mater. Trans. 47

      Pages: 1417-1419

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Filling 80nm-ide and High-Aspect-Ratio-Trench with Pulse Wave Copper Electroplating and Observation of Microstructure2006

    • Author(s)
      Y., Chonan・J., Onuki・T., Nagano・K.P., Khoo・T., Aoyama・H., Akahoshi・T., Haba・T., Saitou
    • Journal Title

      Jpn.J.Appl.Phys. 45

      Pages: 8604-8607

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Observation of Microstructure in the Longitudinal Direction of Very narrow Cu linterconnects2006

    • Author(s)
      K.P., Khoo・J., Onuki・T., Nagano・Y., Chonan・H., Akahoshi・T., Tobita・M., Chiba・T., Saitou・K., lshikawa
    • Journal Title

      Jpn.J.Appl.Phys. 45

      Pages: L852-L853

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Observation of Microstructures in the Longitudinal Direction of Very narrow Cu Interconnects2006

    • Author(s)
      K. P. Khoo, J. Onuki, T. Nagano, Y. Chonan, H. Akahoshi, T. Tobita M. Chiba, T. Saitou and K. Ishikawa
    • Journal Title

      Jpn. J. Appl. Phys. Vol.45

      Pages: L852-L853

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Filling 80nm-ide and High-Aspect-Ratio-Trench with Pulse Wave Copper Electroplating and Observation of Microstructure2006

    • Author(s)
      Y. Chonan, J. Onuki, T. Nagano, K. P. Khoo, T. Aoyama, H. Akahoshi, T. Haba and T. Saitou
    • Journal Title

      Jpn. J. Appl. Phys. Vol.45

      Pages: 8604-8607

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Filling a narrow and High Aspect-Ratio Trench with Electro-Cu Plating2006

    • Author(s)
      Y. Chonan, J. Onuki, T. Nagano, H. Akahoshi, T. Itabashi, T. Saitou and K. P. Khoo
    • Journal Title

      Mater. Trans. Vol.47

      Pages: 1417-1419

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Computer Simulation of Silicon Nanoscratch Test2006

    • Author(s)
      T. Akabane, Y. Sasajima and J. Onuki
    • Journal Title

      Mater. Trans. Vol.47

      Pages: 1090-1097

    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] The Development of an Innovative Process of Large Grained and Low Resistivity Cu Wires for less than hp 45nm ULSI2007

    • Author(s)
      S., Tashiro
    • Organizer
      International Interconnect Technology Conference
    • Place of Presentation
      U.S.A
    • Year and Date
      20070900
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] The Decelopment of an Innovative Process of Large Grained and Low Resistivity Cu Wires for less than hp 45nm ULSI2007

    • Author(s)
      S. Tashiro, K. P. Khoo, T. Nagano, J. Onuki, Y. Chonan, H. Akahoshi, T. Tobita, M. Chiba, K. Ishikawa and N. Ishikawa
    • Organizer
      IITC(International Interconnect Technology Conference, June)
    • Place of Presentation
      Sangrancusco
    • Year and Date
      20070000
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Controlling the Resistivity of Fine Line Cu Interconnects2006

    • Author(s)
      K.P., Khoo
    • Organizer
      ADETA(Advanced Metallization Conference)
    • Place of Presentation
      日本
    • Year and Date
      20061000
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Controlling the Resistivity of Fine Line Cu Interconnects2006

    • Author(s)
      K. P. Khoo, J. Onuki, T. Nagano and Y. Chonan
    • Organizer
      ADMETA(Advanced Metallization Conference)
    • Place of Presentation
      Tokyo
    • Year and Date
      20060000
    • Description
      「研究成果報告書概要(欧文)」より
  • [Patent(Industrial Property Rights)] 半導体集積回路装置及びその製造方法2007

    • Inventor(s)
      大貫、田代、K.P. Khoo.長野、石川、古屋
    • Industrial Property Rights Holder
      茨城大学 物質・材料研究機構 (株)ボンゾー
    • Industrial Property Number
      特願2007-106945号
    • Filing Date
      2007-04-16
    • Description
      「研究成果報告書概要(和文)」より
    • Overseas

URL: 

Published: 2010-02-04  

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