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2008 Fiscal Year Final Research Report

Synthesis of mono-dispersed metallic nanoparticles and its application to electronics wiring

Research Project

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Project/Area Number 17206077
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Metal making engineering
Research InstitutionOsaka University

Principal Investigator

SUGANUMA Katsuaki  Osaka University, 産業科学研究所, 教授 (10154444)

Co-Investigator(Kenkyū-buntansha) INOUE Masahiro  大阪大学, 産業科学研究所, 助手 (60291449)
KIM Keun-soo  大阪大学, 産業科学研究所, 助手 (90304857)
Project Period (FY) 2005 – 2008
Keywords高密度実装 / ナノ材料 / 微細接続 / インクジェット / 配線
Research Abstract

金属ナノ粒子は、その表面の活性さから、低温において焼結が可能になり、ナノ粒子を保護膜で覆い安定インク化することで、プリンテッド・エレクトロニクスの基本的な配線材料になると期待されている。本研究では、当初銀ナノ粒子に集中して開発を行い、ナノ粒子の保護膜としてドデシルアミンを用いたインクの塗布特性を評価したところ、塗布後の配線のアルコール洗浄により、劇的に抵抗値が下がることを見いだした。結果として、ナノ粒子インクを用いた常温配線技術を世界初の成果として達成し、そのアルコール洗浄反応のおよそのメカニズムを明らかにした。また、応用技術として、マイクロカプセル製造、常温接合技術の開発や、銀配線特性評価などへ展開を行った。

  • Research Products

    (44 results)

All 2009 2008 2007 2006 2005

All Journal Article (22 results) (of which Peer Reviewed: 17 results) Presentation (10 results) Book (11 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Room Temperature Sintering Process of Ag Nanoparticles Paste and its Conditions2009

    • Author(s)
      D. Wakuda, K.-S. Kim, K. Suganuma
    • Journal Title

      Conditions, IEEE Trans.CPMT (in press)

    • Peer Reviewed
  • [Journal Article] インクジェット技術の最新動向2009

    • Author(s)
      菅沼克昭
    • Journal Title

      電子材料 Vol.48, No.2

      Pages: 67-73

  • [Journal Article] エレクトロニクス分野の導電性接着剤技術の動向2009

    • Author(s)
      菅沼克昭, 進藤大輔, 大塚寛治, 苅谷義治
    • Journal Title

      エレクトロニクス実装学会誌 Vol.12, No.1

      Pages: 79-85

  • [Journal Article] Preparation of Ag nanorods with high yield by polyol process2009

    • Author(s)
      J.T. Jiu, K. Murai, D.-S. Kim, K.-S. Kim, K. Suganuma
    • Journal Title

      Materials Chemistry and Physics 114

      Pages: 333-338

    • Peer Reviewed
  • [Journal Article] Printed Electronicsの最先端技術動向2008

    • Author(s)
      菅沼克昭
    • Journal Title

      コンバーテック No.7

      Pages: 1-4

  • [Journal Article] インクジェット技術による製造革新2008

    • Author(s)
      菅沼克昭、和久田大介、金槿銖
    • Journal Title

      月刊ディスプレイ 14[6]

      Pages: 41-47

  • [Journal Article] 常温焼結Ag粒子ペーストの性質と常温接合2008

    • Author(s)
      和久田大介, 金槿銖, 菅沼克昭
    • Journal Title

      エレクトロニクス実装学会 (MES2008)

      Pages: 147-150

    • Peer Reviewed
  • [Journal Article] Room Temperature Sintering of Ag Nano-scale particles with drying of the solvent2008

    • Author(s)
      D. Wakuda, K.-S. Kim, K. Suganuma
    • Journal Title

      IEEE Polytronic 2008 Conference Garmisch-Partenkirchen, Germany, August

      Pages: 17-20

    • Peer Reviewed
  • [Journal Article] Room temperature sintering of Ag nanoparticles by drying of the solvent2008

    • Author(s)
      D. Wakuda, K.-S. Kim, K. Suganuma
    • Journal Title

      Scripta Materialia 59[6]

      Pages: 649-652

    • Peer Reviewed
  • [Journal Article] トータルエコデザインによる貴金属ナノ粒子材料のプロセス開発とその応用粉体および粉末冶金2007

    • Author(s)
      林大和、石川 大、滝澤博胤、井上雅博、菅沼克昭、新原皓一
    • Journal Title

      Vol.54, No.3

      Pages: 186-193

    • Peer Reviewed
  • [Journal Article] 常温焼結ナノ粒子ペーストの性質及び焼結メカニズム2007

    • Author(s)
      和久田大介、菅沼克昭
    • Journal Title

      MES2007(第17回マイクロエレクトロニクスシンポジウム)

      Pages: 35-38

    • Peer Reviewed
  • [Journal Article] Novel room temperature wiring process of Ag nanoparticle paste, Proc.6th International IEEE Conference on Polymers and Adhesives in Microelectronics and Photonics(Polytronics 2007)2007

    • Author(s)
      D. Wakuda, K. Suganuma
    • Journal Title

      Tokyo, Japan

      Pages: 110-113

    • Peer Reviewed
  • [Journal Article] Conductive Adhesives : Alternative to High Temperature Solders and The Future2007

