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2007 Fiscal Year Final Research Report Summary

Research on Recycling and Resouae Recovery of Solid Wastes by Hydrothermal Nano-Process

Research Project

Project/Area Number 18201012
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental technology/Environmental materials
Research InstitutionNagoya University

Principal Investigator

ITOH Hideaki  Nagoya University, EcoTopia Science Institute, Emeritus Professor (60109270)

Co-Investigator(Kenkyū-buntansha) SASAI Ryo  Nagoya Univ, Graduate School of Eng, Associate Professor (60314051)
ITAKURA Takeshi  Nagoya Univ, EcoTbpia Science Institute, Research Assistant (20402498)
YOSHIDA Hisao  Nagoya Univ, Graduate Schcol of Eng, Associate Professor (80273267)
Project Period (FY) 2006 – 2007
KeywordsHydrothermal Nano-Process / Resource Recovery / Inorganic Solid Materials / Inorganic Wastewater / Hydrothermal Oxidation / Hydrothermal Mineralization
Research Abstract

Today, the resource depletion is one of the important issues of all over the world. In order to solve this issue, the higher-efficiency techniques for resource recovery from various solid wastes such as ceramics would be required. However, there are no techniques for recovering the variable resources from solid wastes, especially, ceramics, because most ceramics have relatively high stability for heat, mechanical stress and so on. In this research, we investigated on the development of the higher-efficiency techniques for valuable resource from ceramics such as cemented carbides, zirconia and magnet by the hydrothermal nano-process. To show that hydrothermal nano-process technique we proposed is one of key-technologies for solving the resource recovery issues, we investigated the following topics :
1.Hydrothermal mechanochemical nano-process
2.Hydrothermal oxidation nano-process
3.Hydrothermal mineralization nano-process
As a result of this research, we succeeded in recovering valuable res … More ources from the following wastes :
1.WO_3 powder and aqueous solution with Co ions were separated from WC-Co cemented carbide cutting tools by the hydrothermal oxidation treatment with acid aqueous solution.
2.Zrconia powder for sintering with yttrium was recovered from spent partially stabilized zirconia sintered compact by the hydrothermal and mechanochemical treatment.
3.Ferrite particles consisted of Fe and Mn could be recovered from spent toner carrier powder by the hydrothermal oxidation treatment with H_2O_2.
4.Neodymium oxalate was recovered from spent Nd-Fe-B permanent sintered magnet by the hydrothermal oxidation treatment with HC1 and oxalic acid.
5.Co-A1 composite-oxide could be recovered from spent cathode of the Li-secondary battery by the hydrothermal oxidation treatment.
6.Natural minerals could be recovered from wastewaters with various oxo-anions such as boron, fluorine, arsenic, etc. by the hydrothermal mineralization treatment with mineralizer such as hydrated lime and calcium chloride. Less

  • Research Products

    (52 results)

All 2008 2007 2006

All Journal Article (29 results) (of which Peer Reviewed: 13 results) Presentation (18 results) Book (3 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] A precipitation Method for Arsenite Ion in Aqueous Solution as Natural Mineral by Hydrothermal Mineralization2008

    • Author(s)
      Itakura, T.; Sasai, R.; Itoh, H.
    • Journal Title

      Journal of the Ceramic Society of Japan 116

      Pages: 234-238

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] A Precipitation Method for Arsenite Ion in Aqueous Solution as Natural Mineral by Hydrothermal Mineralization2008

    • Author(s)
      Itakura, T., Sasai, R., Itoh, H
    • Journal Title

      Journal of the Ceramic Society of Japan 116

      Pages: 234-238

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] ホウ素・ホウ化物の基礎と応用, シーエムシー出版2008

    • Author(s)
      Sasai, R., Itakura, T., Itoh, H
    • Journal Title

      ホウ素流出規制と排水処理・再資源化技術

      Pages: 357-365

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] 使用済み電子写真用トナーキャリアの水熱処理による再生2007

    • Author(s)
      笹井 亮;斉藤 剛;林 紘正;陌間元晴;岸本惣一郎;伊藤秀章
    • Journal Title

      Journal of Ceramics Society of Japan 115

      Pages: 222-226

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Recycling Process for Yttria-Stabilized Tetragonal Zirconia Ceramics Using A Hydrothermal Treatment2007

