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2009 Fiscal Year Final Research Report

Surface-Mediated Catalyst Design for Selective Oxidation Catalysis

Research Project

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Project/Area Number 18065003
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionInstitute for Molecular Science (2008-2009)
The University of Tokyo (2006-2007)

Principal Investigator

TADA Mizuki  Institute for Molecular Science, 物質分子科学研究領域, 准教授 (70396810)

Co-Investigator(Kenkyū-buntansha) SASAKI Takehiko  東京大学, 大学院・新領域創成科学研究科, 准教授 (90242099)
Project Period (FY) 2006 – 2009
Keywords固定化金属錯体 / 固体触媒 / 触媒構造解析 / 選択酸化 / 触媒反応機構
Research Abstract

Novel unique metal catalysts were designed and prepared on oxide surfaces by metal-complex attaching and selective structural transformation at the surfaces and we have found concerto catalysis for selective oxidation on these surface-mediated metal-complex catalysts. Dynamic structural changes of catalytically active species in the concerto catalysis were investigated by in-situ time-resolved XAFS technique and the reaction mechanism and structural kinetics of the concerto catalysis were demonstrated.

  • Research Products

    (47 results)

All 2010 2009 2008 2007 2006 Other

All Journal Article (19 results) (of which Peer Reviewed: 19 results) Presentation (17 results) Book (9 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Alternative Selective Oxidation Pathways for Aldehyde Oxidation and Alkene Epoxidation on a SiO2-Supported Ru-Monomer Complex Catalyst2010

    • Author(s)
      M. Tada, S. Muratsugu, M. Kinoshita, T. Sasaki, Y. Iwasawa
    • Journal Title

      J. Am. Chem. Soc 132

      Pages: 713-724

    • Peer Reviewed
  • [Journal Article] Layered Materials with Coexisting Acidic and Basic Sites for Catalytic One-Pot Reaction Sequences2009

    • Author(s)
      K. Motokura, M. Tada, Y. Iwasawa
    • Journal Title

      J. Am. Chem. Soc 131

      Pages: 7944-7945

    • Peer Reviewed
  • [Journal Article] Bifunctional Heterogeneous Catalysis of Silica-Alumina-Supported Tertiary Amines with Controlled Acid-Base Interactions for Efficient 1, 4-Addition Reactions2009

    • Author(s)
      K. Motokura, S. Tanaka, M. Tada, Y. Iwasawa
    • Journal Title

      Chem. Eur. J 15

      Pages: 10871-10879

    • Peer Reviewed
  • [Journal Article] Conceptual Integration of Homogeneous and Heterogeneous Catalyses2008

    • Author(s)
      M. Tada, K. Motokura, Y. Iwasawa
    • Journal Title

      Topic Catal 48

      Pages: 32-40

    • Peer Reviewed
  • [Journal Article] Cooperative Catalysis of Primary and Tertiary Amines Immobilized on Oxide Surface for One-Pot C-C Bond Forming Reaction2008

    • Author(s)
      K. Motokura, M. Tada, Y. Iwasawa
    • Journal Title

      Angew. Chem. Int. Ed 47

      Pages: 9230-9235

    • Peer Reviewed
  • [Journal Article] Photoinduced Reversible Structural Transformation and Selective Oxidation Catalysis of Unsaturated Ruthenium Complexes Supported on SiO22008

    • Author(s)
      M. Tada, Y. Akatsuka, Y. Yang, T. Sasaki, M. Kinoshita, K. Motokura, Y. Iwasawa
    • Journal Title

      Angew. Chem. Int. Ed. 47

      Pages: 9252-9255

    • Peer Reviewed
  • [Journal Article] Enantioselectivity Promotion by Achiral Surface Functionalization on SiO2-Supported Cu-bis(oxazoline) Catalysts for Asymmetric Diels-Alder Reactions2007

    • Author(s)
      T.E. Mueller, K. Hultzsch, M. Yus, F. Foubelo, M. Tada
    • Journal Title

      J. Catal. 245

      Pages: 173-183

    • Peer Reviewed
  • [Journal Article] In-situ Time-Resolved Dynamic Surface Events on the Pt/C Cathode in a Fuel Cell under Operando Conditions2007

