2009 Fiscal Year Final Research Report
Construction and Molecular Recognition of Metallo-supramolecules and Their Responding Functions to External Stimulus
| Project/Area Number |
18064005
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| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | University of Tsukuba |
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Principal Investigator |
NABESHIMA Tatsuya University of Tsukuba, 大学院・数理物質科学研究科, 教授 (80198374)
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| Co-Investigator(Kenkyū-buntansha) |
SATO Soichi 筑波大学, 大学院・数理物質科学研究科, 助教授 (90280908)
AKINE Shigehisa 筑波大学, 大学院・数理物質科学研究科, 准教授 (30323265)
IKEDA Chusaku 筑波大学, 大学院・数理物質科学研究科, 準研究員 (30378541)
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| Co-Investigator(Renkei-kenkyūsha) |
YAMAMURA Masaki 筑波大学, 大学院・数理物質科学研究科, 助教 (40524426)
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| Project Period (FY) |
2006 – 2009
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| Keywords | 超分子 / ホスト・ゲスト / 協同効果 / アロステリック効果 / 金属錯体 |
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| Research Abstract |
Artificial molecules with synergistic functions have received much attention not only for allosteric molecules but also for sophisticated functionalized molecular devices. Metal-metal interaction, metal-typical element interaction and metal-ion interaction are known to considerably affect structure and properties and functions of metallo-supramolecules. In this study we design and synthesize responding metallo-supramolecules whose structures and functions can be regulated by such interactions. Selected target molecules are metallo-supramolecules based on pseudomacrocycles, multi-nuclear complexes bearing oxime and Schiff base moieties, complexes of multi-dentate dipyrrin derivatives, etc.
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