    • Author(s)
      KAMIYA, M.; MORI, Y.; KOJIMA, T.; SASAI, R.; ITOH, H.
    • Journal Title

      Journal of Material Cycles and Waste Management 9

      Pages: 27-33

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Detoxification of Antimonic Contaminated Water and Precipitation Recovery of Antimony by Mineralization under Hydrothermal Condition2007

    • Author(s)
      Itakura, T.; Sasai, R.; Itoh, H.
    • Journal Title

      Chemistry Letters, 34

      Pages: 524-525

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Arsenic Recovery from Water Containing Arsenite and Arsenate Ions by Hydrothermal Mineralization2007

    • Author(s)
      Itakura, T.; Sasai, R.; Itoh, H.
    • Journal Title

      Journal of Hazardous Materials 146

      Pages: 328-333

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Disintegration Process of Yttria-stabilized Zirconia Ceramics Using Hydrothermal Conditions2007

    • Author(s)
      Kojima, T.; Mori, Y.; Kamiya, M.; Sasai, R.; Itoh, H.
    • Journal Title

      Journal of Materials Science 42

      Pages: 6056-6061

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] In Site Solid/Liquid Separation Effect for High-Yield Recovery of Boron and Fluorine from Aqueous Media Containing Borate or Fluoroborate Ions2007

    • Author(s)
      Itakura, T.; Sasai, R.; Itoh, H.
    • Journal Title

      Bull. Chem. Soc. Jpn. 80

      Pages: 2014-2018

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] 使用済み電子写真用トナーキャリアの水熱処理による再生2007

    • Author(s)
      Sasai, R., Saitoh, T., Hayashi, H., Hazama, M., Kishimoto, S., Itoh, H
    • Journal Title

      Journal of Ceramics Society of Japan 115

      Pages: 222-226

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Recycling Process for Yttria-Stabilized Tetragonal Zirconia Ceramics Using A Hydrothermal Treatment2007

    • Author(s)
      Kamiya, M., Mori, Y, Kojima, T., Sasai, R., Itoh, H
    • Journal Title

      Journal of Materials Cycles and Waste Management 9

      Pages: 27-33

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Detoxification of Antimonic Contaminated Water and Precipitation Recovery of Antimony by Mineralization under Hydrothermal Condition2007

    • Author(s)
      Itakura, T., Sasai, R., Itoh, H
    • Journal Title

      Chemistiy Letters 34

      Pages: 524-525

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Arsenic Recovery from Water Containing Arsenite and Arsenate Ions by Hydrothermal Mineralization2007

    • Author(s)
      Itakura, T., Sasai, R., Itoh, H
    • Journal Title

      Journal of Hazardous Materials 146

      Pages: 328-333

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Disintegration Process of Yttria-Stabilized Zirconia Ceramics Using Hydrothermal Consitions2007

    • Author(s)
      Kojima, T., Mori, Y., Kamiya, M., Sasai, R., Itoh, H
    • Journal Title

      Journal of Materials Science 42

      Pages: 6056-6061

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] In Site Solid/Liquid Separation Effect for High-Yield Recovery of Boron and Fluorine from Aqueous Media Containing Borate or Fluoroborate Ions2007

    • Author(s)
      Itakura, T., Sasai, R., Itoh, H
    • Journal Title

      Bulletin of the Chemical Society of Japan 80

      Pages: 2014-2018

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] 排水・汚水処理技術集成, NTS2007

    • Author(s)
      Sasai, R., Itakura, T., Itoh, H
    • Journal Title

      加熱・加圧による廃水からのホウ素・フッ素およびヒ素の除去と資源回収

      Pages: 619-629

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] セラミックスデータブック2007工業と製品,(株)テクノプラザ(工業製品技術協会)2007

    • Author(s)
      Sasai, R., Itakura, T., Itoh, H
    • Journal Title

      Geo-Mimetic Technique による難処理性無機排水の処理と資源回収

      Pages: 100-104

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] セラミックスのニュープロセスとナノテクノロジー4.セラミックスの再生技術2006

