多環芳香族炭化水素と大気浮遊微細鉱物の相互作用およびその運搬媒体の解明

2007 Fiscal Year Annual Research Report

• Project/Area Number: 17340163
• Research Institution: Hokkaido University
• Principal Investigator: 佐藤 努 Hokkaido University, 大学院・工学研究科, 准教授 (10313636)
• Co-Investigator(Kenkyū-buntansha): 早川 和一 金沢大学, 大学院・自然科学研究科, 教授 (40115267) ; 柏谷 健二 金沢大学, 環日本海域環境研究センター, 教授 (30161029) ; 川西 琢也 金沢大学, 大学院・自然科学研究科, 准教授 (80234087)
• Keywords: 黄砂 / PAH / 鉱物 / 環日本海 / 越境汚染

Research Abstract

多環芳香族炭化水素(PAH)が国境を超えて長距離運搬されることについて世界の各地で報告がなされてきたが、近年の東アジア諸都市の著しい経済発展にもかかわらず、そこから日本海を越える長距離運搬に関しては明らかにされてこなかった。本研究では、まず初めに、金沢において2003年の春季から1年間エアロゾルをサンプリングし、黄砂粒子に伴われるPAHの長距離運搬に関して検討した。その結果、黄砂に伴われるPAHは東アジア大陸内部のPAHに汚染された土壌からもたらされたものと推定した。後方流跡線解析の結果、PAHを伴う黄砂は工業地帯に隣接する黄土高原から発生していることも明らかとなった。次に、黄砂粒子表面に吸着したPAHの安定性を検討するため、ピレンやフェナントレンをPAHのモデル物質とし、石英、アルミナ、カオリナイトおよびモンモリロナイトに混合されたピレンやフェナントレンの挙動を暗所、相対湿度・温度制御下で調べた。これらの黄砂構成鉱物の中では、粘土鉱物であるモンモリロナイトのPAH吸着量が高く、PAHと高い親和性を有する土壌有機成分であるフミン酸との親和性も高かった。一方、石英は黄砂構成鉱物としての相対量が大きいが、その表面がPAHの分解性を有していることも明らかとなった。以上のことから、モンモリロナイトが最も優勢なPAHの運搬媒体であることが予想される。また、相対湿度0.1%未満の暗所において、カオリナトおよびモンモリロナイトとの混合試料が黒色に変色していることが認められ、反応生成物の質量分析の結果から、反応物はピレン重合したものであると結論づけた。以上のことから(1)粘土鉱物がPAHの優勢な運搬媒体であること、(2)暗所でもPAHの反応を促進させる可能性のあること、(3)その活性は相対湿度等に大きく依存することが明らかとなった。

Research Products

• [Journal Article] A Determination Method for Nitrocatecholamines in Rat Brain with High-Performance Liquid Chromatography-Peroxyoxalate Chemiluminescence Detection (2008)
  • Author(s): Tsunoda, M., Uchino, E., Imai, K., Hayakawa, K., Funatsu, T.
  • Journal Title: Chromatographia (in press)
  • Peer Reviewed
• [Journal Article] Long-Range Transportation of Polycyclic Aromatic Hydrocarbons from China to Japan (2008)
  • Author(s): Yang, X.-Y., Okada, Y., Tang, N., Matsunaga, S., Tamura, K., Kameda, T., Toriba, A., Hayakawa, K.
  • Journal Title: Atmos. Environ. (in press)
  • Peer Reviewed
• [Journal Article] Environmental quinoid polycyclic aromatic hydrocarbon, acenaththenequinone, modulates COX expression through ROS generation and NF-κB activation in A549 cells (2008)
  • Author(s): Chung, S.-W., Chung, H.-Y., Toriba, A., Hayakawa, K.
  • Journal Title: Toxicol. Sci (in press)
  • Peer Reviewed
• [Journal Article] Identification and Quantification of 1-Nitropyrene Metabolites in Human Urine as a Proposed Biomarker for Exposure to Diesel Exhaust (2007)
  • Author(s): Toriba, A., Kitaoka, H., Dills, R., Mizukami, S., Tanabe, K., Takeuchi, N., Ueno, M., Kameda, T., Tang, N., Hayakawa, K., Simpson, C.
