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2008 Fiscal Year Final Research Report

Development of novel catalysts based on rare earth complexes

Research Project

  • PDF
Project/Area Number 18205010
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionThe Institute of Physical and Chemical Research

Principal Investigator

HOU Zhaomin  The Institute of Physical and Chemical Research, 侯有機金属化学研究室, 主任研究員 (10261158)

Project Period (FY) 2006 – 2008
Keywords有機金属化学 / 多核錯体 / 高分子合成 / 錯体・有機金属触媒 / 希土類錯体 / オレフィン
Research Abstract

希土類ジアルキル錯体から調製される触媒活性種は、各種オレフィンの重合や共重合反応に対して非常に高い位置及び立体選択性を示し、従来の触媒では得ることが出来なかったいくつかの新規ポリマーの合成を達成した。さらに希土類ヒドリドクラスターを基盤とするd.f異種金属クラスターの合成に成功し、これらの錯体が異種金属間の協奏機能により特異な反応性を示すことを明らかにした。

  • Research Products

    (55 results)

All 2009 2008 2007 2006 Other

All Journal Article (24 results) (of which Peer Reviewed: 23 results) Presentation (14 results) Book (7 results) Remarks (1 results) Patent(Industrial Property Rights) (9 results)

  • [Journal Article] 1,2-Azaborolyl-Ligated Half-Sandwich Complexes of Scandium(III) and Lutetium(III): Synthesis, Structures, and Syndiotactic Polymerization of Styrene2009

    • Author(s)
      X. Fang, X. Li, Z. Hou, J. Assoud, and R. Zhao
    • Journal Title

      Organometallics 28

      Pages: 517-522

    • Peer Reviewed
  • [Journal Article] Rare Earth/d-Transition Metal Heteromultimetallic Polyhydride Complexes Based on Half-Sandwich Rare Earth Moieties2009

    • Author(s)
      T. Shima and Z. Hou
    • Journal Title

      Organometallics 28

      Pages: 2244-2252

    • Peer Reviewed
  • [Journal Article] Synthesis of (Z)-1-Aza-1,3-enynes by the Cross-Coupling of Terminal Alkynes with Isocyanides Catalyzed by Rare-Earth Metal Complexes2008

    • Author(s)
      W. Zhang, M. Nishiura, and Z. Hou
    • Journal Title

      Angew. Chem. Int. Ed. 47

      Pages: 9700-9703

    • Peer Reviewed
  • [Journal Article] Neutron Diffraction Studies on a 4-Coordinate Hydrogen Atom in an Yttrium Cluster2008

    • Author(s)
      M. Yousufuddin, M. J. Gutmann, J. Baldamus, O. Tardif, Z. Hou, S. A. Mason, G. J. McIntyre, and R. Bau
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 3888-3891

    • Peer Reviewed
  • [Journal Article] Carboxylation of Organoboronic Esters Catalyzed by N-Heterocyclic Carbene Copper(I) Complexes2008

    • Author(s)
      T. Ohishi, M. Nishiura, and Z. Hou
    • Journal Title

      Angew. Chem. Int. Ed. 47

      Pages: 5792-5795

    • Peer Reviewed
  • [Journal Article] Cationic Scandium Allyl Complexes Bearing Mono(cyclopentadienyl) Ligands: Synthesis, Novel Structural Variety, and Olefin-Polymerization Catalysis2008

    • Author(s)
      N. Yu, M. Nishiura, X. Li, Z. Xi, and Z. Hou
    • Journal Title

      Chem. Asian J. 3

      Pages: 1406-1414

    • Peer Reviewed
  • [Journal Article] Isoprene Polymerization with Yttrium Amidinate Catalyst: Switching the Regio- and Stereoselectivity by Addition of AlMe_32008

    • Author(s)
      L. Zhang, M. Nishiura, M. Yuki, Y. Luo, and Z. Hou
    • Journal Title

      Angew. Chem. Int. Ed. 47

      Pages: 2642-2645

    • Peer Reviewed
  • [Journal Article] Rare-Earth-Metal Mixed Hydride/Aryoxyide Complexes Bearing Mono(cyclopentadienyl) Ligands. Synthesis, CO_2 Fixation, and Catalysis on Copolymerization of CO_2 with Cyclohexene Oxide2008