    • Author(s)
      笹井 亮; 伊藤秀章
    • Journal Title

      材料 55(12)

      Pages: 1146-1150

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Resource recovery from Nd-Fe-B sintered magnet by hydrothermal treatment2006

    • Author(s)
      ITAKURA, R.; SASAI, R.; ITOH, H.
    • Journal Title

      Journal of Alloys and Compounds 408-412

      Pages: 1382-1385

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] 亜臨界水熱処理による超硬合金からのWO_3の回収2006

    • Author(s)
      笹井 亮, 稲垣文人, 高 寧峰, 伊藤秀章
    • Journal Title

      Journal of The Society of Materials Science Japan 55

      Pages: 254-257

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Lead Recovery from PBZrO_3 Using Wet Ball-Mill Technique and Hydrothermal Synthesis of α-Zirconium Phosphate from Wastewater for Resource Recovery2006

    • Author(s)
      KAMIYA, M.; SASAI. R.; ITOH, H.
    • Journal Title

      Journal of Hazardous Materials 134

      Pages: 67-73

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Novel Recovery Method for Treating Wastewater Containing and Fluoroboric Acid2006

    • Author(s)
      ITKURA, T.; SASAI, R.; ITOH, H.
    • Journal Title

      Bulletin of the Chemical Society of Japan 79

      Pages: 1303-1307

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Arsenic Recovery from Water Containing Arsenite Ions by Hydrothermal Mineral ization2006

    • Author(s)
      ITAKURA, T.; SASAI, R.; ITOH, H
    • Journal Title

      Chemistry Letters 35

      Pages: 2-3

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] セラミックスのニュープロセスとナノテクノロジー4.セラミックスの再生技術2006

    • Author(s)
      Sasai, R., Itoh, H
    • Journal Title

      Journal of The Society of Matprisle Science, Japan 55(12)

      Pages: 1146-1150

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Resource Recovery from Nd-Fe-B Sintered Magnet by Hydrothermal Treatment2006

    • Author(s)
      Itakura, T., Sasai, R., Itoh, H
    • Journal Title

      Journal of Alloys and Compounds

      Pages: 408-412, 1382-1385

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] 亜臨界水熱処理による超合金からのWO_3の回収2006

    • Author(s)
      Sasai, R., Inagaki, F., Gao, N-E., Itoh, H
    • Journal Title

      Journal of The Society of Materials Science Japan 55

      Pages: 254-257

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Lead Recovery from PbZrO_3 Using Wet Ball-Mill Technique and Hydrothermal Synthesis of α-Zirconium Phosphate from Wastewater for Resource Recovery2006

    • Author(s)
      Kamiya, M., Sasai, R., Itoh, H
    • Journal Title

      Journal of Hazardous Materials 134

      Pages: 67-73

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Novel Recovery Method for Treating Wastewater Containing Fluoride and Fluoroboric Acid2006

    • Author(s)
      Itakura, T., Sasai, R., Itoh, H
    • Journal Title

      Bulletin of the Chemical Society of Japan 79

      Pages: 1303-1307

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Arsenic Recovery from Water Containing Arsenite Ions by Hydrothermal Mineralization2006

    • Author(s)
      Itakura, T., Sasai, R., Itoh, H
    • Journal Title

      Chemistry Letters 35

      Pages: 2-3

    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Detoxification of Wastewater Containing As and Sb by Hydrothermal Mineralization2007

    • Author(s)
      ITAKURA, T.; SASAI, R.; ITOH, H.
    • Organizer
      International Symposium on EcoTopia Science 2007(ISETS07)
    • Place of Presentation
      Nagoya, JAPAN
    • Year and Date
      20071123-25
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Phosphorous Mineralization for Resource Recovery from Wastewater using Hydrothermal Treatment2007

    • Author(s)
      IMAIZUMI, H.; ITAKURA, T.; SASAI, R.; ITOH, H.
    • Organizer
      International Symposium on EcoTopia Science 2007(ISETS07)
    • Place of Presentation
      Nagoya, JAPAN
    • Year and Date
      20071123-25
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Detoxification of Wastewater Containing As and Sb by Hydrothermal Mineralization2007