  • Journal Title: Chem. Res. Toxicol 20(7) Pages: 999-1007
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] Usefulness of Catechins and Caffeine Profiles to Determine Growing Areas of Green Tea Leaves of a Single Variety, Yabukita, in Japan (2007)
  • Author(s): Kodama, S., Ito, Y., Nagase, H., Yamashita, T., Kemmei, T., Yamamoto, A., Hayakawa, K.
  • Journal Title: J. Health Sci. 53(4) Pages: 491-495
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] Determination of Low-Level Ethylenediaminetetraacetic Acid in Water Samples by Ion Chromatography with Ultraviolet Detection (2007)
  • Author(s): Kemmei, T., Kodama, S., Yamamoto, A., Inoue, Y., Hayakawa, K.
  • Journal Title: Chromatographia 65(3/4) Pages: 229-232
  • Description: 「研究成果報告書概要(和文)」より
  • Peer Reviewed
• [Journal Article] Long-range transport of polycyclic aromatic hydrocarbons(PAHs)from the eastern Asian continent to Kanazawa, Japan with Asian dust Atmospheric Environment (2007)
  • Author(s): Tamamura, S., Sato, T., Ota, Y., Wang, X., Tang N., and Hayakawa, K.
  • Journal Title: Atmos. Environ. 41 Pages: 2580-2593
  • Peer Reviewed
• [Journal Article] Uptake of dissolved arsenic in the retrieval of silica from spent geothermal brine (2007)
  • Author(s): Pascua, C. S., Minato, M., Yokoyama, S. and Sato, T.
  • Journal Title: Geothermics 36 Pages: 230-242
  • Peer Reviewed
• [Journal Article] モンモリロナイト/水分酸液の粘度に影響を与える要因 (2007)
  • Author(s): 鈴木啓三, 佐藤 努, 米田哲朗, 榎戸 洋之
  • Journal Title: 粘土科学 46 Pages: 20-130
  • Peer Reviewed
• [Journal Article] 高精製モンモリロナイトの調製とキャラクタリゼーション (2007)
  • Author(s): 鈴木啓三, 高木慎介, 佐藤 努, 米田 哲朗
  • Journal Title: 粘土科学 46 Pages: 147-155
  • Peer Reviewed
• [Journal Article] Evaluation of Endocrine Disrupting Activities of Monohydroxylated Derivatives of 1-Nitropyrene by Yeast Two-hybrid Assay (2007)
  • Author(s): Kameda, T., Akiyama, A., Toriba, A., Tachikawa, C., Yoshita, M., Tang, N., Hayakawa, K
  • Journal Title: J.Health Sci 54(1) Pages: 631-638
  • Peer Reviewed
• [Journal Article] Minireview: Biomarkers of exposure to polycyclic aromatic hydrocarbons and related compounds (2007)
  • Author(s): Toriba, A., Hayakawa
  • Journal Title: J. Health Sci. 56(11) Pages: 905-920
  • Peer Reviewed
• [Journal Article] Determination of Sequestering Agents on Cosmetics and Synthetic Deter gents by High-Performance Liquid Chromatography with Ultraviolet Detection (2007)
  • Author(s): Kemmei, T., Kodama, S., Yamamoto, A., Inoue, Y., Hayakawa, K.
  • Journal Title: J. Chromatogr. A 1171 Pages: 63-68
  • Peer Reviewed
• [Journal Article] 分析化学総説:有害性ニトロ多環芳香族炭化水素類を対象とする分析法の開発と環境動態解析 (2007)
  • Author(s): 早川和一, 鳥羽 陽, 亀田貴之, 唐 寧
  • Journal Title: 分析化学 56(11) Pages: 905-920
  • Peer Reviewed
• [Journal Article] Simultaneous Chiral Resolution of Monosaccharides as 8-Aminonaphthalene-1,3,6-Trisulfonate Derivatives by Ligand-Exchange CE Using Borateas a Central Ion of the Chiral Selector (2007)
  • Author(s): Kodama, S., Aizawa, S., Taga, A., Yamashita, T., Kemmei, T., Yamamoto, A., Hayakawa, K.
