2019 Fiscal Year Final Research Report
Development of Novel Electron-Transfer Reactions via Organonitrogen Active Species
| Project/Area Number |
17K05861
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Project Period (FY) |
2017-04-01 – 2020-03-31
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| Keywords | 有機活性種 |
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| Outline of Final Research Achievements |
We have developed transition metal-catalyzed transformation of cyclic O-acyloximes as an novel type of precursors for organonitrogen active species. In this study, we have utilized 3d transition metal catalysts such as iron and cobalt for such transformations. As a result, we have developed cobalt- and iron-catalyzed several types of transformation reactions of O-acyloximes into various nitrogen-containing heterocyclic molecules.
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| Free Research Field |
有機金属化学，有機合成化学
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| Academic Significance and Societal Importance of the Research Achievements |
本研究成果は電子移動型反応による有機窒素活性種の新規発生法開発という当初目的を十分に達成したと言える．電子移動型反応は効率に優れた反応であるため，様々な触媒反応の効率化に果たす役割は大きく，この成果が有機合成化学の発展を含む分子科学への貢献を将来的に果たすことが予想され，ひいては本邦の社会経済に対する将来的な貢献も期待される．
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