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2018 Fiscal Year Annual Research Report

Galvanic microencapsulation: A novel technique to passivate pyrite and prevent acid mine drainage formation

Research Project

Project/Area Number 17K12831
Research InstitutionHokkaido University

Principal Investigator

タベリン カーリット  北海道大学, 工学研究院, 助教 (60626125)

Project Period (FY) 2017-04-01 – 2019-03-31
Keywordsacid mine drainage / microencapsulation / pyrite / passivation / zero-valent iron / iron phosphate / zero-valent aluminum
Outline of Annual Research Achievements

This research proposed galvanic microencapsulation (GME) as a novel technique to passivate pyrite and prevent acid mine drainage formation and its most important achievements are: (1) galvanic interactions were better under acidic conditions, (2) ZVI was better than ZVAl in suppressing pyrite oxidation, (3) addition of phosphate in pyrite and ZVI system produced Fe-phosphate coatings that limited pyrite oxidation, (4) phosphate-enhanced GME was successfully applied in a ball mill using steel balls as Fe source, (5) GME improved coal and pyrite separation during flotation, (6) Fe-phosphate coatings could be formed at pH 1-3 even without ZVI, and (7) a potentially new process was discovered to create Fe-phosphate coatings on pyrite using acid mine drainage rich in ferrous ions.

  • Research Products

    (14 results)

All 2019 2018

All Journal Article (6 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 6 results,  Open Access: 1 results) Presentation (8 results) (of which Int'l Joint Research: 8 results)

  • [Journal Article] Galvanic microencapsulation (GME) using zero-valent aluminum and zero-valent iron to suppress pyrite oxidation2019

    • Author(s)
      S. Seng, C.B Tabelin, M. Kojima, N Hiroyoshi, M. Ito
    • Journal Title

      Materials Transactions

      Volume: 60 Pages: 277-280

    • DOI

      https://doi.org/10.2320/matertrans.M-M2018851

    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] A review of recent strategies for acid mined drainage prevention and mine tailings recycling2019

    • Author(s)
      I. Park, C.B. Tabelin, S. Jeon, X. Li, K. Seno, M. Ito, N. Hiroyoshi
    • Journal Title

      Chemosphere

      Volume: 219 Pages: 588-606

    • DOI

      https://doi.org/10.1016/j.chemosphere.2018.11.053

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Suppressive effects of ferric-catecholate complexes on pyrite oxidation2019

    • Author(s)
      X. Li, N. Hiroyoshi, C.B. Tabelin, K. Naruwa, C. Harada, M. Ito
    • Journal Title

      Chemosphere

      Volume: 214 Pages: 70-78

    • DOI

      https://doi.org/10.1016/j.chemosphere.2018.09.086

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Suppression of the release of arsenic from arsenopyrite by carrier-microencapsulation using Ti-catechol complex2018

    • Author(s)
      I. Park, C.B. Tabelin, K. Magaribuchi, K. Seno, M. Ito, N. Hiroyoshi
    • Journal Title

      Journal of Hazardous Materials

      Volume: 344 Pages: 322-332

    • DOI

      https://doi.org/10.1016/j.jhazmat.2017.10.025

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Arsenic, selenium, boron, lead, cadmium, copper, and zinc in naturally contaminated rocks: A review of their sources, modes of enrichment, mechanisms of release, and mitigation strategies2018

    • Author(s)
      C.B. Tabelin, T. Igarashi, M. Villacorte-Tabelin, I. Park, E.M. Opiso, M. Ito, N. Hiroyoshi
    • Journal Title

      Science of The Total Environment

      Volume: 645 Pages: 1522-1553

    • DOI

      https://doi.org/10.1016/j.scitotenv.2018.07.103

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Simultaneous suppression of acid mine drainage formation and arsenic release by Carrier-microencapsulation using aluminum-catecholate complexes2018

    • Author(s)
      I. Park, C.B. Tabelin, K. Seno, S. Jeon, M. Ito, N. Hiroyoshi
    • Journal Title

      Chemosphere

      Volume: 205 Pages: 414-425

    • DOI

      https://doi.org/10.1016/j.chemosphere.2018.04.088

    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Prediction of acid mine drainage formation and zinc migration in the tailings dam of a closed mine, and possible countermeasures2018

    • Author(s)
      C.B. Tabelin, A. Sasaki, T. Igarashi, S. Tomiyama, M. Villacorte-Tabelin, M. Ito, N. Hiroyoshi
    • Organizer
      The 25th Regional Symposium on Chemical Engineering (RSCE 2018)
    • Int'l Joint Research
  • [Presentation] Formation of surface protective coatings on arsenopyrite using Al-catecholate complex and its mode of inhibition of arsenopyrite oxidation.2018

    • Author(s)
      I. Park, C.B. Tabelin, H. Inano, K. Seno, K. Higuchi, M. Ito, N. Hiroyoshi
    • Organizer
      The 25th Regional Symposium on Chemical Engineering (RSCE 2018)
    • Int'l Joint Research
  • [Presentation] Carrier-microencapsulation using Al-catecholate complex to suppress arsenopyrite oxidation: Evaluation of the coating stability under simulated weathering conditions2018

    • Author(s)
      K. Seno, I. Park, C.B. Tabelin, K. Magaribuchi, M. Ito, N. Hiroyoshi
    • Organizer
      The 25th Regional Symposium on Chemical Engineering (RSCE 2018)
    • Int'l Joint Research
  • [Presentation] Effects of iron-catecholate complexes on pyrite oxidation2018

    • Author(s)
      X. Li, N. Hiroyoshi, K. Naruwa, C. Harada, C.B. Tabelin, M. Ito
    • Organizer
      The 6th Joint Seminar on Geo-environment Engineering and Recycling (GER 2018)
    • Int'l Joint Research
  • [Presentation] The roles of soluble phases in the release of geogenic arsenic and selenium from tunnel-excavated rocks of marine origin2018

    • Author(s)
      C.B. Tabelin, R. Sasaki, T. Igarashi, I. Park, S. Tamoto, T. Arima, M. Ito, N. Hiroyoshi
    • Organizer
      The 17th Global Joint Seminar on Geo-environmental Engineering
    • Int'l Joint Research
  • [Presentation] Comparison of electrochemical properties of various metal-catecholate complexes for carrier-microencapsulation2018

    • Author(s)
      X. Li, C. Harada, I. Park, N. Hiroyoshi, C.B. Tabelin, M. Ito
    • Organizer
      The 17th Global Joint Seminar on Geo-environmental Engineering
    • Int'l Joint Research
  • [Presentation] Suppression of the release of arsenic from arsenopyrite by titanium- and aluminum-based carrier-microencapsulation2018

    • Author(s)
      I. Park, C.B. Tabelin, K. Seno, K. Magaribuchi, M. Ito, N. Hiroyoshi
    • Organizer
      The 17th Global Joint Seminar on Geo-environmental Engineering
    • Int'l Joint Research
  • [Presentation] Comparison of the thermodynamic and electrochemical properties of various cation-catecholate complexes for carrier-microencapsulation2018

    • Author(s)
      C. Harada, X. Li., K. Naruwa, I. Park, N. Hiroyoshi, M. Ito, C.B. Tabelin
    • Organizer
      International Symposium on Earth Science and Technology
    • Int'l Joint Research

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Published: 2019-12-27  

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