  • Journal Title: Electrophoresis 28 Pages: 3930-3933
  • Peer Reviewed
• [Journal Article] Identification of Estrogenic/Anti-Estrogenic Compounds in Diesel Exhaust Particulate Extract (2007)
  • Author(s): Noguchi, K., Toriba, A., Chung, S.-W., Kizu, R., Hayakawa, K.
  • Journal Title: Biomed. Chromatogr 21(11) Pages: 1135-1142
  • Peer Reviewed
• [Journal Article] Estrogenic/Antiestrogenic Activities of Polycyclic Aromatic Hydocarbons and Their Monohydroxylated Derivatives by Yeast Two-Hybrid Assay (2007)
  • Author(s): Hayakawa, K., Onoda, Y., Tachikawa, C., Hosoi, S., Yoshita, M., Chung, S.-W., Kizu, R., Toriba, A., Kameda, T., and Tang, N.
  • Journal Title: J. Health Sci. 53(5) Pages: 562-570
  • Peer Reviewed
• [Journal Article] Analysis of 1-nitropyrene in air particulate matter standard reference materials by using two-dimensional high performance liquid chromatography with online reduction and tandem mass spectrometry detection (2007)
  • Author(s): Miller-Schulze, J. P., Paulsen, M., Toriba, A., Hayakawa, K., Simpson, C.D.
  • Journal Title: J. Chromatogr. A 1167 Pages: 154-160
  • Peer Reviewed
• [Journal Article] Enantioseparation of Isoxanthohumol in Beer by Hydroxypropyl-Y-cyclodextrin-Modified Micellar Electrokinetic Chromatography (2007)
  • Author(s): Kodama, S., Yamamoto, A., Sato, A., Suzuki, K., Yamashita, T., Kemmei, T., Taga, A., Hayakawa, K.
  • Journal Title: J. Agric. Food Chem 55(16) Pages: 6547-6552
  • Peer Reviewed
• [Journal Article] Degradation of Benzo[a]pyrene using TiO_2 and Ag-loaded BiVO_4 Photocatalysts: Evaluation by the Ames Mutagenicity Assay (2007)
  • Author(s): Kohtani, S., Inaoka, Y., Hayakawa, K., Nakagaki, R.
  • Journal Title: J. Adv. Oxid. Technol. 10 Pages: 381-386
  • Peer Reviewed
• [Journal Article] Atmonspheric Environment in the Northeast Region of China in View of Polycyclic Aromatic Hydrocarbons and Nitropolycyclic Aromatic Hydrocarbons (2007)
  • Author(s): Tang, N., Tamura, K., Yang, X.-Y., Kameda, T., Toriba, A., Hayakawa, K.
  • Journal Title: J. Ecotech. Res 13(1) Pages: 35-42
  • Peer Reviewed
• [Journal Article] Study on atmospheric polycyclic aromatic hydrocarbons at a background site of Ishikawa prefecture. Japan (2007)
  • Author(s): Yang, X.-Y., Okada, Y., Tang, N., Toriba, A., Hayakawa K.
  • Journal Title: J. Ecotech. Research 13 Pages: 5-9
  • Peer Reviewed
• [Journal Article] 多環芳香族炭化水素及びニトロ多環芳香族炭化水素から見た中国東北地方の大気環境 (2007)
  • Author(s): 唐 寧, 田村憲治, 楊 小陽, 亀田 貴之, 鳥羽 陽, 早川和一
  • Journal Title: J. Ecotech. Res. 13 Pages: 35-42
  • Peer Reviewed
• [Journal Article] Deposition analysis of non sea-salt sulfate and nitrate along to the northwest winter monsoon in Hokuriku district by a snow boring core and bulk samples (2007)
  • Author(s): Honoki, H., Watanabe, K., Iida, H., Kawada, K. and Hayakawa, K.
  • Journal Title: Bull. Glaciological Res. 24 Pages: 23-28
  • Peer Reviewed
• [Journal Article] Specific separation of polar analytes on a medium polar stationary phase by gaschromatography with carrier gas containing vaporous modifiers (2007)
  • Author(s): Ito, H., Sugiura, T., Nagai, H., Murase, A., Kodama, S., Inoue, Y., Yamamoto, A., Hayakawa, K.