    • Author(s)
      D. Cui, M. Nishiura, O. Tradif, and Z. Hou
    • Journal Title

      Organometallics 27

      Pages: 2428-2435

    • Peer Reviewed
  • [Journal Article] Synthesis and Styrene Polymerisation Catalysis of η^5- and η^1-Pyrrolyl-Ligated Cationic Rare Earth Metal Aminobenzyl Complexes2008

    • Author(s)
      M. Nishiura, T, Mashiko, and Z. Hou
    • Journal Title

      Chem. Commun.

      Pages: 2019-2021

    • Peer Reviewed
  • [Journal Article] Half-Sandwich o-N,N-Dimethyl- aminobenzyl Complexes over the Full Size Range of Group 3 and Lanthanide Metals. Synthesis, Structural Characterization, and Catalysis of Phosphine P.H Bond Addition to Carbodiimides2008

    • Author(s)
      W.-X. Zhang, M. Nishiura, T. Mashiko, and Z. Hou
    • Journal Title

      Chem. Eur. J. 14

      Pages: 2167-2179

    • Peer Reviewed
  • [Journal Article] Scandium-Catalyzed Syndiospecific Copolymerization of Styrene with Isoprene2008

    • Author(s)
      H. Zhang, Y. Luo, and Z. Hou
    • Journal Title

      Macromorecules 41

      Pages: 1064-1066

    • Peer Reviewed
  • [Journal Article] Organometallic Catalysts for Copolymerization of Cyclic Olefins2008

    • Author(s)
      X. Li and Z. Hou
    • Journal Title

      Coord. Chem. Rev.(A Special Issue: Recent Advances in Organometallic Chemistry: 2008) 252

      Pages: 1842-1869

    • Peer Reviewed
  • [Journal Article] Cationic Rare Earth Metal Alkyls Bearing a Bis-(phosphinophenyl)amido (PNP) Ancillary Ligand. An Excellent Catalyst System for Living cis-1,4-Polymerization and Copolymerization of Isoprene and Butadiene2007

    • Author(s)
      L. Zhang, T. Suzuki, Y. Luo, M. Nishiura, and Z. Hou
    • Journal Title

      Angew. Chem. Int. Ed. 46

      Pages: 1909-1913

    • Peer Reviewed
  • [Journal Article] Isolation and Synthetic Applications of 2,5-Bis(alkylsilyl) Zircona Cyclopentadiene2007

    • Author(s)
      J. Liu, W.-X. Zhang, X. Guo, Z. Hou, and Z. Xi
    • Journal Title

      Organometallics 26

      Pages: 6812-6820

    • Peer Reviewed
  • [Journal Article] Synthesis, Characterization, and Reactivity of Mono(phospholyl) Lanthanoid(III) Bis(dimethylaminobenzyl) Complexes2007

    • Author(s)
      F. Jaroschik, T. Shima, X. Li, K. Mori, L. Ricard, X. -F. Le Goff, F. Nief, and Z. Hou
    • Journal Title

      Organometallics 26

      Pages: 5654-5660

    • Peer Reviewed
  • [Journal Article] Computational Study of Ethylene Insertion into the Metal-Hydrogen Bond of the Tetranuclear Yttrium Polyhydrido Complex [(η^5-C_5Me_4SiMe_3)YH_2]_42007

    • Author(s)
      Y. Luo and Z. Hou
    • Journal Title

      Organometallics 26

      Pages: 2941-2944

    • Peer Reviewed
  • [Journal Article] Catalytic Addition of Amine N-H Bonds to Carbodiimides by Half-Sandwich Rare Earth Metal Complexes: Efficient Synthesis of Substituted Guanidines through Amine Protonolysis of Rare Earth Metal Guanidinates2007