    • Author(s)
      M. Tada, S. Murata, T. Asaoka, K. Hiroshima, K. Okumura, H. Tanida, T. Uruga, H. Nakanishi, S. Matsumoto, Y. Inada, M. Nomura, Y. Iwasawa
    • Journal Title

      Angew. Chem. Int. Ed 46

      Pages: 4310-4315

    • Peer Reviewed
  • [Journal Article] A New Aspect of Heterogeneous Catalysis: Highly Reactive cis-(NO)2 Dimer and Eley-Rideal Mechanism for NO-CO Reactions on a Co-Dimer/γ-Alumina Catalyst2007

    • Author(s)
      T. Taniike, M. Tada, R. Coquet, Y. Morikawa, T. Sasaki, Y. Iwasawa
    • Journal Title

      Chem. Phys. Lett. 443

      Pages: 66-70

    • Peer Reviewed
  • [Journal Article] Selective Formation of a Coordinatively Unsaturated Metal Complex at a Surface: A SiO2-Immobilized, Three-Coordinate Ruthenium Catalyst for Alkene Epoxidation2007

    • Author(s)
      M. Tada, R. Coquet, J. Yoshida, M. Kinoshita, Y. Iwasawa
    • Journal Title

      Angew. Chem. Int. Ed. 46

      Pages: 7220-7223

    • Peer Reviewed
  • [Journal Article] Novel Re-Cluster/HZSM-5 Catalyst for Highly Selective Phenol Synthesis from Benzene and O2: Performance and Reaction Mechanism2007

    • Author(s)
      M. Tada, R. Bal, T. Sasaki, Y. Uemura, Y. Inada, S. Tanaka, M. Nomura, Y. Iwasawa
    • Journal Title

      J. Phys. Chem. C 111

      Pages: 10095-10104

    • Peer Reviewed
  • [Journal Article] Understanding of Novel Surface Events on a Supported Co2+-Ensemble Catalyst Promoted by Gas-Phase Molecules: Increases in the Amount and Reactivity of Adsorbed NO by CO Undetectable at the Catalyst Surface2007

    • Author(s)
      M. Tada, T. Taniike, Y. Iwasawa
    • Journal Title

      J. Phys. Chem. C 111

      Pages: 11663-11675

    • Peer Reviewed
  • [Journal Article] Low-Temperature PROX (Preferential Oxidation) on Novel CeO2-Supported Cu-Cluster Catalysts under Fuel-Cell Operating Conditions2007

    • Author(s)
      M. Tada, R. Bal, X. Mu, R. Coquet, S. Namba, Y. Iwasawa
    • Journal Title

      Chem. Commun.

      Pages: 689-4691

    • Peer Reviewed
  • [Journal Article] Energy-Gaining Formation and Catalytic Behavior of Active Structures in a SiO2-Supported Unsaturated Ru Complex Catalyst for Alkene Epoxidation by DFT Calculations2007

    • Author(s)
      R. Coquet, M. Tada, Y. Iwasawa
    • Journal Title

      Phys. Chem. Chem. Phys. 9

      Pages: 6040-6046

    • Peer Reviewed
  • [Journal Article] Origin and Dynamics of Oxygen Storage/Release in a Pt/Ordered CeO2-ZrO2 Catalyst Studied by Time-Resolved XAFS Analysis2007

    • Author(s)
      T. Yamamoto, A. Suzuki, Y. Nagai, T. Tanabe, F. Dong, Y. Inada, M. Nomura, M. Tada, Y. Iwasawa
    • Journal Title

      Angew. Chem. Int. Ed. 46

      Pages: 9253-9256

    • Peer Reviewed
  • [Journal Article] Advanced Design of Catalytically Active Reaction Space at Surfaces for Selective Catalysis2007

    • Author(s)
      M. Tada, Y. Iwasawa
    • Journal Title

      Coord. Chem. Rev. 251

      Pages: 2702-2716

    • Peer Reviewed
  • [Journal Article] Direct Phenol Synthesis by Selective Oxidation of Benzene with Molecular Oxygen on an Interstitial-N/Re Cluster/Zeolite Catalyst2006

    • Author(s)
      R. Bal, M. Tada, T. Sasaki, Y. Iwasawa
    • Journal Title

      Angew. Chem. Int. Ed 45

      Pages: 448-452

    • Peer Reviewed
  • [Journal Article] Density Functional Theoretical Calculations for a Co2/γ-Al2O3 Model Catalyst: Structures of the γ-Al2O3 Bulk and Surface and Attachment Sites for Co2+ Ions2006

