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2007 Fiscal Year Final Research Report Summary

Development of ultraviolet dosimeter using microcapsules with enclosed solutions of photochromic compounds

Research Project

Project/Area Number 17560490
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Civil and environmental engineering
Research InstitutionAzabu University

Principal Investigator

MORITA Shigemitsu  Azabu University, Health and Environmental Sciences, Associate Professor (50318888)

Project Period (FY) 2005 – 2007
KeywordsUltraviolet inactivation / Distribution of dose / Photochoromic compound / Microcapsules / Flow cytometry
Research Abstract

Ultraviolet (UV) disinfection has been found to be effective even for chlorine-resistant pathogenic microbes such as Cryptosporidium. The efficacy of UV irradiation in inactivating microbes depends on the irradiation dose of UV irradiation. The methods usually used to measure the UV irradiation dose are the photospectrometer and the biodosimeter, in which microbes that are highly sensitive to UV irradiation, such as QB and Bacillus subtilis, are utilized. However, these methods enable us to measure only the average dose in the UV reactor. The minimum dose of UV irradiation, such as when a short circuit flow is generated, cannot be measured directly, and can only be estimated by computational fluid dynamics. In the present study, we encapsulated photochromic compounds, which are organic compounds that develop colors upon UV irradiation, in microcapsules, and prepared a microdosimeter whose diameter and specific gravity were identical with those of the microbes to be sterilized. We then measured the intensity of the color that was developed in individual capsules upon UV irradiation, and attempted to evaluate the distribution of the UV dose with which individual microbes were irradiated.
BMLB was found to be the most sensitive to UV irradiation among the 30 photochromic compounds, and its quenching speed was slow. Therefore, BMLB was the most suitable photochromic compound for preparing the UV dosimeter. Although the mechanism by which BLMB develops a color is complex, it is hypothesized that when BLMB is excited by UV irradiation, BLMB releases H radicals and COPh radicals, which are oxygenated and become cations, thereby developing a color. Although BLMB developed a color upon UV irradiation regardless of the solvent in which it was dissolved, the color was intense and the quenching speed was slow particularly when it was dissolved in 2-propanol (isopropyl alcohol), methanol, 2-butanone (methyl ethyl ketone), or toluene.

  • Research Products

    (32 results)

All 2008 2007 2006 2005

All Journal Article (11 results) (of which Peer Reviewed: 6 results) Presentation (16 results) Book (3 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Journal Article] Inactivation of Cryptosporidium by a combination of UV irradiation and chlorination2007

    • Author(s)
      Morita, S., Nakashima, T., Urakami, I., Iwasaki, T., Hirata. T.
    • Journal Title

      Proceedings of International Water Association ASPIRE Conference and Exhibition

      Pages: 21-29

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Quantifying the removal of pathogenic protozoa during activated sludgeprocessing2007

    • Author(s)
      Morita, S., Ishii, T., Akiba, M., Yagita, K., Kuroki, T., Katayama, H., Haramoto, E., Hirata, T.
    • Journal Title

      Proceedings of International Water Association ASPIRE Conference and Exhibition

      Pages: 114-122

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Quantitative detection of adenoviruses and sapoviruses in raw sewage and effluent2007

    • Author(s)
      Tanimoto, J., Morita, S., Haramoto, E., Katayama, H., Ito, S., Ohgaki, S., Hirata, T.
    • Journal Title

      Proceedings of International Water Association ASPIRE Conference and Exhibition

      Pages: 129-137

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Inactivation of Cryptosporidium by a combination of UV irradiation and chlorination2007

    • Author(s)
      Morita, S., Nakashima, T., Urakami, I., Iwasaki, T., Hirata, T.
    • Journal Title

      Proceedings of International Water Association ASPIRE Conference and Exhibition

      Pages: 21-29

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Quantifying the removal of pathogenic protozoa during activated sludge processing2007

    • Author(s)
      Morita, S., Ishii, T., Akiba, M., Yagita, K, Kuroki, T., Katayama, H., Haramoto, E., Hirata, T.
    • Journal Title

