2010 Fiscal Year Final Research Report
Reaction Chemistry of Transition Metal Clusters
| Project/Area Number |
18105002
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| Research Category |
Grant-in-Aid for Scientific Research (S)
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
SUZUKI Hiroharu Tokyo Institute of Technology, 大学院・理工学研究科, 教授 (30106629)
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| Co-Investigator(Renkei-kenkyūsha) |
高尾 俊郎 東京工業大学, 大学院・理工学研究科, 准教授 (00313346)
大石 理貴 東京工業大学, 大学院・理工学研究科, 助教 (20376940)
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| Project Period (FY) |
2006 – 2010
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| Keywords | 金属クラスター / 多核クラスター / 多電子移動 / 多点相互作用 / 小分子活性化 |
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| Research Abstract |
We have systematically studied on the reaction chemistry of the transition metal polyhydride clusters for these five years in the quest to develop new and effective organic transformations achieved by the synergetic effect of the adjacent metal centers. And we have successfully achieved main subjects such as 1) synthesis of homo- and heterometallic clusters with higher nuclearity, 2) modification of the electronic and steric environment of the reaction site, 3) elucidation of the mechanism of the cluster reaction, and 4) development of new reactions catalyzed by the cluster complexes.
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Research Products
(18 results)
