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2009 Fiscal Year Final Research Report

Reaction dynamics of transition metal atoms

Research Project

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Project/Area Number 18066014
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionUniversity of Hyogo

Principal Investigator

HONMA Kenji  University of Hyogo, 大学院・物質理学研究科, 教授 (30150288)

Co-Investigator(Kenkyū-buntansha) GEJO Tatsuo  兵庫県立大学, 大学院・物質理学研究科, 准教授 (20290900)
MATSUMOTO Yoshiteru  兵庫県立大学, 大学院・物質理学研究科, 助教 (30360051)
Project Period (FY) 2006 – 2009
Keywords化学反応動力学
Research Abstract

Transition metal atoms(TM) play important roles in various catalytic reactions. In this research project, the collisions and reactions of the TM atoms with molecules were studied experimentally to clarify the mechanism of the catalytic abilities of TM. One characteristics of the TM atoms is the electronic structure. It can be easily mediated by the presence of other molecules, reactants. Here, a crossed-beam technique was used to study the collision of TM with O_2 under single collision condition and velocity/angular distributions of products were determined. These information were useful to clarify the interaction between TM and O_2 and the presence of intermediates.

  • Research Products

    (18 results)

All 2011 2010 2009 2008 2007 2006 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (7 results) Book (2 results) Remarks (1 results)

  • [Journal Article] Time-sliced velocity imaging study of reaction Y + O_2 → YO + O2011

    • Author(s)
      Kenji Honma, Yoshiteru Matsumoto
    • Journal Title

      Phys.Chem.Chem.Phys. 13

      Pages: 8236-8244

    • Peer Reviewed
  • [Journal Article] Hydrogen-bonded structures of the pyrrole-solvent clusters : Infrared cavity ringdown spectroscopy and quantum chemical calculations2009

    • Author(s)
      Yoshiteru Matsumoto, Kenji Honma
    • Journal Title

      J.Chem.Phys. 130

      Pages: 054311(11)

    • Peer Reviewed
  • [Journal Article] Excited state reaction dynamics of Ti(a^5F_J) + O_2 → TiO(A,B) + O studied by a crossed-beam technique2009

    • Author(s)
      Ryo Yamashiro, Yoshiteru Matsumoto, Kenji Honma
    • Journal Title

      J.Chem.Phys. 131

      Pages: 044316(6)

    • Peer Reviewed
  • [Journal Article] Hydrogen bonding in methanol clusters probed by inner-shell photoabsorption spectroscopy in the carbon and oxygen K-edge regions2008

    • Author(s)
      Y.Tamenori, K.Okada, O.Takahashi, S.Arakawa, K.Tabayashi, A.Hiraya, T.Gejo, K.Honma
    • Journal Title

      J.Chem.Phys. 128

      Pages: 124321(8)

    • Peer Reviewed
  • [Journal Article] Dynamics of reaction Si + O_2 → SiO + O studied by the crossed beam LIF technique2008

    • Author(s)
      R.Yamashiro, Y.Matsumoto, Kenji Honma
    • Journal Title

      J.Chem.Phys. 128

      Pages: 084308(6)

    • Peer Reviewed
  • [Journal Article] NH Stretching vibrations of pyrrole clusters studied by infrared cavity ringdown spectroscopy2007

    • Author(s)
      Yoshiteru Matsumoto, Kenji Honma
    • Journal Title

      J.Chem.Phys. 127

      Pages: 184310(9)

    • Peer Reviewed
  • [Journal Article] Reaction dynamics of V(a^4FJ)+NO → laser-induced fluorescence technique2006

    • Author(s)
      M.Ishida, R.Yamashiro, Y.Matsumoto, Kenji Honma
    • Journal Title

      J.Chem.Phys. 124

      Pages: 204316(7)

    • Peer Reviewed
  • [Journal Article] Inner-shell excitation spectroscopy and fragmentation of small hydrogen-bonded clusters of formic acid after core-excitations at the oxygen K-edge2006

    • Author(s)
      K.Tabayashi, K.Yamaoto, O.Takahashi, Y.Tamenori, J.Harris, T.Gejo, M.Iseda, T.Tamura, K.Honma, I.H.Suzuki, S.Nagaoka, T.Ibuki
    • Journal Title

      J.Chem.Phys. 125

      Pages: 194703(10)

    • Peer Reviewed
  • [Presentation] Reaction dynamics of gas-phase transition metal atoms2010

    • Author(s)
      Kenji Honma
    • Organizer
      Pacifichem 2010, Symposium on "Frontiers in State-to-State Dynamics"
    • Place of Presentation
      Honolulu, Hawaii
    • Year and Date
      20101215-20101220
  • [Presentation] Reaction dynamics of transition metal atoms studied by a crossed-beam technique2010

    • Author(s)
      Kenji Honma
    • Organizer
      The 69th Okazaki Conference
    • Place of Presentation
      Okazaki Conference Center
    • Year and Date
      20100221-20100223
  • [Presentation] 電子状態と反応性-遷移金属原子の反応ダイナミクス2010

    • Author(s)
      本間健二
    • Organizer
      化学反応のポテンシャル曲面とダイナミクス-加藤重樹先生の足跡をたどって
    • Place of Presentation
      京都大学理学研究科セミナーハウス
    • Year and Date
      2010-06-19
  • [Presentation] Reaction dynamics of transition metal atoms studied by crossed beam technique2009

    • Author(s)
      Kenji Honma
    • Organizer
      XXIII International Symposium on Molecular Beams
    • Place of Presentation
      Dalian
    • Year and Date
      20090601-20090605
  • [Presentation] Reaction Dynamics of Transition Metal Atoms Studied by Crossed Beam Technique2009

    • Author(s)
      Kenji Honma
    • Organizer
      The 13th East Asian Workshop on Chemical Reactions
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      20090318-20090320
  • [Presentation] Reaction dynamics of transition metal atoms studied by crossed beam technique2008

    • Author(s)
      Kenji Honma
    • Organizer
      The 8the Asian International Seminar on Atomic and Molecular Physics
    • Place of Presentation
      University of Western Australia, Perth
    • Year and Date
      20081124-20081128
  • [Presentation] Reaction dynamics studied by crossed-beam LIF technique : Si + O_2 → SiO + O2008

    • Author(s)
      Kenji Honma
    • Organizer
      The 12th East Asian Workshop on Chemical Reactions
    • Place of Presentation
      Korea University, Seoul
    • Year and Date
      20080319-20080321
  • [Book] 物質科学の世界(第12章「化学反応を分子レベルから眺める」)2010

    • Author(s)
      本間健二
    • Total Pages
      153-166
    • Publisher
      共立出版
  • [Book] Dynamics of oxidation reactions of gas-phase metal atoms studied by a crossed-beam LIF technique(in Gas Phase Molecular Reaction and Photodissociation Dynamics)(Ed.By K.C.Lin, Paul Kleiber)2007

    • Author(s)
      Kenji Honma
    • Total Pages
      227-265
    • Publisher
      Transworld Research Network
  • [Remarks] ホームページ等

URL: 

Published: 2012-02-13   Modified: 2016-04-21  

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