2006 Fiscal Year Final Research Report Summary
Chemical analyses of gas hydrate-bearing marine sediments to study natural methane hydrate formation
| Project/Area Number |
17550069
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Analytical chemistry
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| Research Institution | Kitami Institute of Technology |
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Principal Investigator |
MINAMI Hirotsugu Kitami Institute of Technology, Instrumental Analysis Center, Associate Professor, 機器分析センター, 助教授 (40241426)
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| Co-Investigator(Kenkyū-buntansha) |
TAKAHASHI Nobuo Kitami Institute of Technology, Department of Materials Sciences, Professor, 工学部・機能材料工学科, 教授 (20108187)
HACHIKUBO Akihiro Kitami Institute of Technology, New Energy Resources Research Center., Associate Professor, 未利用エネルギー研究センター, 助教授 (50312450)
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| Project Period (FY) |
2005 – 2006
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| Keywords | Methane Hydrates / Marine Sediments / Sakhalin / Pore Water / Chemical analyses / オホーツク海 / バイカル湖 |
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| Research Abstract |
The CHAOS (hydro-Carbon Hydrate Accumulations in the Okhotsk Sea) cooperative project organized by Kitami Institute of Technology (KIT, Japan), All Russia Research Institute. for Geology and Mineral Resources of the Ocean (Russia), Korea Polar Research Institute (Korea), V. I. I1'ichev Pacific Oceanological Institute FEB RAS (Russia), Limnological Institute SB RAS (Russia), and Renard Centre of Marine Geology, Ghent University (Belgium) with the aim of the natural gas hydrate studies at the Okhotsk Sea was conducted in 2005 and 2006. The core sampling areas were located offshore Sakhalin Island, Russia.
The gas hydrate-bearing, gas hydrate-free and reference marine sediments were retrieved from the bottom of the Okhotsk Sea by using gravity-and hydro-corers.
The pore water samples were obtained by a squeezer designed and constructed at KIT. Determination of ions such as sulfate, sodium etc. in the pore water was carried out by ion chromatography, inductively coupled plasma atomic emission spectrometry and flame atomic absorption spectrometry. Stable isotope ratios such as 6180 and 6D of the water samples including dissociated methane hydrate water were measured by a mass spectrometer.
Discharging of deeper sourced water was not observed based on ion analyses at the gas hydrate-bearing cores. The b180 value of the hydrate water was up to +1.4% heavier than that of the seawater obtained at 5 m above the sea floor of the studied area. These results suggested the two distinct possibilities for the main gas hydrate-forming fluids, i.e., (i) not only free gas was expulsed but also the water with light 6180 was discharged and it was the main gas hydrate-forming fluid and (ii) seawater was the main gas hydrate-forming fluid since only free gas was expulsed without any ascending fluid at the gas seepage structures.
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Research Products
(41 results)
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[Journal Article] Coexistence of structure I and II gas hydrates in Lake Baikal suggesting gas sources from microbial and thermogenic origin2007
Author(s)
Masato Kida, Oleg Khlystov, Tamara Zemskaya, Nobuo Takahashi, Hirotsugu Minami, Hirotoshi Sakagami, Alexey Krylov, Akihiro Hachikubo, Satoshi Yamashita, Hitoshi Shoji, Jeffrey Poort, Lieven Naudts
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Journal Title
Geophys.Res.Lett. 33
Pages: L24603
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Sediments and Authigenic Carbonates Related to Gas-Hydrates in the Sea of Okhotsk : First Results from the CHAOS 2005 Expedition2007
Author(s)
A.Krylov, L.Mazurenko, A.Hachikubo, H.Minami, E.Logvina, N.Nikolaeva, M.Kida, Y.Nunokawa, S.Nishio, A.Obzhirov, Y.Jin, J.Poort, H.Shoji
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Journal Title
Gas Hydrates for the Future Energy and Environment(eds.H.Tsunemoto, H.Shoji, S.Yamashita)(Kitami Institute of Technology, Kitami, Japan)
Pages: 49-54
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Field Investigation of Natural Methane Hydrates at Lake Baikal, Autumn 20052007
Author(s)
H.Minami, A.Hachikubo, S.Yamashita, A.Krylov, S.Kataoka, S.Nishio, T.Yokoyama, M.Hyodo, 0.Khlystov, M.Grachev, H.Shoji
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Journal Title
Gas Hydrates for the Future Energy and Environment(eds.H.Tsunemoto, H.Shoji, S.Yamashit)(Kitami Institute of Technology, Kitami, Japan)