    • Author(s)
      T. Taniike, M. Tada, Y. Morikawa, T. Sasaki, Y. Iwasawa
    • Journal Title

      J. Phys. Chem. B 110

      Pages: 4929-4936

    • Peer Reviewed
  • [Journal Article] Advanced Chemical Design with Supported Metal Complexes for Selective Catalysis2006

    • Author(s)
      M. Tada, Y. Iwasawa
    • Journal Title

      Chem. Commun 2833-2844

    • Peer Reviewed
  • [Presentation] リモネン末端C=C結合位置選択的エポキシ化モレキュラーインプリンティングRu触媒の設計2010

    • Author(s)
      唯美津木, 邨次智, 木下睦雄, 楊勇, 岩澤康裕
    • Organizer
      第105回触媒討論会
    • Place of Presentation
      京都
    • Year and Date
      20100324-20100325
  • [Presentation] Advanced Design of Oxide-Supported Metal Complexes for Selective Catalysis2009

    • Author(s)
      M. Tada
    • Organizer
      The 2nd Asian Conference on Coordination Chemistry
    • Place of Presentation
      Nanjing, China
    • Year and Date
      20091101-20091104
  • [Presentation] Design of Novel Molecular-Imprinted Ru-Complex Catalyst for Regioselective Epoxidation2009

    • Author(s)
      M. Tada, Y. Yang, M. Kinoshita, Y. Iwasawa
    • Organizer
      238th ACS National Meeting
    • Place of Presentation
      Washington D.C., USA
    • Year and Date
      20090815-20090821
  • [Presentation] Design of Molecular-Imprinted Metal-Complex Catalysts for Shape-Selective Catalysis2009

    • Author(s)
      M. Tada
    • Organizer
      Japan-Canada Coordination Space Symposium
    • Place of Presentation
      Banff, Canada
    • Year and Date
      20090708-20090711
  • [Presentation] 表面上の触媒活性構造の解析法と機能創出2009

    • Author(s)
      唯美津木
    • Organizer
      第89回日本化学会春季年会ATP講演
    • Place of Presentation
      千葉
    • Year and Date
      20090327-20090330
  • [Presentation] Novel Molecularly- Organized Catalysts for Selective Oxidation and Reforming2009

    • Author(s)
      M. Tada
    • Organizer
      237th ACS National Meeting
    • Place of Presentation
      Salt Lake City, US
    • Year and Date
      20090322-20090326
  • [Presentation] 表面を媒体とした新規高活性Ru錯体の創出とその触媒機能2008

    • Author(s)
      唯美津木
    • Organizer
      第5回特定領域研究協奏機能触媒公開シンポジウム
    • Place of Presentation
      大阪
    • Year and Date
      20081202-20081203
  • [Presentation] Active Structure and Dynamic Mechanism for Direct Phenol Synthesis from Benzene and O2 on a Novel Re10(N)2-Cluster/HZSM-5 Catalyst2008

    • Author(s)
      M. Tada
    • Organizer
      14th International Congress on Catalysis
    • Place of Presentation
      Seoul, Korea
    • Year and Date
      20080713-20080718
  • [Presentation] Novel Molecularly-Organized Materials for O2 Activation in Catalysis2008

    • Author(s)
      M. Tada
    • Organizer
      2008 Gordon Research Conference on Catalysis
    • Place of Presentation
      New London, USA
    • Year and Date
      20080622-20080627
  • [Presentation] Reaction Mechanism of Direct Phenol Synthesis from Benzene and Molecular Oxygen on Re10N2-Cluster/HZSM-5 Catalysts2008

    • Author(s)
      M. Tada
    • Organizer
      235th ACS National Meeting
    • Place of Presentation
      New Orleans, USC
    • Year and Date
      20080406-20080410
  • [Presentation] 選択触媒機能創出を目指した表面を媒体とする高活性金属錯体の構築と反応機構解明2008

    • Author(s)
      唯美津木
    • Organizer
      第88回日本化学会春季年会
    • Place of Presentation
      東京
    • Year and Date
      20080326-20080330
  • [Presentation] Surface-Mediated Asymmetric Catalysis by Supported Metal Complexes2007

