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2009 Fiscal Year Final Research Report

Synthesis of nanophotocrystals via novel green process using water : Solubilization of non-water-soluble metals into water based upon complexation

Research Project

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Project/Area Number 18206069
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionTohoku University

Principal Investigator

KAKIHANA Masato  Tohoku University, 多元物質科学研究所, 教授 (50233664)

Co-Investigator(Kenkyū-buntansha) TOMITA Koji  東海大学, 理学部, 講師 (00419235)
PETRYKIN Valery  東北大学, 多元物質科学研究所, 准教授 (20375166)
Project Period (FY) 2006 – 2009
Keywords水 / グリーンプロセス / ナノ光結晶 / 水溶性金属錯体 / フォトセラミックス
Research Abstract

In this study we developed new water-soluble compounds as precursors for photo-functional ceramics and synthesized high-performanced photoceramics using water as a processing solvent. We succeeded in development of new Si, Nb, and Ta water-soluble compounds through chemical complexation techniques. Our newly developed aqueous solution method using these compounds enabled us not only to prepare materials having properties superior to those for materials synthesized by the conventional method but also to provide highly morphologically controlled particles. Another important achievement in this study includes establishment of the new parallel synthetic scheme using water-soluble Si compound, which made possible to find quickly optimal compositions of high-brightness phosphors.

  • Research Products

    (31 results)

All 2010 2009 2008 2007 2006

All Journal Article (13 results) (of which Peer Reviewed: 13 results) Presentation (11 results) Book (3 results) Patent(Industrial Property Rights) (4 results)

  • [Journal Article] Preparation of Water Soluble Silicon Compound and its Application for Synthesis of (Y,Ce,Gd)_2SiO_5 Blue Emission Phosphor2009

    • Author(s)
      Y. Suzuki, M. Kakihana
    • Journal Title

      J.Ceram.Soc.Jpn. 117

      Pages: 330-334

    • Peer Reviewed
  • [Journal Article] New water soluble and handy silicon precursor for synthesis of (Y, Ce, Gd)_2SiO_5 phosphor2009

    • Author(s)
      Y. Suzuki, M. Kakihana
    • Journal Title

      J.Phys. : Conf.Seri. : Mater.Sci.Eng. 1

      Pages: 012012

    • Peer Reviewed
  • [Journal Article] Synthesis of K_3Ta_3B_2O_<12> photocatalyst by solution based method and effect of co-catalyst and phase purity to water splitting activity2009

    • Author(s)
      Matsumoto, K. Ueda, K. Tomita, Y. Sekine, Y. Miura, N. Yamatani, M. Kakihana
    • Journal Title

      J.Ceram.Soc.Jpn. 117

      Pages: 1191-1194

    • Peer Reviewed
  • [Journal Article] Synthesis of high-performance ceramics based on polymerizable complex method2009

    • Author(s)
      M. Kakihana
    • Journal Title

      J.Ceram.Soc.Jpn. 117

      Pages: 857-862

    • Peer Reviewed
  • [Journal Article] Photocatalytic Patterning using Nano-Colloidal Anatase in Aqueous Solution Process2009

    • Author(s)
      K. Tomita, K. Yamamoto, K. Fujita, V. Petrykin, M. Kakihana
    • Journal Title

      Trans.Mater.Res.Soc.Jpn. 34

      Pages: 279-281

    • Peer Reviewed
  • [Journal Article] Synthesis of TiO_2(B) using glycolato titanium complex and post-synthetic hydrothermal crystal growth of TiO_2(B)2009

    • Author(s)
      K. Yamamoto, K. Tomita, K. Fujita, M. Kobayashi, V. Petrykin, M. Kakihana
    • Journal Title

      J.Cryst.Grow 311

      Pages: 619-622

    • Peer Reviewed
  • [Journal Article] Synthesis of Nano- crystalline YVO_4 : Eu Red Emission Phosphor with High Fluorescence Intensity by Hydrothermal Method using Original Vanadium-Peroxo- Citrate Complex2009

    • Author(s)
      S. Kaowphong, V. Petrykin, S. Thongtem, M. Kakihana
    • Journal Title

