2009 Fiscal Year Final Research Report
New Approaches for Creating New Phosphines and Their Applications
Project/Area Number |
18065014
|
Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
|
Allocation Type | Single-year Grants |
Review Section |
Science and Engineering
|
Research Institution | Kyoto University |
Principal Investigator |
OSHIMA Koichiro Kyoto University, 大学院・工学研究科, 教授 (00111922)
|
Project Period (FY) |
2006 – 2009
|
Keywords | 選択的合成・反応 |
Research Abstract |
Due to the importance of organophosphines as ligands for transition metal catalysts, development of efficient methods for the synthesis of new phosphines is very important. We recognized 1-alkynylphosphines and their derivatives as useful precursors for creation of new phosphines. Chemical modifications of the carbon-carbon triple bonds, including nucleophilic addition and cycloaddition, led to a wide range of new useful phosphines that are otherwise difficult to synthesize.
|
Research Products
(8 results)