Synthesis of Bimetallic Complexes Activated by Tridentate Ligands

2008 Fiscal Year Self-evaluation Report

• Project/Area Number: 18065011
• Research Category: Grant-in-Aid for Scientific Research on Priority Areas
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Nagoya University
• Principal Investigator: NISHIYAMA Hisao Nagoya University, 大学院工学研究科, 教授 (40135421)
• Project Period (FY): 2006 – 2009
• Keywords: 合成化学 / 触媒化学 / 不斉合成

Research Abstract

新規設計による窒素系三座配位子を合成し協奏的な機能をよりどころにして単金属あるいは多金属連携による高触媒活性な分子触媒の開発を目指す。大量合成にも耐えうる実践的な炭素分子骨格構築法ならびに官能基変換法の開発を目指す。

Research Products

• [Journal Article] Intermolecular Antiselective and Enantioselective Reductive Coupling of Enones and Aromatic Aldehydes with Rh(Phebox) Catalysts (2009)
  • Author(s): T.Shiomi, T.Adachi, J.Ito, H.Nishiyama
  • Journal Title: Org.Lett. 11 Pages: 1011-1014
  • Peer Reviewed
• [Journal Article] A New NCN Pincer Ruthenium Complex and its Catalytic Activity for Enantioselective Hydrogenation of Ketones (2008)
  • Author(s): J.Ito, S.Ujiie, H.Nishiyama
  • Journal Title: Chem.Commun. Pages: 1823-1925
  • Peer Reviewed
• [Journal Article] Intermolecular Asymmetric Reducive Aldol Reaction of Ketones as Acceptors Promoted by Chiral Rh(Phebox) (2007)
  • Author(s): T.Shiomi, H.Nishiyama
  • Journal Title: Org. Lett. 9 Pages: 1651-1654
  • Peer Reviewed
• [Journal Article] An Iron-catalysed Hydrosilylation of Ketones (2007)
  • Author(s): H.Nishiyama, A.Furuta
  • Journal Title: Chem. Commun. Pages: 760-762
  • Peer Reviewed
• [Journal Article] A Carbon-Carbon Bond Formation on Bis(oxazolinyl)phenyl-Rhodium Complex in Reduction and Oxidative Sequence (2006)
  • Author(s): J.Ito, T.Miyakawa, H.Nishiyama
  • Journal Title: Organometallics 25 Pages: 5216-5218
  • Peer Reviewed
• [Journal Article] Efficient Preparation of New RHodiumand Iridium-[bis(oxazolinyl)-3,5-dimethyl] Complexes by C-H Bond Activation. An Application in Asymmetric Catalysis (2006)
  • Author(s): J.Ito, T.Shiomi, H.Nishiyama
  • Journal Title: Adv.Synth.Catal. 348 Pages: 1235-1240
  • Peer Reviewed
• [Presentation] 光学活性Phebox-Ru錯体の合成と反応性 (2008)
  • Author(s): 氏家諭史、伊藤淳一、西山久雄
  • Organizer: 日本化学会第88春季年会
  • Year and Date: 20080300
• [Presentation] 不斉還元アルドール反応ー脱ヒドロキシル化連続反応によるα置換ジヒドロケイ皮酸誘導体の合成 (2007)
  • Author(s): 橋本徹、西山久雄
  • Organizer: 日本化学会第87回春季年会
  • Year and Date: 20070300
• [Presentation] 不斉オキサゾリンーロジウム錯体を用いる還元的アルドール反応 (2006)
  • Author(s): 塩見拓史、伊藤淳一、西山久雄
  • Organizer: 第37回中部化学関係学協会支部連合秋季大会
  • Year and Date: 20061100
• [Book] Transition-metal Lewis Acids : From Vanadium to Platinum, "Acid Catalysis in Modern Organic Synthesis", (2008)
  • Author(s): S,Iwasa, H.Nishiyama
  • Total Pages: 859-901
  • Publisher: Eds.H.Yamamoto, K.Ishihara, Wiley-VCH Verlag GmbH & Co.KGaA, Weinheim
• [Book] Reductive Aldol, Michael, and Mannich Reactions, "Top. Curr. Chem. : Metal Catalyzed Reductive C-C Bond Formation" (2007)
  • Author(s): H.Nishiyama, T.Shiomi
  • Total Pages: 105-137
  • Publisher: M.J.Krische, Springer-Verlag, Berlin, 279