    • Author(s)
      M. Tada
    • Organizer
      Workshop in Catalysis and Fine Chemicals 2007
    • Place of Presentation
      Singapore
    • Year and Date
      20071217-20071220
  • [Presentation] 表面を媒体とした活性構造制御と選択酸化触媒能の創出2007

    • Author(s)
      唯美津木
    • Organizer
      第100回触媒討論会「協奏機能触媒」セッション
    • Place of Presentation
      札幌
    • Year and Date
      20070917-20070920
  • [Presentation] Active Structure and Reaction Mechanism for Direct Phenol Synthesis from Benzene and O2 on a Highly Selective N-Interstitial Re-Cluster/HZSM-5 Catalyst2007

    • Author(s)
      M. Tada, R. Bal, Y. Iwasawa
    • Organizer
      13th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis
    • Place of Presentation
      Berkeley, USA
    • Year and Date
      20070711-20070716
  • [Presentation] Direct Phenol Synthesis from Benzene with Molecular Oxygen on a Novel N-Interstitial Re Cluster/Zeolite Catalyst2007

    • Author(s)
      M. Tada, R. Bal, Y. Iwasawa
    • Organizer
      20th North American Catalysis Society Meeting
    • Place of Presentation
      Houston, USA
    • Year and Date
      20070618-20070622
  • [Presentation] 表面を用いた触媒協奏機能の設計・創出と高度反応制御2006

    • Author(s)
      唯美津木
    • Organizer
      特定領域研究「協奏機能触媒」第1回公開シンポジウム
    • Place of Presentation
      吹田
    • Year and Date
      20061212-20061213
  • [Presentation] Advanced Design of Supported Metal-Complex Catalysts on surfaces for Selective Catalysis2006

    • Author(s)
      M. Tada, Y. Iwasawa
    • Organizer
      6th China-Japan Joint Symposium on Metal Cluster Compounds
    • Place of Presentation
      Huangshan, China
    • Year and Date
      20061021-20061027
  • [Book] ナノ空間材料の創製と応用展開2009

    • Author(s)
      唯美津木
    • Publisher
      フロンティア出版
  • [Book] 超分子金属錯体2009

    • Author(s)
      唯美津木, 岩澤康裕
    • Publisher
      三共出版
  • [Book] Modern Surface Organometallic Chemistry2009

    • Author(s)
      M. Tada, Y. Iwasawa
  • [Book] Modern Heterogeneous Oxidation Catalysis2009

    • Author(s)
      M. Tada, Y. Iwasawa
  • [Book] Handbook of Heterogeneous Catalysis 2nd Ed2007

    • Author(s)
      M. Tada, Y. Iwasawa
  • [Book] 固定化触媒のルネッサンス2007

    • Author(s)
      唯美津木, 岩澤康裕
    • Publisher
      株式会社シーエムシー出版
  • [Book] 設計表面の触媒反応2007

    • Author(s)
      唯美津木, 岩澤康裕
  • [Book] Surface and Nanomolecular Catalysis2006

    • Author(s)
      M. Tada, Y. Iwasawa
  • [Book] Model Systems in Catalysis: From Single Crystals and Size Selected Clusters to Supported Enzyme Mimics

    • Author(s)
      M. Tada, Y. Iwasawa
    • Publisher
      Springer(in press)
  • [Patent(Industrial Property Rights)] フェノール製造用触媒の製造方法および該触媒を用いたフェノールの製造方法2009

    • Inventor(s)
      唯美津木, 岩澤康裕, 王林勝, 及川隆
    • Industrial Property Rights Holder
      唯美津木, 岩澤康裕, 王林勝, 及川隆
    • Industrial Property Number
      特願・2009-55354
    • Filing Date
      2009-03-15
  • [Patent(Industrial Property Rights)] ベンゼンの直接酸化によるフェノールの製造方法2008

    • Inventor(s)
      岩澤康裕, 唯美津木, 王林勝, 及川隆
    • Industrial Property Rights Holder
      岩澤康裕, 唯美津木, 王林勝, 及川隆
    • Industrial Property Number
      特願・2008-98460
    • Filing Date
      2008-04-04

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Published: 2011-06-18   Modified: 2016-04-21  

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