Chemistry of Concerto Catalysis

2009 Fiscal Year Final Research Report

• Project/Area Number: 18065010
• Research Category: Grant-in-Aid for Scientific Research on Priority Areas
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Tokyo Institute of Technology
• Principal Investigator: IKARIYA Takao Tokyo Institute of Technology, 大学院・理工学研究科, 教授 (30107552)
• Co-Investigator(Kenkyū-buntansha): 水野 哲孝 東京大学, 大学院・工学系研究科, 教授 (50181904) ; 金田 清臣 大阪大学, 太陽エネルギー化学研究センター, 教授 (90029554) ; 小江 誠司 九州大学, 未来化学創造センター, 教授 (60290904) ; 小宮 三四郎 東京農工大学, 大学院・共生科学技術研究院, 教授 (00111667)
• Project Period (FY): 2006 – 2010
• Keywords: 触媒設計・反応 / 錯体・有機金属触媒 / 環境調和型反応 / 選択的合成・反応 / 不斉合成・反応 / 生物的合成手法

Research Abstract

This research area has focused on exploring conceptually new concerto catalysis and has successfully developed highly efficient and practical catalyst systems on the basis of an appreciable improvement in the performance of molecular catalysts in terms of reactivity and selectivity, a significant accumulation of knowledge of multimetallic catalyst systems, a molecular-or nano-level designing of the heterogeneous catalysts, and well considered integration of biocatalysts and chemocatalysts. The newly developed powerful concerto catalysis can provide a great leap towards the goal of organic synthetic chemistry as well as sustainable and green production processes.