    • Author(s)
      W. Zhang, M. Nishiura, and Z. Hou
    • Journal Title

      Chem. Eur. J. 13

      Pages: 4037-4051

    • Peer Reviewed
  • [Journal Article] Synthesis and Reactions of Polynuclear Polyhydrido Rare Earth Metal Complexes Composed of "(C_5Me_4SiMe_3)LnH_2" Units: A New Frontier of Rare Earth Metal Hydride Chemistry2007

    • Author(s)
      Z. Hou, M. Nishiura, and T. Shima
    • Journal Title

      Eur. J. Inorg. Chem.(Selected as the Back Cover Picture, 10^<th> Anniversary Special Issue)

      Pages: 2535-2545

    • Peer Reviewed
  • [Journal Article] C-C Bond Formation through Reaction of CO_2 with C≡C and C=C-C=C2007

    • Author(s)
      Z. Hou and T. Ohishi
    • Journal Title

      Comprehensive Organometallic Chemistry III, (R. Crabtree and M. Mingos Eds), (Elsevier: Oxford) vol. 10

      Pages: 537-556

  • [Journal Article] Hydrogenation of Carbon Monoxide by Tetranuclear Rare Earth Metal Polyhydrido Complexes. Selective Formation of Ethylene and Isolation of Well-Defined Polyoxo Rare Earth Metal Clusters2006

    • Author(s)
      T. Shima and Z. Hou
    • Journal Title

      J. Am. Chem. Soc. 128

      Pages: 8124-8125

    • Peer Reviewed
  • [Journal Article] π-Conjugated Aromatic Enynes as a Single-Emitting Component for White Electroluminescence2006

    • Author(s)
      Y. Liu, M. Nishiura, Y. Wang, and Z. Hou
    • Journal Title

      J. Am. Chem. Soc. 128

      Pages: 5592-5593

    • Peer Reviewed
  • [Journal Article] Cationic Polyhydrido Rare Earth Metal Complexes. Synthesis, Structure, and Catalysis in 1,3-Cyclohexadiene Polymerization2006

    • Author(s)
      X. Li, J. Baldamus, M. Nishiura, O. Tardif, and Z. Hou
    • Journal Title

      Angew. Chem. Int. Ed. 45

      Pages: 8184-8188

    • Peer Reviewed
  • [Journal Article] A Five-Center Rather than a Four-Center Transition State for Alkene Insertion into the Metal-Alkyl Bond of a Cationic Binuclear Yttrium Complex2006

    • Author(s)
      Y. Luo and Z. Hou
    • Journal Title

      Organometallics 25

      Pages: 6162-6165

    • Peer Reviewed
  • [Journal Article] Alkali-Metal-Catalyzed Addition of Primary and Secondary Phosphines to Carbodiimides. A General and Efficient Route to Substituted Phosphaguanidines2006

    • Author(s)
      W. Zhang, M. Nishiura, and Z. Hou
    • Journal Title

      Chem. Commun. 36

      Pages: 3812-3814

    • Peer Reviewed
  • [Presentation] Regio- and Stereospecific Control of Olefin Polymerization by Well-Defined Rare-Earth Metal Catalysts2008

    • Author(s)
      Z. Hou
    • Organizer
      2008 Japan-USA Seminar on Polymer Synthesis, (Invited lecture)
    • Place of Presentation
      Awaji, Japan
    • Year and Date
      20081200
  • [Presentation] Design and Synthesis of Organo Rare Earth Catalysts for the Synthesis of Novel Polymer Materials2008

    • Author(s)
      Z. Hou
    • Organizer
      2nd Symposium on Applied Chemistry, (Invited lecture)
    • Place of Presentation
      Changchun, China
    • Year and Date
      20080900
  • [Presentation] Rare Earth Metal Hydride Clusters Composed of "LMH_2" Units. Synthesis, Structure, and Novel Reactivity2008

    • Author(s)
      Z. Hou
    • Organizer
      25th Rare Earth Research Conference (RERC08), (Invited lecture)
    • Place of Presentation
      Alabama, USA
    • Year and Date
      20080600
  • [Presentation] Syndiospecific Copolymerization of Styrene and Isoprene by Scandium Catalysts2008