Pages: 55
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Chemical Analysis of Sediment Cores Offshore Sakhalin, Okhotsk Sea2007
Author(s)
H.Minami, J.Bai, H.Sakagami, A.Hachikubo, K.Hyakutake, K.Abe, T.Konno, N.Kimura, A.Nishide, Y.Todome, L.Mazurenko, T.Matveeva, N.Takahashi, A.Obzhirov, V.Soloviev, H.Shoji
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Journal Title
Gas Hydrates for the Future Energy and Environment(eds.H.Tsunemoto, H.Shoji, S.Yamashita)(Kitami Institute of Technology, Kitami, Japan)
Pages: 57-59
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Hydration Number Determinations of Natural Gas Hydrates Using 13C-NMR2007
Author(s)
M.Kida, H.Sakagami, H.Minami, N.Takahashi, K.Hyakutake, A.Hachikubo, H.Shoji, S.Takeya, Y.Kamata, T.Ebinuma, H.Narita, V.Soloviev, 0.Khlystov, M.Grachev
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Journal Title
Gas Hydrates for the Future Energy and Environment, eds. ti. Tsunemoto, H. Shoji and S. Yamashita, Kitami Institute of Technology, Kitami, Japan
Pages: 97-102
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] A Video-Camera Device for Small Bubble Observations in Deep Water near Gas Hydrate Accumulation2007
Author(s)
K.Hyakutake, 0.Kitamura, H.Sakagami, H.Minami, K.Abe, A.Hachikubo, H.Shoji, V.Soloviev, A.Obzhirov, Y.Jin
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Journal Title
Gas Hydrates for the Future Energy and Environment(eds.H.Tsunemoto, H.Shoji, S.Yamashita)(Kitami Institute of Technology, Kitami, Japan)
Pages: 193-196
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Chemical analysis of sediment cores from Lake Baikal and offshore Sakhalin, Okhotsk Sea2006
Author(s)
H.Minami, H.Sakagami, A.Hachikubo, A.Krylov, N.Takahashi, L.Mazurenko, T.Matveeva, A.Obzhirov, O.Khlystov, T.Zemskaya, Y.Jin, H.Shoji
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Journal Title
Proceedings of the International Workshop in Modern Science and Technology
Pages: 135-139
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Authigenic Carbonates Formation in the Sediments Associated with Methane Gas-Hydrates (Sea of Okhotsk)2006
Author(s)
A.Krylov, L.Mazurenko, E.Logvina, N.Nikolaeva, A.Hachikubo, M.Kida, H.Minami, N.Takahashi, A.Obzhirov, Y.Jin, H.Shoji
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Journal Title
Proceedings of the International Workshop in Modern Science and Technology
Pages: 116-119
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Structure and thermal expansion of natural gas clathrate hydrates2006
Author(s)
S.Takeya, M.Kida, H.Minami, H.Sakagami, A.Hachikubo, N.Takahashi, H.Shoji, V.Soloviev, K.Wallmann, N.Biebow, A.Obzhirov, A.Salomatin, J.Poort
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Journal Title
Chem.Eng.Sci. 61
Pages: 2670-2674
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Some ion concentration profiles in pore water samples fro gas hydrate-bearing sediments offshore Sakhalin2005
Author(s)
H.Minami, H.Sakagami, A.Hachikubo, K.Hyakutake, K.Abe T.Konno, N.Takahashi, H.Shoji, L.Mazurenko, T.Matveeva, V.Soloviev, A.Obzhirov
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Journal Title
Proceedings of the Fifth International Conference on Gas Hydrates 3
Pages: 1049-1051
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] CP-MAS 13C-NMR study on the crystallographic structure o natural gas hydrate2005
Author(s)
M.Kida, H Sakagami, H.Minami, Y.Nunokawa, N.Takahashi T.Matveeva, A.Hachikubo, H.Shoji, S.Takeya, Y.Kamata T.Ebinuma, H.Narita, V.Soloviev, K.Wallmann, N.Biebow, A.Obzhirov, A.Salomatin, J.Poort
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Journal Title
Proceedings of the Fifth International Conference on Gas Hydrates 2
Pages: 497-501
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Measurement of some ionic concentration in pore water samples from LV32 marine sediment cores offshore Sakhalin, Russia2005
Author(s)
H.Minami, H.Sakagami, A.Hachikubo, K.Hyakutake, K.Abe, T.Konno, N.Kimura, A.Nishide, Y.Todome, N.Takahashi, H.Shoji, V.A.Soloviev, A.I.Obzhirov
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Journal Title
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Lattice Expansion of Clathrate Hydrates of Methane Mixtures and Natural Gas.2005
Author(s)
S.Takeya, Uchida, T., Kamata Y., Nagao, J., Kida, M., Minami, H., Sakagami, H., Hachikubo, A., Takahashi, N., Shoji, H., Khlystov, 0., Grachev, M., Soloviev, V.
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Journal Title
Angew.Chem.Int.Ed. 44
Pages: 2-6
Description
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