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2008 Fiscal Year Final Research Report

Studies onreactions ofmetals with small molecules:From metalatoms towards metal clusters

Research Project

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Project/Area Number 17350012
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

XU Qiang  National Institute of Advanced Industrial Science and Technology, ナノテクノロジー研究部門, 主任研究員 (50357232)

Co-Investigator(Kenkyū-buntansha) TSUMORI Nobuko  独立行政法人 国立高等専門学校機構 富山工業高等専門学校, 一般科目, 准教授 (20390437)
Project Period (FY) 2005 – 2008
Keywords化学物理 / 無機化学 / 錯体化学 / 分子構造 / 反応動力学 / 金属クラスター / 赤外分光 / マトリックス単離
Research Abstract

本研究では、高感度レーザーアブレーション希ガスマトリックス単離赤外分光測定と理論化学計算を組み合わせて、周期表の広範にわたる金属と小分子との反応を系統的に調べ、一連の新しい金属化合物種の形成を見出した。特に、従来観測が困難であった金属クラスター化合物を発見し、金属クラスター上での小分子の活性化・解離過程を明らかにし、これらの小分子が関与する、関連金属触媒における触媒反応機構の解明に重要な情報を得た。

  • Research Products

    (45 results)

All 2009 2008 2007 2006 2005 Other

All Journal Article (28 results) (of which Peer Reviewed: 28 results) Presentation (17 results)

  • [Journal Article] Matrix Infrared Spectroscopic and Theoretical Studies on the Reactions of Late Lanthanoid Atoms with Nitrous Oxide in Excess Argon2009

    • Author(s)
      Ling Jiang, Qiang Xu
    • Journal Title

      J. Phys. Chem. A 113(13)

      Pages: 3121-3126

    • Peer Reviewed
  • [Journal Article] Matrix Isolation Infrared Spectroscopic and Density Functional Theory Studies on the Reactions of Dysprosium Hydride with Carbon Monoxide2008

    • Author(s)
      Yun-Lei Teng, Qiang Xu
    • Journal Title

      Bull. Chem. Soc. Jpn 81(12)

      Pages: 1575-1579

    • Peer Reviewed
  • [Journal Article] Density functional theory study of the interaction of carbon monoxide with the second-row transition-metal dimers2008

    • Author(s)
      Ling Jiang, Qiang Xu
    • Journal Title

      Chem. Phys 354(1-3)

      Pages: 32-37

    • Peer Reviewed
  • [Journal Article] Matrix Isolation Infrared Spectroscopic and Density Functional Theoretical Studies on the Reactions of Lanthanum Atoms with Acetylene2008

    • Author(s)
      Yun-Lei Teng, Qiang Xu
    • Journal Title

      J. Phys. Chem. A 112(41)

      Pages: 10274-10279

    • Peer Reviewed
  • [Journal Article] Matrix Infrared Spectroscopic and Theoretical Studies on the Reactions of Early Lanthanoid Atoms with Nitrous Oxide in Excess Argon2008

    • Author(s)
      Ling Jiang, Qiang Xu
    • Journal Title

      J. Phys. Chem. A 112(37)

      Pages: 8690-8696

    • Peer Reviewed
  • [Journal Article] Matrix Isolation Infrared Spectroscopic and Density Functional Theory Studies on the Reactions of Yttrium and Lanthanum Hydrides with Dinitrogen2008

    • Author(s)
      Yun-Lei Teng, Qiang Xu
    • Journal Title

      J. Phys. Chem. A 112(33)

      Pages: 7594-7599

    • Peer Reviewed
  • [Journal Article] Infrared Spectroscopic and Density Functional Theory Studies on the Reactions of Yttrium and Lanthanum Atoms with Nitrous Oxide in Solid Argon2008

    • Author(s)
      Ling Jiang, Qiang Xu
    • Journal Title

      .Phys. Chem. A 112(28)

      Pages: 6289-6294

    • Peer Reviewed
  • [Journal Article] Unique Structural Trends in the Lanthanoid Oxocarbonyl Complexes2008

    • Author(s)
      Ling Jiang, Xin-Bo Zhang, Song Han, and Qiang Xu
    • Journal Title

      Inorg. Chem 47(11)

      Pages: 4826-4831

    • Peer Reviewed
  • [Journal Article] Matrix Isolation Infrared Spectroscopic Studies and Density Functional Theory Calculations of the MNN, (MN)2 (M=Y, La) and Y3NN molecules2008

