2009 Fiscal Year Final Research Report
Synergetic effects of dual metal group interaction for catalysis
| Project/Area Number |
18064014
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| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Kyushu University |
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Principal Investigator |
NAGASHIMA Hideo Kyushu University, 先導物質化学研究所, 教授 (50159076)
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| Co-Investigator(Kenkyū-buntansha) |
MOTOYAMA Yukihiro 九州大学, 先導物質化学研究所, 准教授 (20283492)
SUNADA Yusuke 九州大学, 先導物質化学研究所, 助教 (70403988)
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| Project Period (FY) |
2006 – 2009
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| Keywords | 分子触媒 / クラスター / ヒドロシラン / シリコーンゲル / 固定化触媒 |
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| Research Abstract |
Studies on the multinuclear transition metal complexes and silicon-transition metal clusters revealed their unique structures and reactivity, leading to discovery of unique catalysis based on synergetic effects of the element and element in these complexes. Proximity effect of dual Si-H bonds in ruthenium, iron, platinum, and iridium catalyzed hydrosilane reduction of carbonyl compounds provides practical process to access amines, enamines, and other organic molecules. An intriguing discovery is metallic species encapsulated in silicone gel, which behaves reusable catalysts in organic synthesis.
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