Development of Selective Oxidation Catalyst by Control of Multi-Nuclear Active Site of Transition Metal and Reaction Field

2008 Fiscal Year Self-evaluation Report

• Project/Area Number: 18065002
• Research Category: Grant-in-Aid for Scientific Research on Priority Areas
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: The University of Tokyo
• Principal Investigator: MIZUNO Noritaka The University of Tokyo, 大学院・工学系研究科, 教授 (50181904)
• Project Period (FY): 2006 – 2009
• Keywords: 多核遷移金属活性点 / 反応場 / 選択酸化 / 触媒

Research Abstract

本研究では、酸化耐性に優れた金属酸化物クラスター中に多核金属活性点を構築し、これを触媒とする炭化水素類の選択酸化触媒の開発を行っている。

Research Products

• [Journal Article] 1,3-Dipolar Cycloaddition of Organic Azides to Alkynes by a Dicopper-Substituted Silicotungstate (2008)
  • Author(s): K. Kamata, Y. Nakagawa, K. Yamaguchi, N. Mizuno
  • Journal Title: J. Am. Chem. Soc 130 Pages: 15304-15310
• [Journal Article] Synthesis of a Dialuminum-Substituted Silicotungstate and the Diastereoselective Cyclization of Citronellal Derivatives (2008)
  • Author(s): Y. Kikukawa, S. Yamaguchi, Y. Nakagawa, K. Uehara, S. Uchida, K. Yamaguchi, N. Mizuno
  • Journal Title: J. Am. Chem. Soc. 130 Pages: 15872-15878
• [Presentation] Design of Selective Oxidation Catalysts with Polyoxometalates (2008)
  • Author(s): Noritaka Mizuno
  • Organizer: 8th International Symposium on Fine Chemistry and Functional Polymers 4th IUPAC International Symposium on Novel Materials and their Synthesis
  • Place of Presentation: Zhen Jiang
  • Year and Date: 2008-10-15
• [Presentation] 構造・粒子形態制御によるナノ構造触媒の創製 (2008)
  • Author(s): 水野哲孝
  • Organizer: 第102回触媒反応討論会
  • Place of Presentation: 名古屋
  • Year and Date: 2008-09-25
• [Book] Liquid-Phase Oxidations with Hydrogen Peroxide and Molecular Oxygen Catalyzed by Polyoxometalate-Based Compounds, Modern Heterogeneous Oxidation Catalysis(ed. by N. Mizuno) (2009)
  • Author(s): N. Mizuno, K. Kamata, S. Uchida, K. Yamaguchi
  • Total Pages: 185-216
  • Publisher: Wiley-VCH