Development of Integrated Heterogeneous Catalysts for Environmentally Benign Molecular Transformation System Based on the Surface Properties

2009 Fiscal Year Final Research Report

• Project/Area Number: 18065016
• Research Category: Grant-in-Aid for Scientific Research on Priority Areas
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Osaka University
• Principal Investigator: KANEDA Kiyotomi Osaka University, 太陽エネルギー化学研究センター, 特任教授 (90029554)
• Co-Investigator(Kenkyū-buntansha): JITSUKAWA Koichiro 大阪大学, 基礎工学研究科, 教授 (50235793) ; MIZUGAKI Tomoo 大阪大学, 基礎工学研究科, 准教授 (50314406) ; MITSUDOME Takato 大阪大学, 基礎工学研究科, 助教 (00437360)
• Project Period (FY): 2006 – 2009
• Keywords: ハイドロキシアパタイト / モンモリロナイト / ハイドロタルサイト / 金属ナノ粒子 / マクロリガンド / 機能集積触媒 / 環境調和型分子変換

Research Abstract

We have developed highly functionalized heterogeneous metal catalysts based on unique characteristics of inorganic materials such as hydroxyapatite, montmorillonite, and hydrotalcite. These inorganic crystallites are used as macro ligands for active metal species, which are considered as advanced nano-structured catalyst supports. The characteristic features of these catalysts are based on the concerto effect between active metal species and surface properties, such as acidity, basicity, and site isolation, where cooperative catalysis by several immobilized active species on the solid surface can occur.