Research Products

• [Journal Article] Concerto Catalysis-Harmonising [NiFe]- hydrogenase and NiRu Model Catalysts. (2010)
  • Author(s): Ichikawa, K., Nonaka, K., Matsumoto T., Kure, B., Yoon, K.-S., Higuchi, Y., Yagi, T., Ogo, S.
  • Journal Title: Dalton Trans 39 Pages: 2993-2994
• [Journal Article] Electrons form Hydrogen. (2009)
  • Author(s): Ogo, S.
  • Journal Title: Chem.Commun. Pages: 3317-3325
• [Journal Article] Hydrogenation of N-Acylcarbamates and sulfonamides Catalyzed by Bifunctional Cp*Ru(PN) Complex. (2009)
  • Author(s): Ito, M., Koo, L.W., Himizu, A., Kobayashi, C., Sakaguchi, A., Ikariya, T.Angew.Chem.
  • Journal Title: Int.Ed. 48 Pages: 1324-1327
• [Journal Article] Hydrogen- and Oxygen-Driven Interconversion between Imido-Bridged Dirhodium(III) and Amido-Bridged Dirhodium(II) Complexes. (2009)
  • Author(s): Ishiwata, K., Kuwata, S., Ikariya, T.J.Am.Chem.
  • Journal Title: Soc. 131 Pages: 5001-5009
• [Journal Article] Cucurbit[n]uril-Polyoxoanion Hybrids. (2009)
  • Author(s): Fang, X., Kogerler, P., Isaacs, L., Uchida, S., Mizuno, N.J.Am.Chem.
  • Journal Title: Soc. 131 Pages: 432-433
• [Journal Article] Hydrogen-Bond-Assisted Epoxidation of Homoallylic and Allylic Alcohols with Hydrogen Peroxide Catalyzed by Selenium-Containing Dinuclear Peroxotungstate. (2009)
  • Author(s): Kamata, K., Hirano, T., Kuzuya, S., Mizuno, N.J.Am.Chem.
  • Journal Title: Soc. 131 Pages: 6997-7004
• [Journal Article] Efficient Catalytic Syntheshesynthesessy Amines from Alcohols and Urea. (2009)
  • Author(s): He, J., Kim, J.W., Yamaguchi, K., Mizuno, N.Angew.Chem.
  • Journal Title: Int.Ed. 48 Pages: 9888-9891
• [Journal Article] Synthesis and Organic Group Transfer of Organodiplatinum Complex with a 1, 2-Bis(diphenylphosphino)ethane Ligand. (2009)
  • Author(s): Komine, N., Ishiwata, T., Kasahara, J.-y., Matsumoto, E., Hirano, M., Komiya, S.Can.J.Chem.
  • Journal Title: 87 Pages: 176-182
• [Journal Article] Synthesis of Heterodinuclear (Carbene) platinum (or Palladium) Complex That Gives μ-Alkenyl-Type Complex by Deprotonation. (2009)
  • Author(s): Tanaka, S., Komine, N., Hirano, M., Komiya
  • Journal Title: S.Organometallics 28 Pages: 5368-5381
• [Journal Article] Supported Silver Nanoparticle Catalyst for Selective Hydration of Nitriles to Amides in Water. (2009)
  • Author(s): Mitsudome, T., Mikami, Y., Mori, H., Arita, S., Mizugaki, T., Jitsukawa, K., Kaneda, K.
  • Journal Title: Chem.Commun. Pages: 3258-3260
• [Journal Article] Aerobic Oxidative Kinetic Resolution of Racemic Secondary Alcohols with Chiral Bifunctional Amido Complexes. (2008)
  • Author(s): Arita, S., Koike, T., Kayaki, Y., Ikariya, T.
  • Journal Title: Angew.Chem.Int.Ed. 47 Pages: 2447-2449
• [Journal Article] Enantioselective Direct Amination of α-Cyanoacetates Catalyzed by Bifunctional Chiral Ru and Ir Amido Complexes. (2008)
  • Author(s): Hasegawa, Y., Watanabe, M., Gridnev, I.D., Ikariya, T.J.
  • Journal Title: Am.Chem.Soc. 130 Pages: 2158-2159
• [Journal Article] Highly Selective Sorption of Small Unsaturated Hydrocarbons by Non-Porous Flexible Framework with Silver Ion. (2008)
  • Author(s): Uchida, S., Kawamoto, R., Tagami, H., Nakagawa, Y., Mizuno, N.J.
  • Journal Title: Am.Chem.Soc. 130 Pages: 12370-12376
• [Journal Article] E-Selective Allyl Transfer Reaction in a μ-η1:η2-Crotylplatinum-Cobalt Complex. (2008)
  • Author(s): Komine, N., Hirota, T., Hirano, M., Komiya, S.
  • Journal Title: Organometallics 27 Pages: 2145-2148
• [Journal Article] Oxidant-Free Alcohol Dehydrogenation Using a Reusable Hydrotalcite-Supported Silver Nanoparticle Catalyst. (2008)
  • Author(s): Mitsudome, T., Mikami, Y., Funai, H., Mizugaki, T., Jitusukawa, K., Kaneda, K.
  • Journal Title: Angew.Chem.Int.Ed. 47 Pages: 138-141
• [Journal Article] Supported Silver Nanoparticles-Catalyzed Highly Efficient Oxidation of Phenylsilanes to Silanols in Water (2008)
  • Author(s): Mitsudome, T., Arita, S., Mori, H., Mizugaki, T., Jitsukawa, K., Kaneda, K.
  • Journal Title: Angew.Chem.Int.Ed. 47 Pages: 7938-7940
• [Journal Article] Isolation and Crystal Structures of Both Enol and Keto Tautomer Intermediates in a Hydration of an Alkyne-Carboxylic Acid Ester Catalyzed by Iridium Complexes in Water. (2008)
  • Author(s): Kanemitsu, H., Uehara, K., Fukuzumi, S., Ogo, S.
