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2009 Fiscal Year Final Research Report

Research on hexagonal boron nitride semiconductors

Research Project

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Project/Area Number 18206004
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied materials science/Crystal engineering
Research InstitutionNTT Basic Research Laboratories

Principal Investigator

KOBAYASHI Yasuyuki  NTT Basic Research Laboratories, 機能物質科学研究部・薄膜材料研究グループ, 主幹研究員 (90393727)

Co-Investigator(Kenkyū-buntansha) MAKIMOTO Toshiki  日本電信電話株式会社NTT物性科学基礎研究所, 機能物質科学研究部, 部長 (50374070)
AKASAKA Tetsuya  日本電信電話株式会社NTT物性科学基礎研究所, 機能物質科学研究部, 主任研究員 (90393735)
NISHIKAWA Atsushi  日本電信電話株式会社NTT物性科学基礎研究所, 機能物質科学研究部, 社員 (60417095)
NAKANO Hidetoshi  日本電信電話株式会社NTT物性科学基礎研究所, 量子光物性研究部, 主幹研究員 (90393793)
GOTOH Hideki  日本電信電話株式会社NTT物性科学基礎研究所, 量子光物性研究部, 主幹研究員 (10393795)
TAWARA Takehiko  日本電信電話株式会社NTT物性科学基礎研究所, 量子光物性研究部, 研究主任 (40393798)
SANADA Haruki  日本電信電話株式会社NTT物性科学基礎研究所, 量子光物性研究部, 社員 (50417094)
Project Period (FY) 2006 – 2009
Keywords半導体 / 結晶成長 / 半導体物性 / 光物性
Research Abstract

We demonstrate that (0001) hexagonal boron nitrides (h-BN) are epitaxially grown on (111) Ni and (0001) sapphire substrates by metalorganic vapor phase epitaxy. A near-band-gap ultraviolet emission peak centered at energy of 5.47eV (227nm) is clearly observed in cathodoluminescence spectra at room temperature from the h-BN epitaxial layers. The photon energy dependence of the squared absorption coefficient is linear, indicating a direct band gap in the h-BN, and the optical band gap is determined to be 5.9eV. The h-BN has a promising as an optoelectronic material in the deep ultraviolet spectral region.

  • Research Products

    (19 results)

All 2010 2009 2008 2007

All Journal Article (9 results) (of which Peer Reviewed: 8 results) Presentation (10 results)

  • [Journal Article] Optical band gap of h-BN epitaxial film grown on c-plane sapphire substrate2010

    • Author(s)
      Y. Kobayashi、C.L. Tsai、T. Akasaka
    • Journal Title

      Physica Status Solidi(c) (in press)

    • Peer Reviewed
  • [Journal Article] 六方晶窒化ホウ素のエピタキシャル成長とその紫外発光特性2010

    • Author(s)
      小林康之、C.L. Tsai、赤坂哲也
    • Journal Title

      表面科学 31巻

      Pages: 99-105

  • [Journal Article] Molecular beam epitaxial growth of hexagonal boron nitride on Ni(111) substrate2009

    • Author(s)
      C.L. Tsai、T. Akasaka、Y. Kobayashi
    • Journal Title

      Journal of Crystal Growth Vol.311

      Pages: 3054-3057

    • Peer Reviewed
  • [Journal Article] Hexagonal BN epitaxial growth on (0001) sapphire substrate by MOVPE2008

    • Author(s)
      Y. Kobayashi、T. Akasaka
    • Journal Title

      Journal of Crystal Growth Vol.310

      Pages: 5044-5047

    • Peer Reviewed
  • [Journal Article] Hexogonal boron nitride grown by MOVPE2008

    • Author(s)
      Y. Kobayashi、T. Akasaka、T. Makimoto
    • Journal Title

      Journal of Crystal Growth Vol.310

      Pages: 5048-5052

    • Peer Reviewed
  • [Journal Article] Nonpolar AlBN (1120) and (1100) films grown on SiC substrate2007

    • Author(s)
      T. Akasaka、Y. Kobayashi、T. Makimoto
    • Journal Title

      Applied Physics Letters Vol.91

      Pages: 041914-1-3

    • Peer Reviewed
  • [Journal Article] Boron Nitride Thin Films Grown on Graphitized 6H-SiC Substrates by Metalorganic Vapor phase Epitaxy2007

    • Author(s)
      Y. Kobayashi, H. Hibino, T. Nakamura, T. Akasaka, T. Makimoto, N. Matsumoto
    • Journal Title

