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2018 Fiscal Year Annual Research Report

Germanene on Insulators: Towards the realization of a 2D topological insulator

Research Project

Project/Area Number 17K14116
Research InstitutionJapan Advanced Institute of Science and Technology

Principal Investigator

フロランス アントワーヌ  北陸先端科学技術大学院大学, 先端科学技術研究科, 講師 (30628821)

Project Period (FY) 2017-04-01 – 2019-03-31
KeywordsGermanene
Outline of Annual Research Achievements

This project was aimed at finding appropriate substrates for the growth of germanene, a graphene-like two-dimensional material made of germanium atoms and predicted to possess particular topological and conduction properties. For this purpose, Ge was grown on different substrates such as epitaxial h-BN and silicene which are respectively a two-dimensional insulating material and a two-dimensional semconducting material made of silicon atoms, both formed on ZrB2 thin films.
We found that the growth of Ge on h-BN gives rise to an amorphous Ge layer. The post-deposition annealing results in the damaging of the h-BN layer, which suggests that h-BN is not an appropriate substrate for germanene.
We also found that in the low-coverage regime, the growth of Ge on silicene gives rise to the formation of a silicene-Ge alloy. The investigation of the effect of the concentration of Ge atoms on its band structure provided the first experimental demonstration of the possibility of a band structure engineering in a two-dimensional alloy similar to that observed for instance in bulk SiGe alloy. At higher Ge coverages, different two-dimensional structures with unclear yet atomic structures were also observed.
An other part of the project was to use semiconducting InSe thin films grown on Ge(111) as substrate for the growth of germanene. The first step of this project, the determination of appropriate conditions for the growth of single-crystal InSe thin films on Ge(111), was fullfilled. The possibility of growing germanene by depositing Ge on InSe will be investigated in the coming months.

  • Research Products

    (9 results)

All 2019 2018

All Journal Article (3 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 3 results) Presentation (6 results) (of which Invited: 3 results)

  • [Journal Article] Van der Waals integration of silicene and hexagonal boron nitride2019

    • Author(s)
      Wiggers F B、Fleurence A、Aoyagi K、Yonezawa T、Yamada-Takamura Y、Feng H、Zhuang J、Du Y、Kovalgin A Y、de Jong M P
    • Journal Title

      2D Materials

      Volume: 6 Pages: 035001~035007

    • DOI

      https://doi.org/10.1088/2053-1583/ab0a29

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Nanomechanical Properties of Epitaxial Silicene Revealed by Noncontact Atomic Force Microscopy2018

    • Author(s)
      Nogami Makoto、Fleurence Antoine、Yamada-Takamura Yukiko、Tomitori Masahiko
    • Journal Title

      Advanced Materials Interfaces

      Volume: 6 Pages: 1801278~1801283

    • DOI

      https://doi.org/10.1002/admi.201801278

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Atomistic study of GaSe/Ge(111) interface formed through van der Waals epitaxy2018

    • Author(s)
      Yonezawa Takahiro、Murakami Tatsuya、Higashimine Koichi、Fleurence Antoine、Oshima Yoshifumi、Yamada-Takamura Yukiko
    • Journal Title

      Surface and Interface Analysis

      Volume: 51 Pages: 95~99

    • DOI

      https://doi.org/10.1002/sia.6557

    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Influence of strain at GaSe/Ge(111) interface formed through Van der Waals epitaxy2018

    • Author(s)
      Yonezawa T、Nitta H、Murakami T、Higashimine K、Fleurence A、Oshima Y、Yamada-Takamura Y
    • Organizer
      14th international conference on atomically controlled surfaces Interfaces and nanostructures 2018 & 26th international colloquium on scanning tunneling microscopy
  • [Presentation] Nanomechanical responses of epitaxial silicene on ZrB2(0001) examined by non-contact atomic force microscopy2018

    • Author(s)
      Nogami M、Fleurence A、Yamada-Takamura Y、Tomitori M
    • Organizer
      14th international conference on atomically controlled surfaces Interfaces and nanostructures 2018 & 26th international colloquium on scanning tunneling microscopy
  • [Presentation] Band engineering in silicene-Ge alloy2018

    • Author(s)
      Fleurence A、Awatani Y、Wiggers F、Yonezawa T、Wallace S、Huet C、Yamada-Takamura Y
    • Organizer
      14th international conference on atomically controlled surfaces Interfaces and nanostructures 2018 & 26th international colloquium on scanning tunneling microscopy
  • [Presentation] Epitaxial silicene on ZrB2(0001)2018

    • Author(s)
      Fleurence A
    • Organizer
      14th International Conference on Diffusion i Liquids and Solids
    • Invited
  • [Presentation] Epitaxial silicene on ZrB2(0001) : a 2D allotrope of silicon2018

    • Author(s)
      Fleurence A
    • Organizer
      Seminar at MESA+, University of Twente
    • Invited
  • [Presentation] Epitaxial silicene on ZrB2(0001) : a 2D allotrope of silicon2018

    • Author(s)
      Fleurence A
    • Organizer
      CMOS emerging technologies symposium
    • Invited

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Published: 2019-12-27  

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