2009 Fiscal Year Final Research Report
Synthesis of Bimetallic Complexes Activated by Tridentate Ligands
| Project/Area Number |
18065011
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| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Nagoya University |
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Principal Investigator |
NISHIYAMA Hisao Nagoya University, 大学院・工学研究科, 教授 (40135421)
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| Project Period (FY) |
2006 – 2009
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| Keywords | 合成化学 / 触媒化学 / 不斉合成 |
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| Research Abstract |
On the basis of Concerto Catalysis, new types of tridentate nitrogen-based ligands have been developed to show high catalytic activities in the combination of rhodium and ruthenium atoms. The catalysts exhibited high efficiencies in product and optical yields for reduction- or C-H bond activation based asymmetric carbon bond formations such as reductive aldol couplings, asymmetric hydrogenation, asymmetric transfer hydrogenation, asymmetric cyclopropanation, asymmetric direct aldol reaction.
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