    • Author(s)
      Z. Hou
    • Organizer
      International Workshop on Olefin Polymerization Kinetics, (Invited lecture)
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      20080400
  • [Presentation] New Catalysts, New Reactions, and New Materials2007

    • Author(s)
      Z. Hou
    • Organizer
      10th Japanese-American Frontiers of Science Symposium, (Invited lecture)
    • Place of Presentation
      Hayama, Japan
    • Year and Date
      20071200
  • [Presentation] Unprecedented Switching of the Regio- and Stereoselectivity in Yttrium-Catalyzed Isoprene Polymerization2007

    • Author(s)
      Z. Hou
    • Organizer
      Asian Polyolefin Workshop 2007 (APO2007), (Invited lecture)
    • Place of Presentation
      Hangzhou, China
    • Year and Date
      20071000-1100
  • [Presentation] Rare-Earth-Metal-Based Catalysts for Olefin Polymerization and Other Related Reactions2007

    • Author(s)
      Z. Hou
    • Organizer
      1st East China University of Science and Technology (ECUST) International Polyolefin Workshop, (Invited lecture)
    • Place of Presentation
      Shanghai, China
    • Year and Date
      20071000
  • [Presentation] Synthesis and Novel Reactions Polynuclear Polyhydrido Rare Earth Metal Complexes: A New Frontier in Rare Earth Metal Hydride Chemistry2007

    • Author(s)
      Z. Hou
    • Organizer
      1st Asian Conference on Coordination Chemistry, (Invited lecture)
    • Place of Presentation
      Okazaki, Japan
    • Year and Date
      20070700-0800
  • [Presentation] Development of Polymerization Reactions Based on New Organo Rare Earth Metal Catalysts2007

    • Author(s)
      Z. Hou
    • Organizer
      The Third Mitsui Chemicals International Symposium on Catalysis Science, (Award lecture)
    • Place of Presentation
      Kisarazu, Japan
    • Year and Date
      20070300
  • [Presentation] 新しい構造を持つ有機希土類錯体の合成と新規物質変換触媒への展開2007

    • Author(s)
      侯召民
    • Organizer
      日本化学会第87春季年会(受賞講演)
    • Place of Presentation
      吹田市
    • Year and Date
      20070300
  • [Presentation] 希土類ヒドリドクラスターを基盤とする多金属触媒2007

    • Author(s)
      侯召民
    • Organizer
      日本化学会第87春季年会、(依頼講演)
    • Place of Presentation
      吹田市
    • Year and Date
      20070300
  • [Presentation] Organometallic Catalysts for the Synthesis of Functional Materials and Fine Chemicals: An Overview of Researches in RIKEN2006

    • Author(s)
      Z. Hou
    • Organizer
      PKU-CCAST-RIKEN Symposium, (Invited lecture)
    • Place of Presentation
      Beijing, China
    • Year and Date
      20061000
  • [Presentation] Stereospecific Polymerization and Copolymerization of Acyclic and Cyclic Olefins by Group 3 Metal Catalysts2006

    • Author(s)
      Z. Hou
    • Organizer
      ,41st International Symposium on Macromolecules (MACRO 2006), (Invited lecture)
    • Place of Presentation
      Rio de janeiro, Brazil
    • Year and Date
      20060700
  • [Presentation] Novel Olefin Polymerization Catalysts Based on Cationic Rare Earth Metal Alkyls2006

    • Author(s)
      Z. Hou
    • Organizer
      International Symposium on Polymer Chemistry (PC'2006), (Invited lecture)
    • Place of Presentation
      Dalian, China
    • Year and Date
      20060600
  • [Book] 希土類触媒による高分子重合、希土類の材料技術ハンドブック、pp.467-4752008

    • Author(s)
      西浦正芳、侯召民
    • Publisher
      エヌ・ティー・エス、東京
  • [Book] 精密重合を可能とするSc,Y系錯体、マテリアルインテグレーション、21、 pp. 34-422008

    • Author(s)
      侯召民、鈴木俊彰
  • [Book] 希土類ヒドリドクラスターを基盤とする多金属触媒、学術月報、61、 pp. 24-292008

