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2018 Fiscal Year Research-status Report

Experimental modeling of diamond crystallization from C-O-H fluid under controlled oxygen fugacity

Research Project

Project/Area Number 17K14417
Research InstitutionEhime University

Principal Investigator

CHERTKOVA N  愛媛大学, 地球深部ダイナミクス研究センター, 特定研究員 (00791774)

Project Period (FY) 2017-04-01 – 2020-03-31
Keywordsdiamond anvil cell / in situ spectroscopy / C-O-H fluid speciation / diamond stability field
Outline of Annual Research Achievements

The plan for FY 2018 included in situ spectroscopic analysis of the fluids and solid phases, which constitute environment for diamond formation, at the high-pressure and high-temperature conditions. The new assembly of the diamond anvil cell with large optical access to the sample was developed this year particularly for infrared spectroscopy. In situ infrared and Raman measurements of the C-O-H fluid species, coexisting with the silicate minerals of eclogite assembly, were performed in the stability field of diamond. Quenching to room temperature and opening of the experimental cell were accompanied by the change in fluid state, underlining the importance of obtained in situ data. Research findings of this project were reported at the international meetings.

Current Status of Research Progress
Current Status of Research Progress

2: Research has progressed on the whole more than it was originally planned.

Reason

After establishing of the procedure for loading of basaltic glass with methane hydrate fluid source into the sample chamber of diamond anvil cell, experiments were performed in the temperature range to 1000 °C and pressures exceeding 5 GPa. Water and methane were detected after decomposition of methane hydrate upon heating, with the formation of homogeneous C-O-H fluid at higher temperatures. In collaboration with Okayama University, combined infrared and Raman spectroscopic analysis was carried out in order to gain comprehensive information about the types of species and chemical characteristics of the phases observed during experiments. Developed techniques and instrumentation helped to achieve the tasks, which were set in the original plan.

Strategy for Future Research Activity

Research work in the next fiscal year will be concentrated on data processing, comparison of the experimental data with the available large dataset of chemical, structural and mineral analyses of inclusions in natural diamonds. Obtained trends will be used to discuss the models of diamond formation and the reconstruction of conditions for diamond crystallization in the Earth’s mantle. Experimental results will be summarized in the manuscripts prepared for publication in the international scientific journals.

Causes of Carryover

The carryover will be used to cover publication expenses.

  • Research Products

    (5 results)

All 2019 2018

All Journal Article (1 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 1 results) Presentation (4 results) (of which Int'l Joint Research: 3 results)

  • [Journal Article] A step toward better understanding of behavior of organic materials at simultaneous high pressures and high temperatures2018

    • Author(s)
      Chertkova N., Ohfuji H., Nomura R., Kadobayashi H., Irifune, T.
    • Journal Title

      High Pressure Research

      Volume: 38 Pages: 337-347

    • DOI

      10.1080/08957959.2018.1476506

    • Peer Reviewed / Int'l Joint Research
  • [Presentation] A compact diamond anvil cell for in situ spectroscopic measurements at high pressures and high temperatures2019

    • Author(s)
      Chertkova N., Yamashita S., Ohfuji H., Irifune T., Kurio A., Kadobayashi H., Yamamoto Y.
    • Organizer
      International symposium Science and Technology of Nano-Polycrystalline Diamond 2019
    • Int'l Joint Research
  • [Presentation] Probing basalt-5.75H2O-CH4 system by in situ vibrational spectroscopy2019

    • Author(s)
      Chertkova N., Yamashita S., Ohfuji H., Irifune T., Kadobayashi H., Yamamoto Y.
    • Organizer
      Joint symposium of Misasa 2019 & Core-Mantle Coevolution
    • Int'l Joint Research
  • [Presentation] Externally heated lever type diamond anvil cell: application in high-pressure experiments involving COH components2018

    • Author(s)
      Chertkova N., Ohfuji H., Irifune T.
    • Organizer
      JpGU 2018
  • [Presentation] In situ experimental study of basalt-COH system at the upper mantle conditions2018

    • Author(s)
      Chertkova N., Ohfuji H., Irifune T.
    • Organizer
      The 35th International Conference on Magmatism of the Earth and Related Strategic Metal Deposits
    • Int'l Joint Research

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Published: 2019-12-27  

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