2009 Fiscal Year Final Research Report
Creation of Catalysis Based on Cooperative Effect of Transition Metals
| Project/Area Number |
18065006
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
|
| Allocation Type | Single-year Grants |
|---|
| Review Section |
Science and Engineering
|
|---|
| Research Institution | Tokyo University of Agriculture and Technology |
|---|
Principal Investigator |
KOMIYA Sanshiro Tokyo University of Agriculture and Technology, 大学院・共生科学技術研究院, 教授 (00111667)
|
|---|
| Co-Investigator(Renkei-kenkyūsha) |
HIRANO Masafumi 東京農工大学, 大学院・共生科学技術研究院, 准教授 (70251585)
KOMINE Nobuyuki 東京農工大学, 大学院・共生科学技術研究院, 助教 (90302918)
|
|---|
| Project Period (FY) |
2006 – 2009
|
| Keywords | 遷移金属錯体 / 協同効果 / 錯体触媒 / 挿入反応 |
|---|
| Research Abstract |
Series of Heterodinulcear organo(or hydrido, allyl, carbene)platinum(or palladium) complexesd were prepared. Palladium(0)-catalyzed Markovnikov-type olefin insertion into insertion-inactive transition metal hydride complexes MHL´n were achieved, whose activity highly depends on steric factors of tertiary phosphine ligand employed. (E)-Isomer-selective intramolecular fluxional behavior and facile olefin induced reductive elimination of heterodinuclear allyplatinum-cobalt complexes are observed. These unusual reactivities are considered to be arisen from thermodynamic stability of the resulting allyltransition metal complexes.
|