Research Products

• [Journal Article] Wacker-Type Oxidation of Internal Olefins Using a PdCl2/N, N-Dimethylacetamide Catalyst System under Copper-Free Reaction Conditions (2010)
  • Author(s): Mitsudome, T.; Mizumoto, K.; Mizugaki, T.; Jitsukawa, K.; Kaneda, K.
  • Journal Title: Angew. Chem. Int. Ed. 49 Pages: 1238-1240
  • Peer Reviewed
• [Journal Article] Supported Gold Nanoparticles as a Reusable Catalyst for Synthesis of Lactones from Diols Using Molecular Oxygen as an Oxidant under Mild Conditions (2009)
  • Author(s): Mitsudome, T.; Noujima, A.; Mizugaki, T.; Jitsukawa, K.; Kaneda, K.
  • Journal Title: Green Chem. 11 Pages: 793-797
  • Peer Reviewed
• [Journal Article] Supported Silver Nanoparticle Catalyst for Selective Hydration of Nitriles to Amides in Water (2009)
  • Author(s): Mitsudome, T.; Mikami, Y.; Mori, H.; Arita, S.; Mizugaki, T.; Jitsukawa, K.; Kaneda, K.
  • Journal Title: Chem. Commun. Pages: 3258-3260
  • Peer Reviewed
• [Journal Article] Supported Gold Nanoparticle Catalyst for the Selective Oxidation of Silanes to Silanols in Water (2009)
  • Author(s): Mitsudome, T.; Noujima, A.; Mizugaki, T.; Jitsukawa, K.; Kaneda, K.
  • Journal Title: Chem. Commun. Pages: 5302-5304
  • Peer Reviewed
• [Journal Article] Efficient Aerobic Oxidation of Alcohols using a Hydrotalcite-Supported Gold Nanoparticle Catalyst (2009)
  • Author(s): Mitsudome, T.; Noujima, A.; Mizugaki, T.; Jitsukawa, K.; Kaneda, K.
  • Journal Title: Adv. Synth. Catal. 351 Pages: 1890-1896
  • Peer Reviewed
• [Journal Article] Oxidant-Free Alcohol Dehydrogenation Using a Reusable Hydrotalcite-Supported Silver Nanoparticle Catalyst (2008)
  • Author(s): Mitsudome, T.; Mikami, Y.; Funai, H.; Mizugaki, T.; Jitusukawa, K.; Kaneda, K.
  • Journal Title: Angew. Chem. Int. Ed. 47 Pages: 138-141
  • Peer Reviewed
• [Journal Article] Supported Silver Nanoparticles-Catalyzed Highly Efficient Oxidation of Phenylsilanes to Silanols in Water (2008)
  • Author(s): Mitsudome, T.; Arita, S.; Mori, H.; Mizugaki, T.; Jitsukawa, K.; Kaneda, K.
  • Journal Title: Angew. Chem. Int. Ed. 47 Pages: 7938-7940
  • Peer Reviewed
• [Journal Article] PAMAM Dendron-Stabilised Palladium Nanoparticles: Effect of Generation and Peripheral Groups on Particle Size and Hydrogenation Activity (2008)
  • Author(s): Mizugaki, T.; Murata, M.; Fukubayashi, S.; Mitsudome, T.; Jitsukawa, K.; Kaneda, K.
  • Journal Title: Chem. Commun. Pages: 241-243
  • Peer Reviewed
• [Journal Article] Development of Ruthenium-Hydroxyapatite Encapsulated Superparamagneticγ-Fe2O3 Nanocrystallites as an Efficient Oxidation Catalyst by Molecular Oxygen (2007)
  • Author(s): Mori, K.; Kanai, S.; Hara, T.; Mizugaki, T.; Ebitani, K.; Jitsukawa, K.; Kaneda, K.
  • Journal Title: Chem. Mater. 19 Pages: 1249-1256
  • Peer Reviewed
• [Journal Article] Montmorillonite-Entrapped Sub-nanoordered Pd Clusters as a Heterogeneous Catalyst for Allylic Substitution Reactions (2007)
  • Author(s): Mitsudome, T.; Nose, N.; Mori, K.; Mizugaki, T.; Ebitani, K.; Jitsukawa, K.; Kaneda, K.
  • Journal Title: Angew. Chem. Int. Ed. 46 Pages: 3288-3290
  • Peer Reviewed
• [Journal Article] Nucleophilic Substitution Reactions of Alcohols Using Montmorillonite Catalysts as Solid Bronsted Acids (2007)
  • Author(s): Motokura, K.; Nakagiri, N.; Mizugaki, T.; Ebitani, K.; Kaneda, K.
  • Journal Title: J. Org. Chem. 72 Pages: 6006-6015
  • Peer Reviewed
• [Journal Article] Environmentally Friendly One-pot Synthesis of α-Alkylated Nitriles Using Hydrotalcite-Supported Metal Species as Multifunctional Solid Catalysts (2006)
  • Author(s): Motokura, K.; Fujita, N.; Mori, K.; Mizugaki, T.; Ebitani, K.; Jitsukawa, K.; Kaneda, K.
  • Journal Title: Chem. A Eur. J. 12 Pages: 8228-8239
  • Peer Reviewed
• [Journal Article] Bronsted Acid-mediated heterogeneous addition reaction of 1, 3-dicarbonyls to Alkenes and alcohols (2006)
  • Author(s): Motokura, K.; Fujita, K.; Mori, K.; Mizugaki, T.; Ebitani, K.; Kaneda, K.
  • Journal Title: Angew. Chem. Int. Ed. 45 Pages: 2605-2609
  • Peer Reviewed
• [Journal Article] Convenient and efficient Pd-catalyzed regioselective oxyfunctionalization of terminal olefins by using molecular oxygen as sole reoxidant (2006)
  • Author(s): Mitsudome, T.; Umetani, T.; Nosaka, N.; Mori, K.; Mizugaki, T.; Ebitani, K.; Kaneda, K.
  • Journal Title: Angew. Chem. Int. Ed. 45 Pages: 481-485
  • Peer Reviewed
• [Journal Article] Design of High-Performance Heterogeneous Metal Catalysts for Green and Sustainable Chemistry (2006)
  • Author(s): Kaneda, K.; Ebitani, K.; Mizigaki, T.; Mori, K.
  • Journal Title: Bull. Chem. Soc. Jpn. 79 Pages: 981-1016
  • Peer Reviewed
• [Presentation] ~Concerto Catalysts~ Development of Heterogeneous Metal Catalysts Using Inorganic Crystallites (2007)
  • Author(s): Kaneda, K.
  • Organizer: The Eighth International Symposium on catalysis Applied to Fine Chemicals
  • Place of Presentation: Verbania
  • Year and Date: 2007-09-20
• [Presentation] Inorganic Crystalline-Supported Metal Complex Catalysts for Environmentally Benign Organic Synthesis (2006)
  • Author(s): Kaneda, K.
  • Organizer: 1st International IUPAC Conference on Green-Sustainable Chemistry
  • Place of Presentation: Dresden. (Keynote)
  • Year and Date: 2006-09-11
• [Book] design, reactions, and characterization(Mizuno, N. Ed., Design of Well-defined Active Sites on Crystalline Materials for Liquid Phase Oxuidations. In Modern Heterogeneous Oxidation Catalysis) (2009)
  • Author(s): Kaneda, K.; Mitsudome, T.
  • Total Pages: 157-183
  • Publisher: Wiley-VCH
• [Book] 無機結晶表面を配位子とする固定化金属触媒の創製と環境調和型物質変換反応への展開, 固定化触媒のルネサンス (2007)
  • Author(s): 金田清臣, 森浩亮, 海老谷幸喜, 水垣共雄
  • Total Pages: 76-84
  • Publisher: シーエムシー出版
• [Remarks] 新聞報道
• [Remarks] (1)化学工業日報(平成19年8月1日)「Pdナノ粒子を三角錐型に」
• [Remarks] (2)化学工業日報(平成19年5月31日)「酸化剤不要の新触媒」
• [Remarks] 商品化
• [Remarks] (1)RuHAP-Fe_2O_3和光純薬工業(187-02261)
• [Remarks] (2)VAP和光純薬工業(037-20751)
• [Remarks] (3)Ag/HAP和光純薬工業(086-09081)