  • Journal Title: Chromatography 28 Pages: 25-28
  • Peer Reviewed
• [Journal Article] Profiles of Particulate-Bound Polycyclic Aromatic Hydrocarbons and Their Nitrated Derivatives in Three Typical Cities, Liaoning Province, China (2007)
  • Author(s): Hattori, T., Tang, N., Tamura, K., Hokoda, A., Yang, X.-Y., Igarash K., Ohno, M., Okada, Y., Tbriba, A., Hayakawa, K.
  • Journal Title: Environ. Forensics 8 Pages: 165-172
  • Peer Reviewed
• [Journal Article] Rapid and sensitive determination of tryptophan, serotonin and psychoactive tryptamines by thin-layer chromatography/fluorescence detection (2007)
  • Author(s): Kato, N., Kojima, T., Yoshiyagawa, S., Ohta, H., Toriba, A., Nishimura, H., Hayakawa K
  • Journal Title: J. Chromatogr. A 1145 Pages: 229-233
  • Peer Reviewed
• [Journal Article] Bisphenol A(BPA)in foods in Japanese markets and its source (2007)
  • Author(s): Sajiki, J., Miyamoto, F., Fukata, H., Mori, C., Yonekubo, J., Hayakawa, K
  • Journal Title: Food Addit. Contam. 24 Pages: 103-112
  • Peer Reviewed
• [Presentation] 多環芳香族炭化水素類の有害性と環境動態の追跡 (2008)
  • Author(s): 早川和一
  • Organizer: 第78回日本衛生学会総会
  • Place of Presentation: 熊本(熊本市民会館)
  • Year and Date: 20080328-31
• [Presentation] 能登半島輪島における大気中フッ化物イオン実態調査 (2008)
  • Author(s): 唐 寧, 楊 小陽, 山田 丸, 亀田貴之, 鳥羽 陽, 早川和一
  • Organizer: 日本薬学会第128年会
  • Place of Presentation: 横浜(パシフィコ横浜)
  • Year and Date: 20080325-28
• [Presentation] Polycyclic aromatic hydrocarbons and nitropolycyclic aromatic hydrocarbons in urban air and their long-lange transportation (2008)
  • Author(s): Hayakawa, K.
  • Organizer: International Conference on Chemistry Chem 05 "Green and Sustainable Chemistry for Developing Countries"
  • Place of Presentation: Cairo, Egypt(Cairo University)
  • Year and Date: 20080303-06
• [Presentation] 環境汚染物質の分解,処理について (2008)
  • Author(s): 早川和一
  • Organizer: 日本薬学会第128年会
  • Place of Presentation: 横浜(パシフィコ横浜)
  • Year and Date: 2008-03-21
• [Presentation] Atmospheric Behaviors and Health Effects of Polycyclic Aromatic Hydrocarbons and Nitropolycyclic Aromatic Hydrocarbons in Eas (2007)
  • Author(s): Hayakawa, K.
  • Organizer: International Forum for Public Health, Shanghai 2007
  • Place of Presentation: Shanghai, China(Venue) Skyway Landis Hotel
  • Year and Date: 20071212-14
• [Presentation] Long-range transport of polycyclic aromatic hydrocarbons(PAHs)from the eastern Asian continent to Kanazawa, Japan with Asian dust (2007)
  • Author(s): Shuji Tamamura, Tsutomu Sato, Yukie Ota, Xiling Wang, Ning Tang, Kazuichi Hayakawa
  • Organizer: American Geophysical Union Fall Meeting
  • Place of Presentation: San Francisco, America(Moscone South)
  • Year and Date: 20071210-14
• [Presentation] The Environmental Carcinogen of Burning-drived Particulate Exhausts of Mutagenicity and Reactive Oxygen Species (2007)
  • Author(s): Bekki, K., Arashidani, K., Igarashi, K., Kano, F., Kameda, T., Sakai, S., Tang, N., Toriba, A., Hashiba, H., Mishukov, V. F., Hae, Y. C., Lin, J. M., Hayakawa, K.
