Chiral porphyrin complexes for sensing and asymmetric catalysis

2019 Fiscal Year Annual Research Report

• Project/Area Number: 17F17825
• Research Institution: National Institute for Materials Science
• Principal Investigator: HILL Jonathan 国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 主席研究員 (30421431)
• Co-Investigator(Kenkyū-buntansha): PAYNE DANIEL 国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 外国人特別研究員
• Project Period (FY): 2017-11-10 – 2020-03-31
• Keywords: Porphyrin / Chirality / Dimer / Macrocycle / Self-assembly

Outline of Annual Research Achievements

Synthesis of chiral binaphthyl porphyrin dimers for guest binding was completed and the work has been published. The compounds were found to be multichannel sensors for enantiomeric excess of chiral compounds. Related work on resorcinarene macrocycles has been completed and published. Those compounds were found useful for sensing acidity and for generation of singlet oxygen. Further allied work on the novel catalytic properties of the compounds has been completed and published.
Other work is ongoing in collaboration with Dr. Payne.

Research Progress Status

令和元年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

令和元年度が最終年度であるため、記入しない。

Research Products

• [Journal Article] Diporphyrin Tweezer for Multichannel Spectroscopic Analysis of Enantiomeric Excess (2020)
  • Author(s): Daniel T. Payne, Mandeep K. Chahal, Vaclav Brezina, Whitney A. Webre, Katsuhiko Ariga, Francis D’Souza, Jan Labuta, Jonathan P. Hill
  • Journal Title: Frontiers of Chemical Science and Engineering Volume: 14 Pages: 28-40
  • DOI: doi.org/10.1007/s11705-019-1869-1
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Nanomolecular Singlet Oxygen Photosensitizers based on Hemiquinonoid-resorcinarenes, the Fuchsonarenes (2020)
  • Author(s): Daniel T. Payne, Whitney A. Webre, Habtom Gobese, Yoshitaka Matsushita, Paul A. Karr, Mandeep K. Chahal, Jan Labuta, John S. Fossey, Katsuhiko Ariga, Francis D’Souza, Jonathan P. Hill
  • Journal Title: Chemical Science Volume: 11 Pages: 2614-2620
  • DOI: doi.org/10.1039/D0SC00651C
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Supramolecular Ultrafast Energy and Electron Transfer in a Directly Linked BODIPY-oxoporphyrinogen Dyad upon Fluoride Ion Binding (2020)
  • Author(s): Mandeep K. Chahal, Anuradha Liyanage, Habtom B. Gobeze, Daniel T. Payne, Katsuhiko Ariga, Jonathan P. Hill, Francis D’Souza
  • Journal Title: Chemical Communications Volume: 56 Pages: 3855-3858
  • DOI: doi.org/10.1039/D0CC00633E
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Non-planar β-Substituted Porphyrinoids as Bifunctional Hydrogen-bond Donor Catalysts (2020)
  • Author(s): Mandeep K. Chahal, Daniel T. Payne, Yoshitaka Matsushita, Jan Labuta, Katsuhiko Ariga, Jonathan P. Hill
  • Journal Title: European journal of Organic Chemistry Volume: 2020 Pages: 82-90
  • DOI: doi.org/10.1002/ejoc.201901706
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Knock-on Synthesis of Tritopic Calix[4]pyrrole Host for Enhanced Anion Interactions (2019)
  • Author(s): Mandeep K. Chahal, Jan Labuta, Vaclav Brezina, Paul A. Karr, Yoshitaka Matsushita, Whitney A. Webre, Daniel T. Payne, Katsuhiko Ariga, Francis D’Souza, Jonathan P. Hill
  • Journal Title: Dalton Transactions Volume: 48 Pages: 15583-15596
  • DOI: doi.org/10.1039/C9DT02365H
  • Peer Reviewed / Int'l Joint Research
• [Presentation] Resorcinarenes as Molecular Switches (2019)
  • Author(s): Daniel T. Payne
  • Organizer: 14th International Symposium on Macrocyclic and Supramolecular Chemistry
  • Int'l Joint Research
• [Presentation] Non-Planar beta-Substituted Porphyrinoids as Hydrogen-Bond Donor Catalysts (2019)
  • Author(s): Daniel T. Payne
  • Organizer: 8th Asian Conference on Colloids and Interface Science
  • Int'l Joint Research