    • Author(s)
      Itakura, T., Sasai, R., Itoh, H
    • Organizer
      International Symposium on Eco Topia Science 2007 (ISETS07)
    • Place of Presentation
      Nagoya, Japan
    • Year and Date
      20071123-25
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Phosphorous Mineralization for Resource Recovery from Wastewater2007

    • Author(s)
      Imaizumi, H., Itakura, T., Sasai, R., Itoh, H
    • Organizer
      International Symposium on Eco Topia Science 2007 (ISETS07)
    • Place of Presentation
      Nagoya, Japan
    • Year and Date
      20071123-25
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Resource Recovery of Rare Metals from Cemented Carbide by Hydrothermal Nano-Process2007

    • Author(s)
      ITOH, H.; KOJIMA, T.; GAO, N-F.; SASAI, R.
    • Organizer
      R'07 World Congress: Recovery of Materials and Energy for Resource Efficiency
    • Place of Presentation
      Davos, SWITERLAND
    • Year and Date
      20070903-05
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Resource Recovery and Detoxification of Wastewater Containing Hazardous Oxoanions by Hydrothermal Mineralization2007

    • Author(s)
      ITAKURA, T.; SASAI, R.; ITOH, H.
    • Organizer
      R'07 World Congress: Recovery of Materials and Energy for Resource Efficiency
    • Place of Presentation
      Davos, SWITERLAND
    • Year and Date
      20070903-05
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Resource Recovery of Phosphorous from Wastewater by Hydrothermal Mineralization2007

    • Author(s)
      IMAIZUMI, H.; ITAKURA, T.; SASAI, R.; ITOH, H.
    • Organizer
      R'07 World Congress: Recovery of Materials and Energy for Resource Efficiency
    • Place of Presentation
      Davos, SWITERLAND
    • Year and Date
      20070903-05
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Resource Recovery of Rare Metals from Cemented Carbide by Hydrothermal Nano-Process2007

    • Author(s)
      Itoh, H., Kojima, T., Gao, N-F., Sasai, R
    • Organizer
      R'07 World Congress : Recovery of Materials and Energy for Resource Efficiency
    • Place of Presentation
      Davos, Switzerland
    • Year and Date
      20070903-05
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Resource Recovery and Detoxification of Wastewater Containing Hazardous Oxoanions by Hydrothermal Mineralization2007

    • Author(s)
      Itakura, T., Sasai, R., Itoh, H
    • Organizer
      R'07 World Congress : Recovery of Materials and Energy for Resource Efficiency
    • Place of Presentation
      Davos, Switzerland
    • Year and Date
      20070903-05
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Resource Recovery of Phosphorous from Wastewater by Hydrothermal Mineralization2007

    • Author(s)
      Imaizumi, H., Itakura, T., Sasai, R., Itoh, H
    • Organizer
      R'07 World Congress : Recovery of Materials and Energy for Resource Efficiency
    • Place of Presentation
      Davos, Switzerland
    • Year and Date
      20070903-05
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Resource Recovery from Advanced Ceramics by Hydrothermal Treatment2006

    • Author(s)
      Sasai, R.; Shimizu, T.; Inagaki, F.; Miyanaga, H.; Itakura, T.; Kamiya, M.; Kojima, T.; Itoh, H.
    • Organizer
      Asian Young Ceramist Conference on Tokai(AYCeCT)
    • Place of Presentation
      Ogaki, Japan
    • Year and Date
      20061026-28
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Resource Recovery from Advanced Ceramics by Hydrothermal Treatment2006

    • Author(s)
      Sasai, R., Shimizu, T., Inagaki, F., Miyanaga, H., Itakura, T., Kamiya, M., Kojima, T., Itoh, H
    • Organizer
      Asian Young Ceramist Conference on Tokai (AYCeCT)
    • Place of Presentation
      Ogaki, Japan
    • Year and Date
      20061026-28
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Recovery of Rare Metals from Spent Lithium Ion Cells by Hydrothermal Treatment and Its Technology Assessments(INVITED)2006

    • Author(s)
      Itoh, H.; Miyanaga, H.; Kamiya, M.; Sasai, R.
    • Organizer
      3rd International Conference on Waste Management and the Environment(Waste Management 2006)
    • Place of Presentation
      Malta, Malta
    • Year and Date
      20060621-23
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Resource Recovery from Wastewater Containing Hazardous Oxoanions2006

    • Author(s)
      Itakura, T.; Sasai, R.; Itoh, H.
    • Organizer
      3rd International Conference on Waste Management and the Environment(Waste Management 2006)
    • Place of Presentation
      Malta, Malta
    • Year and Date
      20060621-23
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Decomposition and Detoxification of DXNs Adsorbed on Various Solid Wastes by Microwave Plasma Treatmen2006

    • Author(s)
      Sasai, R.; Jin-no, M.; Satoh, A.; Imai, Y.; Itoh, H.
    • Organizer
      3rd International Conference on Waste Management and the Environment(Waste Management 2006)
    • Place of Presentation
      Malta, Malta
    • Year and Date
      20060621-23
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Recovery of Rare Metals from Spent Lithium Ion Cells by Hydrothermal Treatment and Its Technology Assessments (INVITED)2006

    • Author(s)
      Itoh, H., Miyanaga, H., Kamiya, M., Sasai, R
    • Organizer
      3rd International Conference on Waste Management and the Environment (Waste Management 2006)
    • Place of Presentation
      Malta, Malta
    • Year and Date
      20060621-23
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Resource Recovery from Wastewater Containing Hazardous Oxoanions2006

    • Author(s)
      Itakura, T., Sasai, R., Itoh, H
    • Organizer
      3rd International Conference on Waste Management and the Environment (Waste Management 2006)
    • Place of Presentation
      Malta, Malta
    • Year and Date
      20060621-23
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Decomposition and Detoxification of DXNs Adsorbed on Various Solid Wastes by Microwave Plasma Treatment2006

    • Author(s)
      Sasai, R., Jin-no, M., Satoh, A., Imai, Y., Itoh, H
    • Organizer
      3rd International Conference on Waste Management and the Environment (Waste Management 2006)
    • Place of Presentation
      Malta, Malta
    • Year and Date
      20060621-23
    • Description
      「研究成果報告書概要(欧文)」より
  • [Book] ホウ素・ホウ化物の基礎と応用(シーエムシー出版)2008

    • Author(s)
      笹井亮, 板倉剛, 伊藤秀章
    • Total Pages
      357-365
    • Publisher
      ホウ素流出規制と排水処理・再資源化技術
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] 排水・汚水処理技術集成(NTS)2007

    • Author(s)
      笹井亮, 板倉剛, 伊藤秀章
    • Total Pages
      616-629
    • Publisher
      加熱・加圧による廃水からのホウ素,フッ素およびヒ素の除去と資源回収
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] セラミックデータブック2007工業と製品((株)テクノプラザ(工業製品技術協会))2007

    • Author(s)
      笹井亮, 板倉剛, 伊藤秀章
    • Total Pages
      100-104
    • Publisher
      Geo-Mimetic Techniqueによる難処理性無機排水の処理と資源回収
    • Description
      「研究成果報告書概要(和文)」より
  • [Patent(Industrial Property Rights)] イオン液体の分解処理方法2007

    • Inventor(s)
      平田和正, 伊藤秀章, 吉田寿雄, 笹井 亮, 板倉 剛, 青木正矩
    • Industrial Property Rights Holder
      日本合成化学工業株式会社
    • Industrial Property Number
      特願2007-060371
    • Filing Date
      2007-03-09
    • Description
      「研究成果報告書概要(和文)」より
  • [Patent(Industrial Property Rights)] イオン液体の分解処理方法2007

    • Inventor(s)
      平田和正, 伊藤秀章, 吉田寿雄, 笹井 亮, 板倉 剛, 青木正矩
    • Industrial Property Rights Holder
      日本合成化学工業株式会社
    • Industrial Property Number
      特願2007-060372
    • Filing Date
      2007-03-09
    • Description
      「研究成果報告書概要(和文)」より

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Published: 2010-02-04  

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