      Proceedings of International Water Association ASPIRE Conference and Exhibition

      Pages: 114-122

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] γ線および電子線照射によるCryptosporidium parvumオーシストの不活化効果2006

    • Author(s)
      森田重光, 平田 強
    • Journal Title

      水環境学会誌 29, 2

      Pages: 79-85

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Measurement of UV irradiation dose with the use of photochromic compounds2006

    • Author(s)
      Tanimoto, J., Morita, S., Katayama, H., Iwasaki, T., Motoyama, N.
    • Journal Title

      Proc. 7^<th> International Symposium on water supply technology

      Pages: 660-661

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Measurement of UV irradiation dose with the use of photochromic compounds2006

    • Author(s)
      Tanimoto, J., Morita, S., Katayama, H., Iwasaki, T., Motoyama, N.
    • Journal Title

      Proceedings of International Symposium on Water Supply Technology

      Pages: 660-661

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Effect of the presence of coexisting substances on UV inactivation of Cryptosporidium parvum oocysts2005

    • Author(s)
      Morita S., Hirata T.
    • Journal Title

      J. Water and Environmental Technology 3

      Pages: 33-40

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Effect of the presence of substances on UV inactivation of Cryptosporidium parvum oocysts2005

    • Author(s)
      Morita S., Hirata T.
    • Journal Title

      Journal of Water and Environment Technology 3

      Pages: 33-40

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Inactivation of Cryptosporidium parvum oocysts using gamma-ray and electron beam (In Japanese)2005

    • Author(s)
      Morita S., Hirata T
    • Journal Title

      Journal of Japan Society on Water Environment 29, 2

      Pages: 79-85

    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] 水環境における豚由来HEVの挙動に関する研究2008

    • Author(s)
      谷本惇, 森田重光, 李天成, 伊東正吾, 片山浩之, 原本英司, 武田直和, 平田強
    • Organizer
      第42回日本水環境学会
    • Place of Presentation
      名古屋
    • Year and Date
      20080300
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] CryptosporidiumおよびGiardiaの定量法に関する研究2008

    • Author(s)
      森田重光, 岩崎好夏, 小杉沙織, 石井孝明, 平田強
    • Organizer
      第42回日本水環境学会
    • Place of Presentation
      名古屋
    • Year and Date
      20080300
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Inactivation of Cryposporidium by a combination of UV irradiation and chlorination2007

    • Author(s)
      Morita, S., Nakashima, T., Urakami, I., Iwasaki, T., Hirata, T.
    • Organizer
      International Water Association ASPIRE Conference and Exhibition
    • Place of Presentation
      Parth
    • Year and Date
      20071000
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Quantifying the removal of pathogenic protozoa during activated sludge processing2007

    • Author(s)
      Morita, S., Ishii, T., Akiba, M., Yagita, K., Kuroki, T., Katayama, H., Haramoto, E., Hirata, T.
    • Organizer
      International Water Association ASPIREConference and Exhibition
    • Place of Presentation
      Parth
    • Year and Date
      20071000
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Quantitative detection of adenoviruses and sapoviruses in raw sewage and effluent2007

    • Author(s)
      Tanimoto, J., Morita, S., Haramoto, E., Katayama, H., Ito, S., Ohgaki, S ., Hirata, T.
    • Organizer
      International Water Association ASPIRE Conference and Exhibition
    • Place of Presentation
      Parth
    • Year and Date
      20071000
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Detection of HEV in swine feces and environmental waters using real-time PCR2007

    • Author(s)
      Tanimoto, J., Morita, S., Ito, M., Haramoto, E., Katayama, H., Ito, S., Sunaga, R., Arai, S., Hirata, T.
    • Organizer
      International Symposium on Health-Related Water Microbiology
    • Place of Presentation
      東京
    • Year and Date
      20070900
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] 紫外線と塩素の組み合わせ処理によるCryptosporidiumの不活化2007