    • Author(s)
      K. Suganuma
    • Journal Title

      6th International IEEE Conference on Polymer and Adhesives in microelectronics and Photonics(Tokyo)

      Pages: 30-35

    • Peer Reviewed
  • [Journal Article] Thermal stability of poly(vinylidene fluoride) films pre-annealed at various temperatures2007

    • Author(s)
      M. Inoue, Y. Tada, K. Suganuma, H. Ishiguro
    • Journal Title

      Polymer Degradation and Stability 92[10]

      Pages: 1833-1840

    • Peer Reviewed
  • [Journal Article] Novel method for room temperature sintering of Ag nanoparticle paste in air2007

    • Author(s)
      D. Wakuda, M. Hatamura, K. Suganuma
    • Journal Title

      Chemical Physics Letters 441

      Pages: 305-308

    • Peer Reviewed
  • [Journal Article] Tanaami, Low Temperature Printing Wiring with Ag Salt Pastes, 39th International Symposium on Microelectronics(IMAPS2006), Bringing Together the Entire Microelectronics Supply Chain!2006

    • Author(s)
      M. Kawazome, K. Suganuma, M. Hatamura, K.-S. Kim, S. Horie, A. Hirasawa, H. Tanaami
    • Journal Title

      San Diego October 8-12

      Pages: 1050-1055

    • Peer Reviewed
  • [Journal Article] Fabrication and Applications of Nano-metal Particle Composites by Ultrasonic Eco-process2006

    • Author(s)
      Y. Hayashi, H. Takizawa, Y. Saijo, T. Sekino, K. Suganuma, K. Niihara
    • Journal Title

      Key Engineering Materials 317-318

      Pages: 231-234

  • [Journal Article] Degradation by Sn diffusion applied to surface mounting with Ag-epoxy conductive adhesive with joining pressure2006

    • Author(s)
      M. Yamashita, K. Suganuma
    • Journal Title

      Microelectronics Reliability 46[7]

      Pages: 1113-1118

    • Peer Reviewed
  • [Journal Article] Effect of curing conditions on the electrical properties of isotropic conductive adhesives composed of an epoxy-based binder2006

    • Author(s)
      M. Inoue, K. Suganuma
    • Journal Title

      Soldering & Surface Mount Technology 18[2]

      Pages: 40-45

    • Peer Reviewed
  • [Journal Article] Improvement in high-temperature degradation by isotropic conductive adhesives including Ag-Sn alloy fillers2006

    • Author(s)
      M. Yamashita, K. Suganuma
    • Journal Title

      Microelectronics Reliability 46 (5-6)

      Pages: 850-858

    • Peer Reviewed
  • [Journal Article] Differences in heat exposure degradation of Sn alloy platings joined with Ag-epoxy conductive adhesive2006

    • Author(s)
      M. Yamashita, K. Suganuma
    • Journal Title

      J. Mater. Sci. 41 (2)

      Pages: 583-585

    • Peer Reviewed
  • [Journal Article] Effect of curing conditions on the interconnect properties of isotropic conductive adhesives composed of an epoxy-based binder2005

    • Author(s)
      M. Inoue, K. Suganuma
    • Journal Title

      Proc. 7th IEEE CPMT Conference on High Density Microsystem Design, Packaging and Failure Analysis (HDP'05)

      Pages: 128-133

    • Peer Reviewed
  • [Presentation] Degradation Mechanism of Ag-Epoxy Conductive Adhesive Joints by Heat and Humidity Exposure2008

    • Author(s)
      S. S. Kim, K.-S. Kim, K. Suganuma, H. Tanaka
    • Organizer
      2nd Electronics System-Integration Technology Conference(ESTC 2008), University of Greenwich
    • Place of Presentation
      London, UK
    • Year and Date
      20080901-04
  • [Presentation] Room Temperature Sintering Mechanism of Ag Nanoparticle Paste2008

    • Author(s)
      D. Wakuda, C.-J. Kim, K.-S. Kim, and K. Suganuma
    • Organizer
      IEEE 2nd Electronics System-Integration Technology Conference
    • Place of Presentation
      Greenwich, UK
    • Year and Date
      20080901-04
  • [Presentation] Synthesis of Ag nanorods and application to soft die attaching2008

    • Author(s)
      J. Jiu, K. Murai, K.S. Kim, K. Suganuma
    • Organizer
      7th IEEE Conference on Polymers & Adhesives in Microelectronics & Photonics
    • Place of Presentation
      Germany
    • Year and Date
      20080817-20
  • [Presentation] Room Temperature Sintering of Ag Nano-scale particles with drying of the solvent2008

    • Author(s)
      D. Wakuda, K.-S. Kim, K. Suganuma
    • Organizer
      IEEE Polytronic 2008 Conference, Garmisch-Partenkirchen
    • Place of Presentation
      Germany
    • Year and Date
      20080817-20
  • [Presentation] Large-sacel synthesis of micrometer-scale single-crystal gold nanosheets by polyol process2008