      J.Ceram.Soc.Jpn. 117

      Pages: 273-276

    • Peer Reviewed
  • [Journal Article] Hydrothermal Synthesis and Photocatalytic Activity of Whisker-Like Rutile-Type Titanium Dioxide2009

    • Author(s)
      M. Kobayashi, V. Petrykin, M. Kakihana, K. Tomita
    • Journal Title

      J.Am.Ceram.Soc. 92

      Pages: S21-S26

    • Peer Reviewed
  • [Journal Article] Direct synthesis of brookite-type titanium oxide by hydrothermal method using water-soluble titanium complexes2008

    • Author(s)
      M. Kobayashi, K. Tomita, V. Petrykin, M. Yoshimura, M. Kakihana
    • Journal Title

      J.Mat.Sci. 43

      Pages: 2158-2162

    • Peer Reviewed
  • [Journal Article] One-step synthesis of TiO_2(B) nanoparticles from a Water-Soluble titanium complex2007

    • Author(s)
      M. Kobayashi, V. Petrykin, M. Kakihana, K. Tomita, M. Yoshimura
    • Journal Title

      Chem.Mat. 19

      Pages: 5373-5376

    • Peer Reviewed
  • [Journal Article] Microwave-assisted hydrothermal synthesis of brookite nanoparticles from a water-soluble titanium complex and their photocatalytic activity2007

    • Author(s)
      Y. Morishinia, M. Kobayashi, V. Petrykin, M. Kakihana, K. Tomita
    • Journal Title

      J.Ceram.Soc.Jpn 115

      Pages: 826-830

    • Peer Reviewed
  • [Journal Article] A water-soluble titanium complex for the selective synthesis of nanocrystalline brookite, rutile, and anatase by a hydrothermal method2006

    • Author(s)
      K. Tomita, V. Petrykin, M. Kobayashi, M. Shiro, M. Yoshimura, M. Kakihana
    • Journal Title

      Ang.Chem.Int.Ed. 45

      Pages: 2378-2381

    • Peer Reviewed
  • [Journal Article] Synthesis and structure of new water-soluble and stable tantalum compound : Ammonium tetralactatodiperoxo-μ-oxo-ditantalate(V)2006

    • Author(s)
      V. Petrykin, M. Kakihana, K. Yoshioka, S. Sasaki, Y. Ueda, K. Tomita, Y. Nakamura, M. Shiro, A. Kudo
    • Journal Title

      Inorg.Chem. 45

      Pages: 9251-9256

    • Peer Reviewed
  • [Presentation] 水からつくるナノセラミックス2010

    • Author(s)
      垣花眞人
    • Organizer
      日本セラミックス協会2010年年会
    • Place of Presentation
      小金井市
    • Year and Date
      2010-03-22
  • [Presentation] Synthesis of sulfide-based phosphors by multiply combined methods based upon inorganic chemistry2009

    • Author(s)
      M. Kakihana, V. Petrykin
    • Organizer
      The 9th International Meeting on Information Display (IMID 2009)
    • Place of Presentation
      KINTEX, Seoul, Korea
    • Year and Date
      2009-10-12
  • [Presentation] Synthesis of high performance phosphor materials by advanced solution methods2009

    • Author(s)
      M . Kakihana
    • Organizer
      Sungkyunkwan University (SKKU) Advanced Institute of Nanotechnology (SAINT) seminar
    • Place of Presentation
      Sungkyunkwan University, Korea
    • Year and Date
      2009-10-01
  • [Presentation] 水溶性金属錯体を活用した水溶液からの無機機能材料の合成-難水溶性金属の親水錯体技術2009

    • Author(s)
      垣花眞人
    • Organizer
      錯体化学若手の会北海道・東北支部勉強会
    • Place of Presentation
      山形市
    • Year and Date
      2009-07-04
  • [Presentation] 高分子前駆体法によるセラミックス合成2009

    • Author(s)
      垣花眞人
    • Organizer
      第28回無機高分子シンポジウム
    • Place of Presentation
      東京都
    • Year and Date
      2009-06-26
  • [Presentation] New generation of Si, Ti, Nb and Ta precursors for aqueous solution synthesis of advanced nanophotoceramicsi2009