    • Author(s)
      島隆則、侯召民
  • [Book] 希土類の特徴を生かした新規精密重合触媒の開発、ファインケミカル、36、pp. 17-232007

    • Author(s)
      滝本真徳、侯召民
  • [Book] 有機希土類錯体化学の新展開、化学工業、58、pp. 799-8042007

    • Author(s)
      今野陽介、侯召民
  • [Book] オレフィン精密重合触媒の新展開:希土類金属高性能重合触媒の開発、高分子、56、pp. 915-9202007

    • Author(s)
      鈴木俊彰、侯召民
  • [Book] 希土類錯体触媒を利用した新しいポリマー材料の合成、未来材料、7、 pp. 24-312007

    • Author(s)
      侯召民、滝本真徳
  • [Remarks] ホームページ

    • URL

      http://www.riken.jp/lab-www/organometallic/index.html

  • [Patent(Industrial Property Rights)] 重合体およびそれを用いた光学材料2009

    • Inventor(s)
      西浦正芳、侯召民、藤堂昭、木津巧一
    • Industrial Property Rights Holder
      (独)理化学研究所、三井化学(株)
    • Industrial Property Number
      特許,特願2009-083795
    • Filing Date
      2009-03-30
  • [Patent(Industrial Property Rights)] イソプレン系重合体環化物およびその製造方法2008

    • Inventor(s)
      侯召民,西井圭、角替靖男
    • Industrial Property Rights Holder
      (独)理化学研究所、日本ゼオン
    • Industrial Property Number
      特許,特願2008-225152
    • Filing Date
      2008-09-02
  • [Patent(Industrial Property Rights)] ポリスチレン系樹脂組成物2007

    • Inventor(s)
      侯召民,石原伸英
    • Industrial Property Rights Holder
      (独)理化学研究所(50%),出光興産(株)(50%)
    • Industrial Property Number
      特許,特願2007-011277
    • Filing Date
      2007-01-22
  • [Patent(Industrial Property Rights)] スチレン系共重合体延伸成形品2007

    • Inventor(s)
      侯召民,石原伸英
    • Industrial Property Rights Holder
      (独)理化学研究所(50%),出光興産(株)(50%)
    • Industrial Property Number
      特許,特願2007-011278
    • Filing Date
      2007-01-22
  • [Patent(Industrial Property Rights)] 複素環配位子を含む金属錯体,及びそれを含む重合触媒組成物2007

    • Inventor(s)
      西浦正芳,増子智洋,侯召民
    • Industrial Property Rights Holder
      (独)理化学研究所
    • Industrial Property Number
      特許,特願2007-060121
    • Filing Date
      2007-03-09
  • [Patent(Industrial Property Rights)] イソプレン系化合物の重合用の重合触媒組成物2007

    • Inventor(s)
      張立新,侯召民
    • Industrial Property Rights Holder
      (独)理化学研究所
    • Industrial Property Number
      特許,特願2007-06065
    • Filing Date
      2007-03-09
  • [Patent(Industrial Property Rights)] イソプレン系化合物の重合用の重合触媒組成物2007

    • Inventor(s)
      侯召民,張立新
    • Industrial Property Rights Holder
      (独)理化学研究所
    • Industrial Property Number
      特許,PCT/12/282148
    • Filing Date
      2007-02-05
  • [Patent(Industrial Property Rights)] メタロセン錯体を含む重合触媒組成物,およびそれを用いて製造される重合体2006

    • Inventor(s)
      侯召民,李暁芳,郁楠
    • Industrial Property Rights Holder
      (独)理化学研究所
    • Industrial Property Number
      特許,特願2006-280074
    • Filing Date
      2006-10-13
  • [Patent(Industrial Property Rights)] 化合物およびその使用方法,有機EL素子ならびにその製造方法および使用方法2006

    • Inventor(s)
      侯召民,劉宇
    • Industrial Property Rights Holder
      (独)理化学研究所
    • Industrial Property Number
      特許,PCT/12/224847
    • Filing Date
      2006-11-28

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Published: 2010-06-10   Modified: 2016-04-21  

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