    • Author(s)
      森田重光, 萩原信之介, 中嶋崇詞, 松本朋也, 平田強
    • Organizer
      第41回日本水環境学会
    • Place of Presentation
      大阪
    • Year and Date
      20070300
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] 下水処理によるCryptosporidiumおよび腸管系ウイルスの除去特性2007

    • Author(s)
      谷本惇, 石井孝明, 石川章弘, 加来健一, 森田重光, 平田強
    • Organizer
      第41回日本水環境学会
    • Place of Presentation
      大阪
    • Year and Date
      20070300
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] E型肝炎ウイルスの環境分布2007

    • Author(s)
      森田重光, 谷本惇
    • Organizer
      日本養豚開業獣医師協会セミナー
    • Place of Presentation
      相模原
    • Year and Date
      20070300
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Inactivation of Cryptosporidium by a combination of UV irradiation and chlorination2007

    • Author(s)
      Morita, S., Nakashima, T., Urakami, I., Iwasaki, T., Hirata, T.
    • Organizer
      International Water Association ASPIRE Conference and Exhibition
    • Place of Presentation
      Parth
    • Year and Date
      20070000
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Quantifying the removal of pathogenic protozoa during activated sludge processing2007

    • Author(s)
      Morita, S., Ishii, T., Akiba, M., Yagita, K., Kuroki, T., Katayama, H., Haramoto, E., Hirata, T.
    • Organizer
      International Water Association ASPIRE Conference and Exhibition
    • Place of Presentation
      Parth
    • Year and Date
      20070000
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] フォトクロミック化合物による紫外線照射線量の測定2006

    • Author(s)
      谷本惇, 森田重光
    • Organizer
      第57回全国水道研究発表会
    • Place of Presentation
      長崎
    • Year and Date
      20060500
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] 有機発色剤による紫外線照射線量の測定2006

    • Author(s)
      森田重光, 谷本惇, 平田強
    • Organizer
      第40回日本水環境学会
    • Place of Presentation
      仙台
    • Year and Date
      20060300
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] 病原性原虫の消毒技術2006

    • Author(s)
      森田重光
    • Organizer
      第51回日本水環境学会セミナー
    • Place of Presentation
      東京
    • Year and Date
      20060100
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Measurement of UV irradiation dose with the use of photochromic compounds2006

    • Author(s)
      l. Tanimoto, J., Morita, S., Katayama, H., Iwasaki, T., Motoyama, N.
    • Organizer
      International Symposium on Water Supply Technology
    • Place of Presentation
      Yokohama
    • Year and Date
      20060000
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] 紫外線のクリプトスポリジウム不活化効果2005

    • Author(s)
      森田重光, 平田強
    • Organizer
      第8回日本水環境学会シンポジウム
    • Place of Presentation
      滋賀
    • Year and Date
      20050900
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] 紫外線照射-水の消毒への適用性-2008

    • Author(s)
      分担共著
    • Total Pages
      169
    • Publisher
      技報堂
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] 水道の病原微生物対策2006

    • Author(s)
      分担共著
    • Total Pages
      255
    • Publisher
      丸善
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] 水環境ハンドブック2006

    • Author(s)
      分担共著
    • Total Pages
      760
    • Publisher
      朝倉書店
    • Description
      「研究成果報告書概要(和文)」より
  • [Patent(Industrial Property Rights)] Radiation dosimeter for fluid very small substances, and method for measuring radiation dose2008

    • Inventor(s)
      森田重光
    • Industrial Property Rights Holder
      麻布獣医学園
    • Industrial Property Number
      12/224, 994
    • Filing Date
      20080000
    • Description
      「研究成果報告書概要(和文)」より
    • Overseas
  • [Patent(Industrial Property Rights)] 微小物質用の輻射線線量計, 及び輻射線線量の測定方法2006

    • Inventor(s)
      森田重光
    • Industrial Property Rights Holder
      麻布獣医学園
    • Industrial Property Number
      特願2006-06755
    • Filing Date
      20060000
    • Description
      「研究成果報告書概要(和文)」より

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Published: 2010-06-09  

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