    • Author(s)
      M. Kakihana, M. Kobayashi, Y. Suzuki, V. Petrykin, S. Tezuka, K.Tomita
    • Organizer
      The third international conference on the science and technology for advanced ceramics
    • Place of Presentation
      横浜市
    • Year and Date
      2009-06-16
  • [Presentation] 多核金属錯体をテクトンとする溶液プロセスによるナノフォトセラミックス2009

    • Author(s)
      垣花眞人
    • Organizer
      日本化学会第89春季大会
    • Place of Presentation
      船橋市
    • Year and Date
      2009-03-28
  • [Presentation] New Generation of Precursors for Highly Selective Synthesis of Nano-crystalline TiO_2 Polymorphs with Controlled Morphology2008

    • Author(s)
      M. Kakihana, M. Kobayashi, V. Petrykin, K. Tomita
    • Organizer
      (Invited Talk) IUMRS-ICA2008
    • Place of Presentation
      名古屋市
    • Year and Date
      2008-12-10
  • [Presentation] 環境調和型水溶液プロセスによる高機能セラミックス2008

    • Author(s)
      垣花眞人
    • Organizer
      化学系学協会東北大会
    • Place of Presentation
      八戸市
    • Year and Date
      2008-10-12
  • [Presentation] 水溶性チタン錯体を用いた水熱法による酸化チタン多形の選択的合成2007

    • Author(s)
      垣花眞人, 小林亮, ペトリキンヴァレリー, 冨田恒之
    • Organizer
      平成19年度粉体粉末冶金協会秋季大会
    • Place of Presentation
      京都市
    • Year and Date
      2007-11-19
  • [Presentation] 水溶液プロセスによるチタン系セラミックス材料の合成2007

    • Author(s)
      冨田恒之, 山本和広, 瀬戸智行, 藤田一美, 小林亮,ペトリキンヴァレリー, 垣花眞人
    • Organizer
      日本セラミックス協会第20回秋季シンポジウム
    • Place of Presentation
      名古屋市
    • Year and Date
      2007-09-12
  • [Book] セラミックスデータブック2009(水溶液化学に立脚したナノセラミックス合成)2009

    • Author(s)
      鈴木義仁, 小林亮, 垣花眞人
    • Total Pages
      125-128
    • Publisher
      (株)テクノプラザ
  • [Book] セラミックス製造プロセス、応用技術大全集(第1章第1節[3]液相合成法)2007

    • Author(s)
      垣花眞人
    • Total Pages
      35-48
    • Publisher
      技術情報協会
  • [Book] ナノ蛍光体の開発と応用2007

    • Author(s)
      垣花眞人
    • Total Pages
      9-24
    • Publisher
      シーエムシー出版
  • [Patent(Industrial Property Rights)] 黄色蛍光体とその製造方法2009

    • Inventor(s)
      ペトリキンヴァレリー, 垣花眞人, 高塚裕二
    • Industrial Property Rights Holder
      住友金属鉱山 (株)、東北大学
    • Patent Publication Number
      特許特開2009-270056
    • Filing Date
      2009-11-19
  • [Patent(Industrial Property Rights)] 水溶性Si化合物及び水溶性Siの製造方法2008

    • Inventor(s)
      鈴木義仁, 垣花眞人, 大豆生田勉
    • Industrial Property Rights Holder
      東北大学, マツモトファィンケミカル (株)
    • Industrial Property Number
      特許特願2008-171301
    • Filing Date
      2008-06-30
  • [Patent(Industrial Property Rights)] 低アンモニウム型チタンペルオキソ化合物の合成方法2007

    • Inventor(s)
      小林亮, 冨田恒之, 垣花眞人, 樋口隆行, 吉野亮悦
    • Industrial Property Rights Holder
      東北大学・電気化学工業(株)
    • Industrial Property Number
      特許特開2008ー247811
    • Filing Date
      2007-03-30
  • [Patent(Industrial Property Rights)] ブルッカイト型二酸化チタンの製造方法2006

    • Inventor(s)
      垣花眞人, 冨田恒之, 小林亮, 佐藤次雄, 殷シュウ
    • Industrial Property Rights Holder
      東北大学
    • Patent Publication Number
      特許特開2007-246301
    • Filing Date
      2006-03-13

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Published: 2011-06-18   Modified: 2016-04-21  

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