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2009 Fiscal Year Final Research Report

Functional Transition Metal Complexes with Heavier Element Ligands

Research Project

  • PDF
Project/Area Number 18064010
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionKyoto University

Principal Investigator

OZAWA Fumiyuki  Kyoto University, 化学研究所, 教授 (40134837)

Co-Investigator(Kenkyū-buntansha) OKAZAKI Masaaki  弘前大学, 大学院・理工学研究科, 教授 (20292203)
TAKITA Ryo  京都大学, 化学研究所, 助教 (50452321)
NAKAJIMA Yumiko  京都大学, 化学研究所, 助教 (80462711)
Project Period (FY) 2006 – 2009
Keywords元素相乗系錯体 / 低配位リン配位子 / 拡張π共役系錯体 / dπ-pπ相互作用 / ヒドロシリル化 / σ結合メタセシス / P-C還元的脱離
Research Abstract

It has been recognized that heavier main-group elements have fundamental difference in electronic properties from their lighter congeners. This viewpoint should be true for coordination chemistry using heavier element ligands as well. In this study, we examined structures and reactivities of group 8-10 metal complexes bearing heavier element ligands. A particular interest has been focused on applications of low-coordinate phosphorus ligands to catalytic reactions and functional molecule synthesis.

  • Research Products

    (28 results)

All 2010 2009 2008 2007 2006 Other

All Journal Article (19 results) (of which Peer Reviewed: 19 results) Presentation (8 results) Remarks (1 results)

  • [Journal Article] Electronic Structure of Four- coordinate Iron(I)Complex Supported by a Bis(phosphaetheny1)pyridine Ligand2010

    • Author(s)
      中島裕美子, 小澤文幸, 他4名
    • Journal Title

      J. Am. Chem. Soc. 132(accepted)

    • Peer Reviewed
  • [Journal Article] Substituent Effects on P-C Reductive Elimination from Styrylpalladium(II)Phosphine Complexes2010

    • Author(s)
      脇岡正幸, 小潭文幸
    • Journal Title

      Organometallics 29(accepted)

    • Peer Reviewed
  • [Journal Article] Synthesis and Structures of Platinum Diphenylacetylene and Dithiolate Complexes Bearing Diphos- phinidenecyclobutene ligands (DPCB-Y)2010

    • Author(s)
      中島裕美子, 滝田良, 岡崎雅明, 小潭文幸, 他3名
    • Journal Title

      New J. Chem. 34(accepted)

    • Peer Reviewed
  • [Journal Article] A Highly Selective Catalytic System for the Cross-Coupling of (E)-Styry1 Bromide with Benzeneboronic Acid:Application to the Synthesis of All-trans Poly(arylene-vinylene)s2009

    • Author(s)
      脇岡正幸, 武藤雄一郎, 滝田良, 小潭文幸
    • Journal Title

      Bull. Chem. Soc. Jpn. 82

      Pages: 1292-1298

    • Peer Reviewed
  • [Journal Article] Redox-Active Phosphorus Ligands Bearing a [4Fe-4C亅Core SubstitUent2009

    • Author(s)
      岡崎雅明, 吉村健一, 高野正人, 小潭文幸
    • Journal Title

      Organometallics 28

      Pages: 7055-7058

    • Peer Reviewed
  • [Journal Article] ジホスフィニデンシクロブテン錯体の構造と触媒作用2009

    • Author(s)
      小潭文幸
    • Journal Title

      有合化 67

      Pages: 529-539

    • Peer Reviewed
  • [Journal Article] Mechanism of C-P Reductive Elimination from trans-[Pd(CH=CHPh)Br(PMePh2)2]2009

    • Author(s)
      脇岡正幸, 中島裕美子, 小潭文幸
    • Journal Title

      Organometallics 28

      Pages: 2527-2534

    • Peer Reviewed
  • [Journal Article] Redox- responsive Recombination of Carbon- Carbon Bonds on Flexible Tetrairon Cores2009

    • Author(s)
      岡崎雅明, 高野正人, 小潭文幸
    • Journal Title

      J. Am. Chem. Soc. 131

      Pages: 1684-1685

    • Peer Reviewed
  • [Journal Article] Synthesis, Structures, and Reactions of Dirhodium Complexes Bearing 1, 2-Dipheny 1-3, 4-diphosphinidene- cyclobutene Ligand2009

    • Author(s)
      岡崎雅明, 林昭人, 小潭文幸, 他2名
    • Journal Title

      Organometallics 28

      Pages: 902-908

    • Peer Reviewed
  • [Journal Article] Synthesis and Ligand Properties of 1-Phosphaetheny1-2-phospha- nylferrocenes2008

    • Author(s)
      滝田良, 高田有子, Rader. S. Jensen, 岡崎雅明, 小潭文幸
    • Journal Title

      Organometallics 27

      Pages: 6279-6285

    • Peer Reviewed
  • [Journal Article] Synthesis and Reactions of Diphosphinidenecyclobutene Ruthenium Complexes Relevant to Catalytic Hydrosilylation of Terminal Alkynes2008

    • Author(s)
      林昭人, 吉富隆彦, 梅田和俊, 岡崎雅明, 小潭文幸
    • Journal Title

      Organometallics 27

      Pages: 2321-2327

    • Peer Reviewed
  • [Journal Article] Synthesis and StmctUres of Platinum(0)Alkyne Complexes with Extendedπ-Conjugated Systems2008