  • Organizer: 1st Asian Conference on Environmental Mutagens/36th Annual Meeting of The Japanese Environmental Mutagen Society
  • Place of Presentation: Kitakyushu, Japan(Kitakyushu International Conference Center)
  • Year and Date: 20071129-30
• [Presentation] アジア大陸起源の水溶性フッ化物イオンの日本への長距離輸送 (2007)
  • Author(s): 楊 小陽, 山田 丸, 唐 寧, 亀田貴之, 鳥羽 陽, 早川和一
  • Organizer: フォーラム2007:衛生薬学, 環境トキシコロジー
  • Place of Presentation: 大阪(アピオ大阪森ノ宮ピロティホール)
  • Year and Date: 20071101-02
• [Presentation] Monitoring and Atmospheric Behaviors of Carrcinogenic/Endocrine Disrupting Chemicals in East Asis: Polycyclic Aromatic Hydrocarbons and Nitropolycyclic Derivatlves (2007)
  • Author(s): Hayakawa, K., Tang, N., Kameda, T. Toriba, A.
  • Organizer: 4th Asian-Pacific International Conference on Pollutants' Analysis and Control
  • Place of Presentation: Beijing, China(Xijiao Hotel)
  • Year and Date: 20071010-15
• [Presentation] Vertical Mixing of Lake Water and Sediment Transport Based on Four Year Continuous Monitoring in the Hypolimnion of Lake Biwa (2007)
  • Author(s): Yasuaki Aota, Kenji Kashiwa ya and Michio Kumagai
  • Organizer: 4th CJK International workshop on Present Earth Surface Processes and Historical Environmental Changes in East Asia-Modern Lake-Catchment Processes and Human Activity in East Asia
  • Place of Presentation: Nanjing, China(Nanjing Institute of Geography and Limnology)
  • Year and Date: 20070917-21
• [Presentation] Hydro-environmental fluctuations around Lake Biwa during the past 2000 years (2007)
  • Author(s): Taeko Itono and Kenji Kashi wava
  • Organizer: 4th CJK International workshop on Present Earth Surface Processes and Historical Environmental Changes in East Asia-Modern Lake-Catchment Processes and Human Activity in East Asia
  • Place of Presentation: Nanjing, China(Nanjing Institute of Geography and Limnology)
  • Year and Date: 20070917-21
• [Presentation] モンモリロナイト粒子のアスペクト比と水分散液の粘度との関係 (2007)
  • Author(s): 鈴木啓三、佐藤努、米田哲朗
  • Organizer: 第51回粘土科学討論会
  • Place of Presentation: 札幌(北海道大学)
  • Year and Date: 20070912-14
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] フミン酸をコーティングした鉱物へのフェナントレンの吸着とその後の安定性 (2007)
  • Author(s): 蒲生真也、佐藤努、玉村修司、米田哲朗
  • Organizer: 第51回粘土科学討論会
  • Place of Presentation: 札幌(北海道大学)
  • Year and Date: 20070912-14
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] 相対湿度制御下における鉱物粒子に伴われるPAHsの安定性 (2007)
  • Author(s): 玉村修司, 佐藤努, 大田由貴恵, 蒲生真也, 弘山郁織, 米田哲朗
  • Organizer: 第51回粘土科学討論会
  • Place of Presentation: 札幌(北海道大学)
  • Year and Date: 20070912-14
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] Long-range transport of fluoride from the Asian Continent to Japan (2007)
  • Author(s): Yang, X. -Y., Yamada, M., Tang, N., Kameda, T., Toriba, A., Hayakawa, K.
  • Organizer: 第48回大気環境学会年会
  • Place of Presentation: 岡山(岡山理科大学)
  • Year and Date: 20070905-07
• [Presentation] Isomer Profile of PCDDs and Dioxin-Like PCBs in Sediment from Kahokugata Lagoon and Inflowng Rivers, Japan (2007)
  • Author(s): Kakimoto, H., Oka, H., Noguchi, K., Tsukabayashi, H., Tang, N., Toriba, A., Kizu, R., Hayakawa, K.
  • Organizer: DIOXIN 2007
  • Place of Presentation: Tokyo, Japan(Hotel Okura)
  • Year and Date: 20070902-07
• [Presentation] Long-Range Transport of Fluoride from China to Japan (2007)
  • Author(s): Yang, X-Y., Yamada, M., Tang, N., Kameda, T. Toriba, A., Hayakawa, K.