    • Author(s)
      Yun-Lei Teng, Qiang Xu
    • Journal Title

      J. Phys. Chem. A 112(16)

      Pages: 3607-3613

    • Peer Reviewed
  • [Journal Article] Theoretical study of the interaction of carbon monoxide with 3d metal dimers2008

    • Author(s)
      Ling Jiang and Qiang Xu
    • Journal Title

      J. Chem. Phys 128(12)124317

    • Peer Reviewed
  • [Journal Article] Matrix Isolation Infrared Spectroscopic and Density Functional Theory Studies on the Reactions of Yttrium and Lanthanum Hydrides with Carbon Monoxide2007

    • Author(s)
      Yun-Lei Teng, Qiang Xu
    • Journal Title

      J. Phys. Chem. A 111(51)

      Pages: 13380-13386

    • Peer Reviewed
  • [Journal Article] Matrix-Isolation Infrared Spectroscopic and Density Functional Theory Studies on Reactions of Laser-Ablated Lead and Tin Atoms with Water Molecules2007

    • Author(s)
      Yun-Lei Teng, Ling Jiang, Song Han, Qiang Xu
    • Journal Title

      Bull. Chem. Soc. Jpn 80(11)

      Pages: 2149-2156

    • Peer Reviewed
  • [Journal Article] Infrared Spectroscopic and Density Functional Theory Study on the Reactions of Rhodium and Cobalt Atoms with Carbon Dioxide in Rare-Gas Matrices2007

    • Author(s)
      Ling Jiang, Yun-Lei Teng, and Qiang Xu
    • Journal Title

      J. Phys. Chem. A 111(32)

      Pages: 7793-7799

    • Peer Reviewed
  • [Journal Article] Matrix-Isolation Infrared Spectroscopic and Theoretical Studies on Reactions of Laser-Ablated Germanium Atomswith Water Molecules2007

    • Author(s)
      Yun-Lei Teng, Ling Jiang, Song Han, Qiang Xu
    • Journal Title

      J. Phys. Chem. A 111(28)

      Pages: 6225-6231

    • Peer Reviewed
  • [Journal Article] Infrared Spectroscopic and Density Functional Theory Study on the Reactions of Lanthanum Atoms with Carbon Dioxide in Rare-Gas Matrices2007

    • Author(s)
      Ling Jiang and Qiang Xu
    • Journal Title

      J. Phys. Chem. A 111(18)

      Pages: 3519-3525

    • Peer Reviewed
  • [Journal Article] Reactions of Laser-Ablated La and Y Atoms with CO:Matrix Infrared Spectra and DFT Calculations of the M(CO)x and MCO+ (M = La, Y; x = 1-4) Molecules2007

    • Author(s)
      Ling Jiang and Qiang Xu
    • Journal Title

      J. Phys. Chem. A 111(17)

      Pages: 3271-3277

    • Peer Reviewed
  • [Journal Article] Infrared Spectroscopic and Theoretical Studies on the Reactions of Copper Atoms with Carbon Monoxide and Nitric Oxide Molecules inRare-gas Matrices2007

    • Author(s)
      Ling Jiang and Qiang Xu
    • Journal Title

      J. Phys. Chem. A 111(14)

      Pages: 2690-2696

    • Peer Reviewed
  • [Journal Article] Infrared Spectra of the M(NO)n (M = Sn, Pb; n = 1, 2) and PbNO- Molecules2006

    • Author(s)
      Qiang Xu, Ling Jiang
    • Journal Title

      Inorg. Chem 45(21)

      Pages: 8648-8654

    • Peer Reviewed
  • [Journal Article] Infrared Spectra of the (AgCO)2 and AgnCO (n = 2-4) Molecules in Rare-Gas Matrices2006

    • Author(s)
      Ling Jiang and Qiang Xu
    • Journal Title

      J. Phys. Chem. A 110(40)

      Pages: 11488-11493

    • Peer Reviewed
  • [Journal Article] Infrared Spectroscopic and Density Functional Theory Studies on the Reactions of Zinc and Cadmium Atoms with Ammonia2006

    • Author(s)
      Ling Jiang, Qiang Xu
    • Journal Title

      Bull. Chem. Soc. Jp 79(10)