      Japanese Jounal of Applied Physics Vol.46

      Pages: 2554-2557

    • Peer Reviewed
  • [Journal Article] Ultraviolet luminescence from hexagonal boron nitride heteroepitaxial layers on Ni(111) grown by flow-rate modulation epitaxy2007

    • Author(s)
      Y. Kobayashi、T. Nakamura、T. Akasaka、T. Makimoto、N. Matsumoto
    • Journal Title

      Physica Status Solidi(b) Vol.244

      Pages: 1789-1792

    • Peer Reviewed
  • [Journal Article] BGaN micro-islands as novel buffers fro growth of high quality GaN on sapphire2007

    • Author(s)
      T. Akasaka、Y. Kobayashi、T. Makimoto
    • Journal Title

      Journal of Crystal Growth Vol.298

      Pages: 320-324

    • Peer Reviewed
  • [Presentation] Optical Band Gap of Hexagonal BN Epitaxial Film Grown on c-Plane Sapphire Substrate2009

    • Author(s)
      Y. Kobayahi、T. Akasaka
    • Organizer
      2009 Asia-Core Workshop on Wide Bandgap Semiconductors、招待講演
    • Place of Presentation
      韓国、慶州
    • Year and Date
      20091023-20091025
  • [Presentation] Optical Band Gap of Hexagonal BN Epitaxil Film Grown on c-Plane Sapphire Substrate2009

    • Author(s)
      Y. Kobayahi、C.L. Tsai、T. Akasaka
    • Organizer
      8th International Conference on Nitride Semiconductors
    • Place of Presentation
      韓国、済州島
    • Year and Date
      20091018-20091023
  • [Presentation] Hexagonal BN epitaxial Growth by Flow-Rate Modulation Epitaxy on MBE-Grown h-BN Buffer Layer2009

    • Author(s)
      Y. Kobayahi、C.L. Tsai、T. Akasaka
    • Organizer
      8th International Conference on Nitride Semiconductors
    • Place of Presentation
      韓国、済州島
    • Year and Date
      20091018-20091023
  • [Presentation] Near Band-Gap Luminescnece of Hexagonal Boron Nitride Grown on Ni(111) Substrtae by Plasma-assisted MBE2009

    • Author(s)
      C.L. Tsai、Y. Kobayashi、T. Akasaka、M. Kasu
    • Organizer
      Electronic Materials Conference
    • Place of Presentation
      アメリカ、ペンシルベニア
    • Year and Date
      20090624-20090626
  • [Presentation] Molecular beam epitaxial growth of hexagonal boron nitride on Ni(111) substrtae2008

    • Author(s)
      C.L. Tsai、T. Akasaka、Y. Kobayashi
    • Organizer
      Second International Symposium on Growth of III-Nitrides
    • Place of Presentation
      日本、修善寺
    • Year and Date
      20080706-20080709
  • [Presentation] Anisotropic in-plane strains in Al(B, Ga)N (11-20) films grown on SiC (11-20)2008

    • Author(s)
      T. Akasaka、Y. Kobayashi
    • Organizer
      Second International Symposium on Growth of III-Nitrides
    • Place of Presentation
      日本、修善寺
    • Year and Date
      20080706-20080709
  • [Presentation] Hexagonal BN epitaxial growth on (0001) sapphire substrate by MOVPE2008

    • Author(s)
      Y. Kobayashi、T. Akasaka
    • Organizer
      14th International Conference on Metal Organic Vapor Phase Epitaxy
    • Place of Presentation
      フランス、メス
    • Year and Date
      20080602-20080606
  • [Presentation] Boron Nitride grown by MOVPE2008

    • Author(s)
      Y. Kobayashi、T. Akasaka
    • Organizer
      14th International Conference on Metal Organic Vapor Phase Epitaxy、招待講演
    • Place of Presentation
      フランス、メス
    • Year and Date
      20080602-20080606
  • [Presentation] Nonpolar AlBN (1120) and (1100) films grown on SiC substrates2007

    • Author(s)
      T. Akasaka、Y. Kobayashi、T. Makimoto
    • Organizer
      7th International Conference of Nitride semiconductors
    • Place of Presentation
      アメリカ、ラスベガス
    • Year and Date
      20070916-20070921
  • [Presentation] In-situ monitoring of hexagonal BN flow-rate modulation epitaxy by shallow-angle reflectance using ultraviolet light2007

    • Author(s)
      Y. Kobayashi、T. Miyamoto、T. Akasaka、T. Makimoto、N. Matsumoto
    • Organizer
      The 15th International Conference on Crystal Growth
    • Place of Presentation
      アメリカ、ソルトレイク
    • Year and Date
      20070812-20070817

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Published: 2011-06-18   Modified: 2016-04-21  

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