    • Author(s)
      林恭平, 中谷充晴, 林昭人, 岡崎雅明, 小潭文幸, 他3名
    • Journal Title

      Organometallics 27

      Pages: 1970-1972

    • Peer Reviewed
  • [Journal Article] Reaction of trans-[Pd(styry1)Br(PMePh2)2] with Styryl Bromide Affording 1, 4-Dipheny1- butadiene. An Unexpected Homocoupling Process Induced by P-C Reductive Elimination2008

    • Author(s)
      脇岡正幸, 長尾将人, 小潭文幸
    • Journal Title

      Organometallics 27

      Pages: 602-608

    • Peer Reviewed
  • [Journal Article] Synthesis, StructUres, and Catalytic Properties of Late-Transition-Metal 2, 6- Bis-(2-phosphaetheny1)pyridine Complexes2007

    • Author(s)
      林昭人, 岡崎雅明, 小澤文幸, 田中里佳
    • Journal Title

      Organometallics 26

      Pages: 5246-5249

    • Peer Reviewed
  • [Journal Article] Cationic Iridium(III) Complexes bearing Phosphaalkene and 2-Pyridylphenyl Ligands2007

    • Author(s)
      林昭人, 石山武, 岡崎雅明, 小澤文幸
    • Journal Title

      Organometallics 26

      Pages: 3708-3712

    • Peer Reviewed
  • [Journal Article] Synthesis and Catalytic Properties of Cationic Palladium(II) and Rhodium(I)Complexes Bearing Diphosphinidenecyclobutene Ligands2007

    • Author(s)
      RaderS. Jensen, 梅田和俊, 岡崎雅明, 小澤文幸, 吉藤正明
    • Journal Title

      J. Organomet. Chem. 692

      Pages: 286-294

    • Peer Reviewed
  • [Journal Article] Stereoselective Synthesis of cis-and trans-Oligo(phenylenevinylene)s via Palladium-Catalyzed Cross-Coupling Reactions2006

    • Author(s)
      片山博之, 長尾将人, 小澤文幸, 池上和志, 新井達郎
    • Journal Title

      J. Org. Chem. 71

      Pages: 2699-2705

    • Peer Reviewed
  • [Journal Article] Cyclodehydration of cis-2-Butene- 1, 41diol with Active Methylene Compounds Catalyzed by a Diphosphi- nidenecyclobutene-coordinated Palladium Complex2006

    • Author(s)
      村上博美, 松井佑紀男, 小潭文幸, 吉藤正明
    • Journal Title

      J. Organomet. Chem. 691

      Pages: 3151-3156

    • Peer Reviewed
  • [Journal Article] Catalytic Appli- cations of Transition Metal Complexes Bearing Diphosphinidenecyclobutenes (DPCB)2006

    • Author(s)
      小澤文幸, 吉藤正明
    • Journal Title

      Dalton Trans (Perspectire)

      Pages: 4987-4995

    • Peer Reviewed
  • [Presentation] Synthesis, StmctUres, and Properties of Phosphaalkene Complexes, Visiting Scholar Program2010

    • Author(s)
      小澤文幸
    • Organizer
      香港中文大学
    • Year and Date
      2010-03-18
  • [Presentation] P-C Reductive Elimination from Palladium(II) Phosphine Complexes2009

    • Author(s)
      小澤文幸, 脇岡正幸, 中島裕美子
    • Organizer
      2009 Workshop on Organometallic Chemistry
    • Place of Presentation
      九州大学
    • Year and Date
      2009-10-28
  • [Presentation] Synthesis and Properties of Bis(phosphaetheny1)pyridine Iron Complexes2009

    • Author(s)
      小澤文幸, 中島裕美子
    • Organizer
      The 14th Japan-Korea Joint Symposium on Organometallic and Coordination Chemistry
    • Place of Presentation
      名古屋大学
    • Year and Date
      2009-10-09
  • [Presentation] P-C Reductive Elimination from [Pd(styry1)Br(PR3)2] Complexes2008

    • Author(s)
      脇岡正幸, 小澤文幸
    • Organizer
      ChinaーJapan Joint Workshop on Organometallic Chemistry
    • Place of Presentation
      北京大学
    • Year and Date
      2008-10-09
  • [Presentation] Catalytic Applications of Transition Metal Complexes Bearing Diphosphinedenecyclobutenes (DPCB-Y)2008

    • Author(s)
      小澤文幸
    • Organizer
      International Symposium on Chemistry of Concerto Catalysis Based on Synergy of Elements
    • Place of Presentation
      フランス・レンヌ大学
    • Year and Date
      2008-07-12
  • [Presentation] [RuCl(μ-Cl)(CO)(DPCB-OMe)]2:A Highly Efficient Catalyst for (Z)-Selective Hydrosilylation of Terminal Alkynes2008

    • Author(s)
      小澤文幸
    • Organizer
      The 15th International Symposium on Organosilicon Chemistry
    • Place of Presentation
      韓国・済州島
    • Year and Date
      2008-06-04
  • [Presentation] 低配位リン化合物が創る新しい遷移金属錯体反応場2007

    • Author(s)
      小澤文幸
    • Organizer
      日本化学会第88春季年会
    • Place of Presentation
      関西大学
    • Year and Date
      2007-03-27
  • [Presentation] Highly Active Catalysts Bearing Diphosphinidenecyclobutene Ligands (DPCB)2006

    • Author(s)
      小澤文幸
    • Organizer
      The Chemistry Research Promotion Center Lectureship
    • Place of Presentation
      国立台湾大学
    • Year and Date
      2006-11-08
  • [Remarks]

    • URL

      http://om.kuicr.kyoto-u.ac.jp

URL: 

Published: 2011-06-18   Modified: 2016-04-21  

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