      Pages: 1519-1524

    • Peer Reviewed
  • [Journal Article] Reactions of the small Tin clusters with carbon monoxide: Infrared spectra and DFT calculations of the SnnCO (n = 2-5) and Sn2(CO)2 molecules in solid argon2006

    • Author(s)
      Ling Jiang, Qiang Xu
    • Journal Title

      Bull. Chem. Soc. Jp 79(6)

      Pages: 857-863

    • Peer Reviewed
  • [Journal Article] Reactions of Laser-Ablated Zinc and Cadmium Atoms with CO: Infrared Spectra of the Zn(CO)x (x = 1-3), CdCO-, and Cd(CO)2 Molecules in Solid Neon2006

    • Author(s)
      Ling Jiang, Yun-Lei Teng, Qiang Xu
    • Journal Title

      J. Phys. Chem. A 110(22)

      Pages: 7092-7096

    • Peer Reviewed
  • [Journal Article] Infrared Spectroscopic and Density Functional Theory Studies on the CO Dissociation by Scandium and Yttrium Dimers2006

    • Author(s)
      Ling Jiang, Qiang Xu
    • Journal Title

      J. Phys. Chem. A 110(17)

      Pages: 5636-5641

    • Peer Reviewed
  • [Journal Article] Infrared Spectroscopic and Density-Functional-Theory Investigations of the LaCO, La2[η2(μ2-C, O)], and c-La2(μ-C)(μ-O) Molecules in Solid Argon2006

    • Author(s)
      Qiang Xu, Ling Jiang, Ru-Qiang Zou
    • Journal Title

      Chem. Eur. J 12(12)

      Pages: 3226-3232

    • Peer Reviewed
  • [Journal Article] Oxidation of Carbon Monoxide on Group 11 Metal Atoms:Matrix-Isolation Infrared Spectroscopic and Density Functional Theory Study2006

    • Author(s)
      Qiang Xu, Ling Jiang
    • Journal Title

      J. Phys. Chem. A 110(8)

      Pages: 2655-2662

    • Peer Reviewed
  • [Journal Article] Infrared Spectroscopic and Density Functional Theory Studies on the Reactions of Cadmium Atoms with Carbon Monoxide in Solid Argon2005

    • Author(s)
      Ling Jiang, Qiang Xu
    • Journal Title

      J. Phys. Chem. A 109(40)

      Pages: 9001-9005

    • Peer Reviewed
  • [Journal Article] Experimental and Theoretical Evidence for the Formation of Zinc Tricarbonyl in Solid Argon2005

    • Author(s)
      Ling Jiang, Qiang Xu
    • Journal Title

      J. Am. Chem. Soc 127(25)

      Pages: 8906-8907

    • Peer Reviewed
  • [Journal Article] Reactions of Rhodium and Ruthenium Atoms with Nitrous Oxide: A Combined Matrix Infrared Spectroscopic and Theoretical Study

    • Author(s)
      Ling Jiang, Qiang Xu
    • Journal Title

      J. Phys. Chem. A, in press

      Pages: 0

    • Peer Reviewed
  • [Presentation] Matrix isolation infrared spectroscopic studies of lanthanide complexes2009

    • Author(s)
      Qiang Xu
    • Organizer
      The 2009 Gordon Conference on the Physics and Chemistry of Matrix Isolated Species
    • Place of Presentation
      Magdalen College, Oxford, UK
    • Year and Date
      2009-07-19
  • [Presentation] 金属クラスターへのCO のSide-on 結合形成とCOの活性化2008

    • Author(s)
      江 凌, 滕雲雷, 徐強
    • Organizer
      平成20年度第2回キャタリストクラブ例会 第1回触媒表面化学研究発表会
    • Place of Presentation
      関西大学
    • Year and Date
      2008-10-31
  • [Presentation] 金クラスターとNO との反応の研究2008

    • Author(s)
      滕雲雷, 江 凌, 徐強
    • Organizer
      平成20年度第2回キャタリストクラブ例会 第1回触媒表面化学研究発表会
    • Place of Presentation
      関西大学
    • Year and Date
      2008-10-31
  • [Presentation] 金属クラスターへのCO のSide-on 結合形成とCO の活性化2008

    • Author(s)
      江 凌, 滕雲雷, 徐強
    • Organizer
      第2回分子科学討論会2008
    • Place of Presentation
      福岡
    • Year and Date
      2008-09-27
  • [Presentation] レーザーアブレーションマトリックス単離赤外分光法による金クラスターとNO との反応の研究2008

