2009 Fiscal Year Final Research Report
Development of Multi Element Compounding Reaction System by Highly Coordinated Transition Metal Complexes
| Project/Area Number |
18064012
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| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Kyoto University (2008-2009)
Osaka University (2006-2007) |
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Principal Investigator |
TERAO Jun Kyoto University, 大学院・工学研究科, 准教授 (00322173)
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| Project Period (FY) |
2006 – 2009
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| Keywords | 遷移金属触媒 / 炭素-炭素結合形成反応 / クロスカップリング反応 / アート型錯体 / 多元素相乗効果 |
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| Research Abstract |
Transition metal-catalyzed reactions have matured into powerful, selective, and high-yielding methods for carbon-carbon and carbon-silicon bond formation, and such processes are routinely used in the wide fields ranging from materials science to natural product synthesis. Transition metal complexes are classified broadly into neutral, cationic, and anionic complexes. The former two have been widely used as catalysts for organic synthesis in both academia and industry while the latter is applicably behind. Anionic complexes formed by the reaction of neutral complexes with organometallic reagents possess high electron densities. Consequently, it is considered that the nucleophilicity at the metal center or π-carbon ligands, and the electron-donating ability of anionic complexes would be enhanced in comparison with the corresponding neutral complexes. We have developed new methodologies for carbon-carbon and carbon-silicon bond forming reactions using alkyl halides and/or chlorosilanes by drawing focus to these characteristics of an anionic complex.
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[Journal Article]2009
Author(s)
Jun Terao, Yuji Tanaka, Susumu Tsuda, Nobuaki Kambe, Masateru Taniguchi, Tomoji Kawai, Akinori Saeki, Shu Seki
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Journal Title
J. Am. Chem. Soc. 131
Pages: 18046-18047
Peer Reviewed
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[Journal Article]2009
Author(s)
Jun Terao, Susumu Tsuda, Yuji Tanaka, Kento Okoshi, Tetsuaki Fujihara, Yasushi Tsuji, Nobuaki Kambe
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Journal Title
J. Am. Chem. Soc. 131
Pages: 16604-16605
Peer Reviewed
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[Journal Article]2008
Author(s)
Jun Terao, Nobuaki Kambe
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Journal Title
Acc. Chem. Res. 41
Pages: 1545-1554
Peer Reviewed
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[Journal Article]2007
Author(s)
Jun Terao, Hirohisa Todo, Shameem Ara Begum, Hitoshi Kuniyasu, Nobuaki Kambe
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Journal Title
Angew. Chem. Int. Ed. 46
Pages: 2086-2089
Peer Reviewed
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[Remarks] (2)受賞
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[Remarks] (1)2007/7/7 Merck Banyu Lectureship Award(万有生命科学振興国際交流財団)
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[Remarks] (1)2007/4/17 文部科学大臣表彰若手科学者賞(文部科学省)
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[Remarks] (3)2007/3/14 三井触媒科学奨励賞(三井化学)
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[Remarks] (4)2006/11/18 Banyu Young Chemist Award(Banyu Life Science Foundation International)
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[Remarks] (5)2006/11/11 ケイ素化学協会奨励賞(ケイ素化学協会)
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[Remarks] (6)2006/5/19 石油学会奨励賞(石油学会)
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