  • Journal Title: J.Am.Chem.Soc. 130 Pages: 17141-17147
• [Journal Article] Montmorillonite-Entrapped Sub-nanoordered Pd Clusters as a Heterogeneous Catalyst for Allylic Substitution Reactions. (2007)
  • Author(s): Mitsudome, T., Nose, K., Mori, K., Mizugaki, T., Ebitani, K., Jitsukawa, K., Kaneda, K.
  • Journal Title: Angew.Chem.Int.Ed. 46 Pages: 3288-3290
• [Journal Article] Asymmetric Transfer Hydrogenation of Ketones with Bifunctional Transition Metal-based Molecular Catalysts. (2007)
  • Author(s): Ikariya, T., Blacker, A.
  • Journal Title: J.Acc.Chem.Res. 40 Pages: 1300-1308
• [Journal Article] A Dinuclear Ni(μ-H)Ru Complex Derived from H2.Ogo (2007)
  • Author(s): S.Kabe, R.Uehara, K.Kure, B.Nishimura, T.Menon, S.C.Harada, R.Fukuzumi, S.Higuchi, Y.Ohhara, T.Tamada, T.Kuroki
  • Journal Title: R.Science 316 Pages: 585-587
• [Journal Article] Bifunctional Transition Metal-based Molecular Catalysts for Asymmetric Syntheses. (2006)
  • Author(s): Ikariya, T., Murata, K., Noyori, R.
  • Journal Title: Org.Biomol.Chem. 4 Pages: 393-406
• [Presentation] Green Oxidation Reactions by Polyoxometalate-Based Catalysts : From Molecular to Solid Catalysts (2009)
  • Author(s): Noritaka Mizuno
  • Organizer: International Symposium on Relations between Homogeneous and Heterogeneous Catalysis XIV
  • Place of Presentation: Stockholm, Sweden
  • Year and Date: 20091917
• [Presentation] Recent Progress in Concerto Molecular Catalysis, International Symposium on Homogeneous and Heterogeneous Catalysis XIV (2009)
  • Author(s): Takao Ikariya
  • Organizer: Stockholm
  • Place of Presentation: Sweden
  • Year and Date: 2009-09-13
• [Presentation] An Efficient Oxidative Alkyne-Alkyne Homocoupling by a Dicopper-Substituted Silicotungstate (2009)
  • Author(s): Noritaka Mizuno
  • Organizer: 6th World Congress on Oxidation Catalysis, Lille
  • Place of Presentation: France
  • Year and Date: 2009-07-07
• [Presentation] Recent Progress in Chiral Bifunctional Molecular Catalysis (2008)
  • Author(s): Takao Ikariya
  • Organizer: XXIII International Conference on Organometallic Chemistry, Rennes
  • Place of Presentation: France
  • Year and Date: 20080713-20080718
• [Presentation] Chiral Bifunctional Molecular Catalysts for Reductive and Oxidative Trans- formation (2008)
  • Author(s): Takao Ikariya
  • Organizer: International Symposium on Homogeneous Catalysis XVI, Florence
  • Place of Presentation: Italy
  • Year and Date: 20080706-20080711
• [Presentation] Activation of Hydrogen in Water (2008)
  • Author(s): Seiji Ogo
  • Organizer: International Symposium on Bioorganometallic Chemistry (ISBOMC'08)
  • Place of Presentation: Montana, USA
  • Year and Date: 2008-07-10
• [Presentation] ~Concerto Catalysts~ Development of Heterogeneous Metal Catalysts Using Inorganic Crystallites (2007)
  • Author(s): Kiyotomi Kaneda
  • Organizer: The Eighth International Symposium on Catalysis Applied to Fine Chemicals
  • Place of Presentation: Verbania, Italy
  • Year and Date: 20070916-20090920
• [Book] Modern Heterogeneous Oxidation Catalysis (ed.By N.Mizuno)(Liquid-Phase Oxidations with Hydrogen Peroxide and Molecular Oxygen Catalyzed by Polyoxometalate-Based Compounds) (2009)
  • Author(s): Noritaka Mizuno, et al
  • Total Pages: 185-216
  • Publisher: Wiley-VCH
• [Book] Modern Heterogeneous Oxidation Catalysis (ed.By N.Mizuno)(Design of Well-Defined Active Sites on Crystalline Materials for Liquid-Phase Oxidation) (2009)
  • Author(s): Kiyotomi Kaneda, et al
  • Total Pages: 157-183
  • Publisher: Wiley-VCH
• [Remarks]
  • URL: http://concerto.cstm.kyushu-u.ac.jp/index.html
• [Patent(Industrial Property Rights)] エステル類およびラクトン類の実用的な還元方法 (2009)
  • Inventor(s): 碇屋隆雄、伊藤正人、椎橋彬、大塚隆史
  • Industrial Property Rights Holder: 東工大, 他
  • Industrial Property Number: 特願2009150401
  • Filing Date: 2009-06-25
• [Patent(Industrial Property Rights)] アミド類およびラクタム類の実用的な還元方法 (2009)
  • Inventor(s): 碇屋隆雄、伊藤正人、大塚隆史
  • Industrial Property Rights Holder: 東工大, 他
  • Industrial Property Number: 特願2009285820
  • Filing Date: 2009-12-17
• [Patent(Industrial Property Rights)] エステル化合物の水素化によるアルコールの製造方法 (2008)
  • Inventor(s): 碇屋隆雄、伊藤正人、椎橋彬
  • Industrial Property Rights Holder: 東工大, 他
  • Industrial Property Number: 特願2008177857
  • Filing Date: 2008-01-04