    • Author(s)
      滕雲雷, 江 凌, 徐強
    • Organizer
      第2回分子科学討論会2008
    • Place of Presentation
      福岡
    • Year and Date
      2008-09-27
  • [Presentation] レーザーアブレーションマトリックス単離赤外分光法によるイットリウムとランタンの水素化物とCO との反応の研究2008

    • Author(s)
      滕雲雷, 徐 強
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      東京
    • Year and Date
      2008-03-26
  • [Presentation] INFRARED SPECTROSCOPIC AND DENSITY FUNCTIONAL THEORY STUDIES ON THE REACTIONS OF SMALL METAL CLUSTERS WITH CARBON MONOXIDE IN RARE-GAS MATRICES2007

    • Author(s)
      Ling Jiang, Qiang Xu
    • Organizer
      41st IUPAC CONGRESS
    • Place of Presentation
      Torino, Italy
    • Year and Date
      20070805-10
  • [Presentation] Recent developments in metal carbonyl chemistry: An approach frommatrix isolation infrared spectroscopy2007

    • Author(s)
      Qiang Xu
    • Organizer
      The 3rd Nanjing-Hokkaido University Joint Symposium on Progress in advanced chemistry
    • Place of Presentation
      Nanjing, China
    • Year and Date
      2007-11-21
  • [Presentation] レーザーアブレーションマトリックス単離赤外分光法による第14族金属と水との反応の研究2007

    • Author(s)
      滕雲雷, 江凌, 徐 強
    • Organizer
      日本化学会第87春季年会
    • Place of Presentation
      吹田
    • Year and Date
      2007-03-27
  • [Presentation] レーザーアブレーションマトリックス単離赤外分光法による金属クラスターとCO の反応の研究2007

    • Author(s)
      江 凌, 滕雲雷, 徐強
    • Organizer
      日本化学会第87春季年会
    • Place of Presentation
      吹田
    • Year and Date
      2007-03-25
  • [Presentation] Reactions of Gold Atoms and Small Clusters with CO and CO/O2: Matrix-isolation Infrared Spectroscopic and Theoretical studies2006

    • Author(s)
      Qiang Xu
    • Organizer
      International Conference on the Science, Technology and Industrial Applications of Gold (Gold 2006)
    • Place of Presentation
      Limerick, Ireland
    • Year and Date
      2006-09-04
  • [Presentation] レーザーアブレーションマトリックス単離赤外分光法による第11 族金属原子によるCO 酸化反応の研究2006

    • Author(s)
      江 凌, 徐 強
    • Organizer
      日本化学会第86春季年会
    • Place of Presentation
      船橋
    • Year and Date
      2006-03-28
  • [Presentation] 赤外分光法による新しい金属カルボニル化合物に関する研究2006

    • Author(s)
      徐 強, 江凌
    • Organizer
      日本化学会第86春季年会
    • Place of Presentation
      船橋
    • Year and Date
      2006-03-28
  • [Presentation] Experimental and Theoretical Evidence for the Formation of [c-Ag3(μ-CO)3]+: A Cyclic CO-bridged Trisilver Cluster Cation2005

    • Author(s)
      Ling Jiang, Qiang Xu
    • Organizer
      PACIFICHEM 2005
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      20051200
  • [Presentation] Reactions of Zn Atoms with CO: Experimental and Theoretical Characterization of Unprecedented Zinc Tricarbonyl Zn(CO)3 in Solid Argon2005

    • Author(s)
      Ling Jiang, Qiang Xu
    • Organizer
      PACIFICHEM 2005
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      20051200
  • [Presentation] Recent developments in metal carbonyl chemistry2005

    • Author(s)
      Qiang Xu, Ling Jiang
    • Organizer
      9th National Meeting of Chemical Reaction Kinetics
    • Place of Presentation
      Hangzhou, China
    • Year and Date
      20050900
  • [Presentation] Reactions of Zn Atoms with CO: Experimental and Theoretical Characterization of Zinc Tricarbonyl in Solid Argon2005

    • Author(s)
      Ling Jiang, Qiang Xu
    • Organizer
      9th National Meeting of Chemical Reaction Kinetics
    • Place of Presentation
      Hangzhou, China
    • Year and Date
      20050900

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Published: 2010-06-10   Modified: 2016-04-21  

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