Synthesis and Catalytic Properties of Hemi-labile Ligands

2008 Fiscal Year Self-evaluation Report

• Project/Area Number: 18065008
• Research Category: Grant-in-Aid for Scientific Research on Priority Areas
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Tokyo Institute of Technology
• Principal Investigator: TANAKA Masato Tokyo Institute of Technology, 資源化学研究所, 教授 (20343163)
• Project Period (FY): 2006 – 2009
• Keywords: 有機工業化学 / 合成化学 / 触媒・化学プロセス / 錯体触媒 / 配位子 / 有機リン化合物

Research Abstract

(1) 窒素又は3価リン部位と、ホスフィン酸エステル又はホスフィンオキシド部位を持つ配位子の合成法を開拓する。
(2) 既存の配位子を基準としてこれらの配位子の触媒反応における性能を評価する。特に、重合反応、ヘック反応、有機リン化合物の合成反応、その他のヘテロ原子導入反応を中心に検討する。

Research Products

• [Journal Article] Rhodium-Complex-Catalyzed Addition Reactions of Chloroacetyl Chlorides to Alkynes (2008)
  • Author(s): Kashiwabara Taigo, Fuse Kohichiro, Hua Ruimao, Tanaka Masato
  • Journal Title: Org. Lett. 10 Pages: 5469-5472
  • Peer Reviewed
• [Journal Article] Palladium-catalysed regioselective addition reaction of ethyl phenylphosphinate with terminal acetylenes: Ligandand solvent-dependent regioselectivity (2007)
  • Author(s): Satish Kumar Nune, Tanaka Masato
  • Journal Title: Chem. Commun. Pages: 2858-2860
  • Peer Reviewed
• [Journal Article] Nickel-Catalyzed Thioallylation of Alkynes with Allyl Phenyl Sulfides (2007)
  • Author(s): Hua Ruimao, Takeda Hideaki, Onozawa Shun-ya, Abe Yoshimoto, Tanaka Masato
  • Journal Title: Org. Lett. 9 Pages: 263-266
  • Peer Reviewed
• [Journal Article] Palladium-complex-catalyzed regioselective Markovnikov addition reaction and dehydrogenative double phosphinylation to terminal alkynes with diphenylphosphine oxide (2007)
  • Author(s): Dobashi Naotomo, Fuse Kouichiro, Hoshino Takako, Kanada Jun, Kashiwabara Taigo, Kobata Chihiro, Satish Kumar Nune, Tanaka Masato
  • Journal Title: Tetrahedron Lett. 48 Pages: 4669-4673
  • Peer Reviewed
• [Journal Article] Decarbonylative Coupling of Fluorobenzoyl Chlorides with Hexamethyldisilane in the Presence of Pd Complex Catalyst: Extremely Facile Decarbonylation of Pentafluorobenzoyl-Pd Complex Relevant to C6F5SiMe3 Formation (2006)
  • Author(s): Kashiwabara Taigo, Tanaka Masato
  • Journal Title: Organometallics 25 Pages: 4648-4652
  • Peer Reviewed
• [Presentation] Disilylbenzenes: Rich Sources for Silyl-Metals of Unusual Structures (2008)
  • Author(s): Masato Tanaka
  • Organizer: International conference on organometallic and coordination chemistry
  • Place of Presentation: Nizhny Novgorod, Russia
  • Year and Date: 20080902-20080908
• [Presentation] Palladium-Catalyzed Addition-Cyclization Reaction of Diphenyl phosphine Oxide with Diynes in the Presence of Phosphinic Acid (2008)
  • Author(s): Masato Tanaka
  • Organizer: The 16th International Symposium on Homogeneous Catalysis
  • Place of Presentation: Florence, Italy
  • Year and Date: 20080706-11
• [Presentation] Catalytic Reactions of Hydrooligosilanes (2008)
  • Author(s): Masato Tanaka
  • Organizer: The 15th International Symposium on Organosilicon Chemistry
  • Place of Presentation: Jeju, Korea
  • Year and Date: 20080601-06
• [Presentation] Selective Markovnikov Addition of P-H Bond to Terminal Alkynes and Related Reactions (2007)
  • Author(s): Masato Tanaka
  • Organizer: International Symposium on Catalysis and Fine Chemicals 2007
  • Place of Presentation: Singapore
  • Year and Date: 20071217-20071221
• [Presentation] Recent progress in H-P bond addition catalysis (2006)
  • Author(s): Masato Tanaka
  • Organizer: The 15th International Symposium on Homogeneous Catalysis
  • Place of Presentation: Sun City, South Africa
  • Year and Date: 20060820-20060825
• [Remarks] ホームページ
  • URL: http://www.res.titech.ac.jp/~gosei/tanaka/index.html
• [Patent(Industrial Property Rights)] (Z,Z)-1,4-ジハロ-1,3-ブタジエン化合物の製造方法 (2008)
  • Inventor(s): 田中正人、柏原泰吾
  • Industrial Property Rights Holder: 東京工業大学
  • Industrial Property Number: 特許,特願2008-200200
  • Filing Date: 2008-07-04
• [Patent(Industrial Property Rights)] 分枝鎖状アルケニルホスフィンオキシド化合物の製造方法 (2007)
  • Inventor(s): 田中正人、N. Satish Kumar、田中良典
  • Industrial Property Rights Holder: 東京工業大学と大八化学との共願
  • Industrial Property Number: 特許・特願2007-059928
  • Filing Date: 2007-03-09
• [Patent(Industrial Property Rights)] 1,2-ビス(ジアリールホスフィニル)エテン骨格を有する化合物の製造方法 (2007)
  • Inventor(s): 田中正人、田中良典
  • Industrial Property Rights Holder: 東京工業大学と大八化学との共願
  • Industrial Property Number: 特許・特願2007-53468
  • Filing Date: 2007-03-02
• [Patent(Industrial Property Rights)] 1,4-ジクロロ-3-ブテン-2-オン化合物及びその製造方法 (2007)
  • Inventor(s): 田中正人、柏原泰吾
  • Industrial Property Rights Holder: 東京工業大学
  • Industrial Property Number: 特許・特願2007-054811
  • Filing Date: 2007-02-05
• [Patent(Industrial Property Rights)] 有機リン置換ピロール化合物及びその製造方法 (2007)
  • Inventor(s): 田中正人、N. Satish Kumar、田中良典
  • Industrial Property Rights Holder: 東京工業大学と大八化学との共願
  • Industrial Property Number: 特許・特願2007-31226
  • Filing Date: 2007-02-09