• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

2009 Fiscal Year Final Research Report

Development of Multi Element Compounding Reaction System by Highly Coordinated Transition Metal Complexes

Research Project

  • PDF
Project/Area Number 18064012
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionKyoto University (2008-2009)
Osaka University (2006-2007)

Principal Investigator

TERAO Jun  Kyoto University, 大学院・工学研究科, 准教授 (00322173)

Project Period (FY) 2006 – 2009
Keywords遷移金属触媒 / 炭素-炭素結合形成反応 / クロスカップリング反応 / アート型錯体 / 多元素相乗効果
Research Abstract

Transition metal-catalyzed reactions have matured into powerful, selective, and high-yielding methods for carbon-carbon and carbon-silicon bond formation, and such processes are routinely used in the wide fields ranging from materials science to natural product synthesis. Transition metal complexes are classified broadly into neutral, cationic, and anionic complexes. The former two have been widely used as catalysts for organic synthesis in both academia and industry while the latter is applicably behind. Anionic complexes formed by the reaction of neutral complexes with organometallic reagents possess high electron densities. Consequently, it is considered that the nucleophilicity at the metal center or π-carbon ligands, and the electron-donating ability of anionic complexes would be enhanced in comparison with the corresponding neutral complexes. We have developed new methodologies for carbon-carbon and carbon-silicon bond forming reactions using alkyl halides and/or chlorosilanes by drawing focus to these characteristics of an anionic complex.

  • Research Products

    (19 results)

All 2010 2009 2008 2007 2005 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (3 results) Book (1 results) Remarks (8 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article]2010

    • Author(s)
      Jun Terao, Masahiro Tomita Surya Prakash Singh, Nobuaki Kambe
    • Journal Title

      Angew. Chem. Int. Ed. 49

      Pages: 144-147

    • Peer Reviewed
  • [Journal Article]2009

    • Author(s)
      Jun Terao, Yuji Tanaka, Susumu Tsuda, Nobuaki Kambe, Masateru Taniguchi, Tomoji Kawai, Akinori Saeki, Shu Seki
    • Journal Title

      J. Am. Chem. Soc. 131

      Pages: 18046-18047

    • Peer Reviewed
  • [Journal Article]2009

    • Author(s)
      Jun Terao, Susumu Tsuda, Yuji Tanaka, Kento Okoshi, Tetsuaki Fujihara, Yasushi Tsuji, Nobuaki Kambe
    • Journal Title

      J. Am. Chem. Soc. 131

      Pages: 16604-16605

    • Peer Reviewed
  • [Journal Article]2008

    • Author(s)
      Jun Terao, Nobuaki Kambe
    • Journal Title

      Acc. Chem. Res. 41

      Pages: 1545-1554

    • Peer Reviewed
  • [Journal Article]2007

    • Author(s)
      Jun Terao, Hirohisa Todo, Shameem Ara Begum, Hitoshi Kuniyasu, Nobuaki Kambe
    • Journal Title

      Angew. Chem. Int. Ed. 46

      Pages: 2086-2089

    • Peer Reviewed
  • [Presentation] 1-ロタキサンモノマーの重合による被覆分子ワイヤの合成とその応用2008

    • Author(s)
      寺尾潤
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      大阪市立大学杉本キャンパス
    • Year and Date
      2008-09-25
  • [Presentation] Cross-Coupling Reaction Using Anionic Transition Metal Complexes2007

    • Author(s)
      Jun Terao
    • Organizer
      2007 Workshop on Organometallic Chemistry
    • Place of Presentation
      Venue: Suzuki Umetaro Hall, RIKEN
    • Year and Date
      20071108-20071109
  • [Presentation] クロスカップリング反応の新方法論2007

    • Author(s)
      寺尾潤
    • Organizer
      プロセス化学ラウンジ2007
    • Place of Presentation
      須磨
    • Year and Date
      2007-12-13
  • [Book] ハロゲン化アルキル類のクロスカップリング反応を利用する(sp3)炭素-炭素結合生成の新手法(共著)、現代化学増刊最新有機合成化学, 東京化学同人2005

    • Author(s)
      寺尾潤, 神戸宣明
    • Total Pages
      123-135
  • [Remarks] (1)研究代表者HP

    • URL

      http://twww.ehcc.kyoto-u.ac.jp/terao/index.html

  • [Remarks] (2)受賞

  • [Remarks] (1)2007/7/7 Merck Banyu Lectureship Award(万有生命科学振興国際交流財団)

  • [Remarks] (1)2007/4/17 文部科学大臣表彰若手科学者賞(文部科学省)

  • [Remarks] (3)2007/3/14 三井触媒科学奨励賞(三井化学)

  • [Remarks] (4)2006/11/18 Banyu Young Chemist Award(Banyu Life Science Foundation International)

  • [Remarks] (5)2006/11/11 ケイ素化学協会奨励賞(ケイ素化学協会)

  • [Remarks] (6)2006/5/19 石油学会奨励賞(石油学会)

  • [Patent(Industrial Property Rights)] マグネシウム化合物を用いたヘテロ原子含有化合物の製造方法

    • Inventor(s)
      神戸宣明、寺尾潤(大阪大学)、足達健二(ダイキン工業)
    • Industrial Property Rights Holder
      国立大学法人大阪大学、ダイキン工業株式会社
    • Industrial Property Number
      特願2006-352726
  • [Patent(Industrial Property Rights)] 複数の有機環状構造とその有機環状構造を貫通する鎖状構造とを備える有機重合体およびその製造方法

    • Inventor(s)
      竹内孝之、美濃規央、(松下電器産業)、神戸宣明、寺尾潤(大阪大学)
    • Industrial Property Rights Holder
      松下電器産業株式会社、国立大学法人大阪大学
    • Industrial Property Number
      特願2006-332048

URL: 

Published: 2011-06-18   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi