2009 Fiscal Year Final Research Report
Laser spectroscopic study on conformer selective photo-chemistry and complexation of amino acids and related molecules
| Project/Area Number |
18205003
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Physical chemistry
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| Research Institution | Hiroshima University |
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Principal Investigator |
EBATA Takayuki Hiroshima University, 大学院・理学研究科, 教授 (70142924)
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| Co-Investigator(Kenkyū-buntansha) |
INOKUCHI Yoshiya 広島大学, 大学院・理学研究科, 准教授 (30311187)
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| Co-Investigator(Renkei-kenkyūsha) |
IWATA Suehiro (財)豊田理化学研究所, フェロー (20087505)
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| Project Period (FY) |
2006 – 2009
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| Keywords | アミノ酸 / コンフォマー / 機能性分子 / 超音速分子線 / 二重共鳴レーザー分光 / 赤外スペクトル / 水和 / 量子化学計算 |
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| Research Abstract |
Conformational stability and conformation specific photochemistry and complexation has been studied for aromatic amino-acids in the gas phase by laser spectroscopy and quantum chemical calculation. The study has been extended to reveal the mechanism of the encapsulation of guest molecules by functional molecules, such as calixarene and crown-ether. Finally, a new mass-spectrometry combined with laser desorption has been developed to study the structures of nonvolatile molecules, such as bio-related molecules and functional molecules having large molecular weight.
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[Remarks] 江幡孝之,平成19年度日本化学会学術賞,平成20年3月27日
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[Remarks] 江幡孝之,広島大学学長賞,平成19年12月