  • Organizer: 5th Asian Aerosol Conference
  • Place of Presentation: Kaohsiung, Taiwan(Tuntex Sky Tower)
  • Year and Date: 20070826-29
• [Presentation] Late Cenozoic Hydro-Climatic Changes Inferred from Lake Baik al Sediment (2007)
  • Author(s): S. Ochiai and K. Kashiwaya
  • Organizer: 6th International Symposium on Terrestrial Environmental Changes in East Eurasia and Adjacent Areas
  • Place of Presentation: Russia Irkutsk-Listvyanka(Pribaikalskaya Hotel)
  • Year and Date: 20070824-28
• [Presentation] Stability of polycyclic aromatic hydrocarbons(PAHs)on mineral surfaces (2007)
  • Author(s): Shuji Tamamura, Tsutomu Sato, Yukie Ota, Shinya Gamou and Tetsuro Yoneda
  • Organizer: EUROCLAY 2007
  • Place of Presentation: Aveiro, Portugal(University of Aveiro)
  • Year and Date: 20070721-27
• [Presentation] Combined effects of pH, temperature and deviation from equilibrium on dissolution rate of smectite under alkaline conditions (2007)
  • Author(s): Tsutomu Sato, Yusuke Otani, Hideki Takayama, Sshingo Yokoyama and Testuro Yoneda
  • Organizer: EUROCLAY 2007
  • Place of Presentation: Aveiro, Portugal(University of Aveiro)
  • Year and Date: 20070721-27
• [Presentation] 湖沼-流域系における地表過程と環境変動 (2007)
  • Author(s): 柏谷健二
  • Organizer: 日本地球惑星科学連合2007年大会
  • Place of Presentation: 千葉(幕張メッセ国際会議場)
  • Year and Date: 20070520-25
  • Description: 「研究成果報告書概要(和文)」より
• [Presentation] Atmospheric behaviors of polycyclic aromatic hydrocarbons and nitropoly cycllc aromatic hydrocarbons in East Asia (2007)
  • Author(s): Hayakawa, K., Tang, N., Kameda, T. Toriba, A.
  • Organizer: The 2007 Environmental Societies Joint Conference
  • Place of Presentation: Busan, Korea(Busan BEXCO: Busan Exhibition and Convention Center)
  • Year and Date: 20070502-04
• [Presentation] Hydro-environmental fluctuations around Lake Biwa during the east 2000 years (2007)
  • Author(s): T. Itono and K. Kashiwaya
  • Organizer: Taiwan and Japan Joint Symposium on Geomornhological Hazards and Management
  • Place of Presentation: Taiwan(National Taiwan University)
  • Year and Date: 20070317-22
• [Presentation] Kinetics study on montmorillonite dissolution in high pH cement reaching solution (2007)
  • Author(s): Shingo Yokoyama, Tsutomu Sato, Kunihiko Nakamura, Yukihisa Tanaka, Michihiko Hironaga, Tomoyuki Tani, Kazuhito Niwase
  • Organizer: Asia Pacific Workshop on Sustainable Energy & Materails(APWSEM)
  • Place of Presentation: Ishigaki, Okinawa(Nobumoto Ohama Memorial Hall)
  • Year and Date: 2007-11-01
• [Presentation] Effect of deviation from equilibrium on dissolution rate of smectite under hyperalkaline condition (2007)
  • Author(s): Tsutomu Sato, Yusuke Otani, Hideki Takayama, Shingo Yokoyama, Chie Oda, Akir a Honda, Tetsuro Yoneda
  • Organizer: Clays in Natural & Engineered Barriers for Radioactive Waste Confinement
  • Place of Presentation: Lille, France(Lille Grand Palais)
  • Year and Date: 2007-09-19
• [Book] 粘土ハンドブック (2008)
  • Author(s): 佐藤努
  • Publisher: 技報堂(印刷中)
  • Description: 「研究成果報告書概要(和文)」より
• [Book] 黄砂を構成する鉱物粒子表面の特性と分析、黄砂 (2008)
  • Author(s): 佐藤努, 玉村修司
  • Publisher: 古今書院(印刷中)