    • Author(s)
      J. Jiu, K. Suganuma, K.-S. Kim, T. Nemoto, T. Ogawa, S. Isoda
    • Organizer
      2008 International Materials Research Conference
    • Place of Presentation
      Chongqing, China
    • Year and Date
      20080609-12
  • [Presentation] Ink-Jet Printing Nanoparticle Pastes for Printed Electronics2007

    • Author(s)
      K. Suganuma
    • Organizer
      International Conference on High Density Packaging(HDP2007)
    • Place of Presentation
      IEEE CPMT
    • Year and Date
      20070627-28
  • [Presentation] Novel room temperature wiring process of Ag nanoparticle paste2007

    • Author(s)
      D. Wakuda, K. Suganuma
    • Organizer
      Proc. 6th International Adhesives in Microelectronics and Photonics (Polytronics 2007)
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      20070116-18
  • [Presentation] Conductive Adhesives : Alternative to High Temperature Solders and The Future2007

    • Author(s)
      K. Suganuma
    • Organizer
      6th International IEEE Conference on Polymer and Adhesives in microelectronics and Photonics
    • Place of Presentation
      Tokyo
    • Year and Date
      20070116-18
  • [Presentation] Low Temperature Printing Wiring with Ag Salt Pastes2006

    • Author(s)
      M. Kawazome, K. Suganuma, M. Hatamura, K.-S. Kim, S. Horie, A. Hirasawa, and H. Tanaami
    • Organizer
      39th International Symposium on Microelectronics (IMAPS2006), Bringing Together the Entire Microelectronics Supply Chain!
    • Place of Presentation
      San Diego
    • Year and Date
      20061008-12
  • [Presentation] Low/high Temperature Lead-free Soldering, Tin Whiskers and Next Steps Towards the Future2006

    • Author(s)
      K. Suganuma
    • Organizer
      1^<st> Electronics Systemintegration Technology Conference(ESTC2006)
    • Place of Presentation
      IEEE CPMT, Dresden, Germany
    • Year and Date
      20060905-07
  • [Book] プリンテッド・エレクトロニクス技術(共著)2009

    • Author(s)
      菅沼克昭、棚網宏
    • Publisher
      工業調査会
  • [Book] 電子回路形成への応用(分担執筆)、Electronic Journal別冊「2009インクジェット技術大全」2008

    • Author(s)
      菅沼克昭、金 槿銖、和久田大介
    • Total Pages
      89-97
    • Publisher
      電子ジャーナル
  • [Book] インクジェット技術による金属ナノ粒子インク配線(分担執筆)、インクジェットプリンターの応用と材料II2007

    • Author(s)
      菅沼克昭、和久田大介、金 槿銖
    • Total Pages
      209-218
    • Publisher
      CMC出版
  • [Book] インクジェット配線技術(分担執筆)、最新導電性材料技術大全集<下巻>2007

    • Author(s)
      菅沼克昭
    • Total Pages
      221-233
    • Publisher
      技術情報協会
  • [Book] インクジェット印刷による微細配線技術(分担執筆)、最新インクジェット技術2007

    • Author(s)
      菅沼克昭
    • Total Pages
      213-220
    • Publisher
      技術情報協会
  • [Book] 電子回路形成への応用(分担執筆)、Electronic Journal別冊「2007インクジェット技術大全」2007

    • Author(s)
      菅沼克昭、金槿銖、和久田大介
    • Total Pages
      76-82
    • Publisher
      電子ジャーナル
  • [Book] インクジェット印刷による微細配線技術(分担執筆)、最新エレクトロニクス実装大全集<下巻>2007

    • Author(s)
      菅沼克昭
    • Total Pages
      102-109
    • Publisher
      技術情報協会
  • [Book] 金属ナノ粒子インクの合成と微細配線形成(分担執筆)、最新エレクトロニクス実装大全集<下巻>2007

    • Author(s)
      菅沼克昭
    • Total Pages
      93-101
    • Publisher
      技術情報協会
  • [Book] Printed Electronicsのためのナノ粒子微細配線技術2006

    • Author(s)
      河染 満、金 槿銖、畑村眞里子、菅沼克昭
    • Total Pages
      27-31
    • Publisher
      粉砕
  • [Book] 金属ナノ粒子ペーストのインクジェット微細配線(監修)2006

    • Author(s)
      菅沼克昭
    • Publisher
      シーエムシー出版
  • [Book] 金属ナノ粒子ペーストと微細配線技術(分担執筆)、導電性ナノフィラーと応用製品2005

    • Author(s)
      菅沼克昭、金 槿銖
    • Total Pages
      150-159
    • Publisher
      CMC出版
  • [Patent(Industrial Property Rights)] 金属ナノ粒子の焼結方法およびその焼結方法を用いた配線2006

    • Inventor(s)
      菅沼克昭、畑村眞里子、和久田大介
    • Industrial Property Rights Holder
      財団法人大阪産業振興機構/国立大学法人大阪大学
    • Industrial Property Number
      特許, 特願2006-251329
    • Filing Date
      2006-09-15

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Published: 2010-06-10   Modified: 2016-04-21  

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