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2007 Fiscal Year Final Research Report Summary

Growth of conductive suboxide films and the study of the functionalities of the films

Research Project

Project/Area Number 17550139
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials chemistry
Research InstitutionRikkyo University

Principal Investigator

EDAMOTO Kazuyuki  Rikkyo University, Faculty of Science, Professor (80185123)

Project Period (FY) 2005 – 2007
KeywordsThin film / Suboxide / Single-crystal epitaxy / Angle-resolved photoemission spectroscopy / Resonant photoemission spectroscopy
Research Abstract

Ti monoxide(TiO) has attracted much attention in recent years because it is predicted to have an interesting combination of useful properties such as extreme hardness, a high melting point and metallic conductivity. However, very limited information has been obtained as to the physical and chemical properties of TiO, because it is difficult to synthesize the single-crystal under an atmospheric condition. The aim of this study is to synthesize the TiO single-crystal film by Ti deposition onto Ag(100) in an O_2 atmosphere.
It was found that the TiO_2 film with a(5×1) periodicity is formed by Ti deposition on Ag(100) in O_2 at 10^<-5>-10^<-7> Torr and subsequent annealing at 600℃. On the other hand, the TiO fihn with a(1×1) periodicity was formed by Ti deposition in 02 at 10^<-8>-3×10^<-9> Ibrr and subsequent annealing at 600℃. Therefore, it is concluded that the TiO_2 and TiO films can be selectively formed on Ag(100) by the control of the O_2 pressure during the deposition.
The electronic structure of the TiO film on Ag(100) was investigated by angle-resolved photoemission spectroscopy. The conduction band and the valence band were found at 0-2 eV and 4-8 eV, respectively. Resonant photoemission measurements showed that the spectral intensity of the conduction band exhibits the resonant behavior characteristic of the Ti 3d photoionization cross section, suggesting that the band is mostly composed of Ti 3d component. The two-dimensional band structure was measured, and it was found that the conduction band includes partially filled metallic states. The overall results are compatible with the results of previous theoretical band-calculations for the TiO crystal.

  • Research Products

    (18 results)

All 2008 2007 2006

All Journal Article (4 results) (of which Peer Reviewed: 2 results) Presentation (14 results)

  • [Journal Article] Growth of ordered titanium oxide films on Ag(100)2007

    • Author(s)
      H.Kaneko, et. al.
    • Journal Title

      Solid State Communications 142

      Pages: 32-35

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Angle-resolved and resonant photoemission study of the ZrO-like film on ZrC(100)2007

    • Author(s)
      K.Edamoto, et. al.
    • Journal Title

      Surface Science 601

      Pages: 5077-5082

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Growth of ordered titanium oxide films on Ag(100)2007

    • Author(s)
      H. Kaneko, M. Ono, K. Ozawa, K. Edamoto
    • Journal Title

      Solid State Communications 142

      Pages: 32-35

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Angle-resolved and resonant photoemission study of the ZrO-like film on ZrC(100)2007

    • Author(s)
      K. Edamoto, T. Nagayama, K. Ozawa, S. Otani
    • Journal Title

      Surface Science 601

      Pages: 5077-5082

    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] 角度分解光電子分光によるTiO/Ag(100)超薄膜の電子状態2008

    • Author(s)
      金 子誉、田中 優、今村 賢司、枝元 一之、小澤 健一
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      立教大学
    • Year and Date
      20080326-30
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Angle-resolved photoemission study of the TiO(100) film on Ag(100)2008

    • Author(s)
      H. Kaneko, M. Tanaka, K. Imamura, K. Edamoto, K. Ozawa
    • Organizer
      88th Spring Meeting of the Chemical Society of Japan
    • Place of Presentation
      Tokyo
    • Year and Date
      20080326-30
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Ag(100)上に作成したTiO(100)超薄膜の角度分解光電子分光2007

    • Author(s)
      金 子誉
    • Organizer
      第3回放射光表面科学部会シンポジウム
    • Place of Presentation
      東京大学
    • Year and Date
      20071204-05
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Angle-resolved photoemission study of the TiO(100) film on Ag(100)2007

    • Author(s)
      H. Kaneko
    • Organizer
      3rd Symposium on SR Surface Science
    • Place of Presentation
      Tokyo
    • Year and Date
      20071204-05
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] ZrC(100)面上に作成したZrO薄膜の共鳴光電子分光2007

    • Author(s)
      永山 隆博、枝元 一之、小澤 健一
    • Organizer
      第27回表面科学講演大会
    • Place of Presentation
      東京大学生産研
    • Year and Date
      20071101-03
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Resonant photoemission study of the ZrO film on ZrC(100)2007

    • Author(s)
      T. Nagayama, K. Edamoto, K. Ozawa
    • Organizer
      27th Annual Meeting of the Surface Science Society of Japan
    • Place of Presentation
      Tokyo
    • Year and Date
      20071101-03
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Photoelectron spectroscopy study of the ordered titanium oxide films on Ag(100)2007

    • Author(s)
      H.Kaneko, K.Edamoto, K.Ozawa, M.Ono
    • Organizer
      The 15th International Conference on Vacuum Ultraviolet Radiation Physics
    • Place of Presentation
      Berlin,Germany
    • Year and Date
      20070729-0803
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Resonant photoemission study of the electronic structure of the ZrO(100)thin film on ZrC(100)2007

    • Author(s)
      T.Nagayama, K.Edamoto, K.Ozawa
    • Organizer
      The 15th International Conference on Vacuum Ultraviolet Radiation Physics
    • Place of Presentation
      Berlin,Germany
    • Year and Date
      20070729-0803
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Photoelectron spectroscopy study of the ordered titanium oxied films on Ag(100)2007

    • Author(s)
      H. Kaneko, K. Edamoto, K. Ozawa, M. Ono
    • Organizer
      The 15th International Conference on Vacuum Ultraviolet Radiation Physics
    • Place of Presentation
      Berlin Bermany
    • Year and Date
      20070729-0803
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Resonant photoemission study of the electronic structure of the ZrO(100) thin film on ZrO(100)2007

    • Author(s)
      T. Nagayama, K. Edamoto, K. Ozawa
    • Organizer
      The 15th International Conference on Vacuum Ultraviolet Radiation Physics
    • Place of Presentation
      Berlin Bermany
    • Year and Date
      20070729-0803
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Ag(100)上におけるチタン酸化物超薄膜の研究2006

    • Author(s)
      金 子誉、小野 真梨江、枝元 一之、小澤 健一
    • Organizer
      第26回表面科学講演大会
    • Place of Presentation
      大阪大学
    • Year and Date
      20061106-09
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] ZrC(100)面上に作成したZrO(100)薄膜の電子状態2006

    • Author(s)
      枝元 一之、永山 隆博、小澤 健一
    • Organizer
      第26回表面科学講演大会
    • Place of Presentation
      大阪大学
    • Year and Date
      20061106-09
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Growth of ultra-thin Ti oxide films on Ag(100)2006

    • Author(s)
      H. Kaneko, K. Ono, K. Edamoto, K. Ozawa
    • Organizer
      26th Annual Meeting of the Surface Science Society of Japan
    • Place of Presentation
      Osaka
    • Year and Date
      20061106-09
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] The electronic structure of the ZrO(100) film on ZrC(100)2006

    • Author(s)
      K. Edamoto, T. Nagayama, K. Ozawa
    • Organizer
      26th Annual Meeting of the Surface Science Society of Japan
    • Place of Presentation
      Osaka
    • Year and Date
      20061106-09
    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2010-02-04  

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