Dynamics and simultaneous evaluation of X-ray scattering and spectroscopy of structure formation and templating processes of super anisotropic nanocylinders

2008 Fiscal Year Self-evaluation Report

• Project/Area Number: 18101005
• Research Category: Grant-in-Aid for Scientific Research (S)
• Allocation Type: Single-year Grants
• Research Field: Nanomaterials/Nanobioscience
• Research Institution: Tokyo Institute of Technology
• Principal Investigator: IYODA Tomokazu Tokyo Institute of Technology, 資源化学研究所, 教授 (90168534)
• Project Period (FY): 2006 – 2010
• Keywords: ナノシリンダー構造 / ブロックコ ポリマー / X線散乱分光同時測定

Research Abstract

本研究は材料作製に効率よくフィードバックできる実験室仕様の薄膜小角X線散乱-分光同時測定システムを開発することにより、高分子ミクロ相分離構造形成を"なすがまま"から"思い通り"の自己組織化プロセスに進化させ、膨大な探索実験に代わるナノ構造製膜プロセスの効率よい最適化と指導原理を導くものである。

Research Products

• [Journal Article] Laboratory-GISAXS Measurements of Block Copolymer Films with Highly Ordered and Normally Oriented Nanocylinders (2009)
  • Author(s): Komura, M.; Watanabe, K.; Iyoda T.; Yamada, T.; Yoshida, H.; Iwasaki, Y.
  • Journal Title: Chem. Lett. 38(5) Pages: 408-409
  • Peer Reviewed
• [Journal Article] Nanostructured Titanium Oxide Fabricated via Block Copolymer Template (2009)
  • Author(s): Watanabe, R.; Iyoda, T.; Ito, K.
  • Journal Title: Electrochemistry 77(3) Pages: 214-218
  • Peer Reviewed
• [Journal Article] Tuning surface interactions to control shape and array behavior of diblock copolymer micelles on a silicon substrate (2009)
  • Author(s): Laskar, I. R.; Watanabe, S.; Hada, M.; Yoshida, H.; Li, J.; Iyoda, T.
  • Journal Title: Surface Science 603(4) Pages: 625-631
  • Peer Reviewed
• [Journal Article] Controlled homeotropic and homogeneous orientations for nanoscale phase-separated domain of light-emitting amphiphilic block copolymer bearing a 2,5-diarylthiazole moiet (2008)
  • Author(s): Mori, A.; Shikuma, J.; Kinoshita, M.; Ikeda, T.; Misaki, M.; Ueda, Y.; Komura, M.; Asaoka, S.; Iyoda, T.
  • Journal Title: Chemistry Letters 37(3) Pages: 272-273
  • Peer Reviewed
• [Journal Article] Smart block copolymer masks with molecule-transport channels for total wet nanopatterning (2008)
  • Author(s): Watanabe, R.; Kamata, K.; Iyoda, T.
  • Journal Title: Journal of Materials Chemistry 18(45) Pages: 5482-5491
  • Peer Reviewed
• [Journal Article] Order-order and order-disorder transitions in thin films of an amphiphilic liquid crystalline diblock copolymer (2008)
  • Author(s): Yoon, J.; Jung, S.Y.; Ahn, B.; Heo, K.; Jin, S.; Iyoda, T.; Yoshida, H.; Ree, M.
  • Journal Title: Journal of Physical Chemistry B 112(29) Pages: 8486-8495
  • Peer Reviewed
• [Journal Article] Highly ordered arrays of mesoporous silica nanorods with tunable aspect ratios from block copolymer thin films (2008)
  • Author(s): Chen, A.; Komura, M.; Kamata, K.; Iyoda, T.
  • Journal Title: Advanced Materials 20(4) Pages: 763
  • Peer Reviewed
• [Presentation] Block Copolymer Templating Processes for Highly Ordered Nanostructured Materials (2008)
  • Author(s): T. Iyoda, K. Ito
  • Organizer: UMRS-ICA2008, symposium EE
  • Place of Presentation: Nagoya.(招待)
  • Year and Date: 2008-12-12
• [Presentation] 高分子ナノ相分離構造テンプレートの創製 (2008)
  • Author(s): 彌田智一
  • Organizer: 日本化学会第2回関東支部大会 メソスケールの化学-ナノと実用を繋ぐ-
  • Place of Presentation: 桐生(招待)
  • Year and Date: 2008-09-19
• [Presentation] 高分子ナノ相分離構造テンプレートの創製 (2008)
  • Author(s): 彌田智一
  • Organizer: 日本ゴム協会
  • Place of Presentation: 東京(招待)
  • Year and Date: 2008-09-12
• [Book] Nano-Materials Research Toward Applications(Hideo Hosono)(Elsevior, Chapter) (2006)
  • Author(s): Kaori Kamata, Tomokazu Iyoda
  • Total Pages: 171-223
  • Publisher: Nanocylinder Array Structures in Functional Diblock Copolymers
• [Book] 高秩序ナノシリンダーアレイ構造薄膜の構築と光電気化学機能、「機能物質の集積膜と応用展開」(関隆広) (2006)
  • Author(s): 渡辺一史、彌田智一
  • Total Pages: 283-294
  • Publisher: シーエムシー出版