Synthesis of highly active and multi-functional carbon-based solid acid

2008 Fiscal Year Final Research Report

• Project/Area Number: 18206081
• Research Category: Grant-in-Aid for Scientific Research (A)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Catalyst/Resource chemical process
• Research Institution: Tokyo Institute of Technology
• Principal Investigator: HARA Michikazu Tokyo Institute of Technology, 応用セラミックス研究所, 教授 (70272713)
• Co-Investigator(Kenkyū-buntansha): TATSUMI Takashi 東京工業大学, 資源化学研究所, 教授 (30101108) ; NOMURA Junko 東京工業大学, 資源化学研究所, 准教授 (60234936)
• Project Period (FY): 2006 – 2008
• Keywords: 固体酸触媒 / カーボン系固体酸 / セルロース / 加水分解

Research Abstract

本研究は高密度のスルホ基を結合したナノサイズのグラフェンで構成されるアモルファスカーボンであるカーボン系固体酸の形態、官能基を制御することによって高性能・多機能な新規触媒を創生する。

Research Products

• [Journal Article] Amorphous Carbon Bearing Sulfonic Acid Groups in Mesoporous Silica as a Selective Catalyst (2009)
  • Author(s): Kiyotaka Nakajima, Mai Okamura, Junko N. Kondo, Kazunari Domen, Takashi Tatsumi, Shigenobu Hayashi, and Michikazu Hara
  • Journal Title: Chem. Mater 21 Pages: 186-193
  • Peer Reviewed
• [Journal Article] Hydrolysis of Cellulose by a Solid Acid Catalyst under Optimal Reaction Conditions (2009)
  • Author(s): Daizo Yamaguchi, Masaaki Kitano, Satoshi Suganuma, Kiyotaka Nakajima, Hideki Kato, and Michikazu Hara
  • Journal Title: J. Phys. Chem. C 113 Pages: 3181-3188
  • Peer Reviewed
• [Journal Article] Adsorption-Enhanced Hydrolysis of β-1, 4 Glucans on Graphene-Based Amorphous Carbon Bearing SO_3H, COOH, and OH groups (2009)
  • Author(s): Masaaki Kitano, Daizo Yamaguchi, Satoshi Suganuma, Kiyotaka Nakajima, Hideki Kato, Shigenubu Hayashi, and Michikazu Hara
  • Journal Title: Langmuir 25 Pages: 5068-5075
  • Peer Reviewed
• [Journal Article] Hydrolysis of Cellulose by Amorphous Carbon Bearing SO_3H, COOH, and OH Groups (2008)
  • Author(s): Satoshi Suganuma, Kiyotaka Nakajima, Daizo Yamaguchi, Masaaki Kitano, Hideki Kato, Shigenubu Hayashi, and Michikazu Hara
  • Journal Title: J. Am. Chem. Soc. 130 Pages: 12787-12793
  • Peer Reviewed
• [Journal Article] Acid-Catalyzed Reactions on Flexible Polycyclic Aromatic Carbon in Amorphous Carbon (2006)
  • Author(s): Mai Okamura, Atsushi Takagaki, Masakazu Toda, Junko N. Kondo, Kazunari Domen, Takashi Tatsumi, Shigenobu Hayashi, Michikazu Hara
  • Journal Title: Chem. Mater. 18 Pages: 3039-3045
  • Peer Reviewed
• [Presentation] Keynote lecture : Hydrolysis of cellulose by using a solid acid catalyst (2008)
  • Author(s): M. Hara
  • Organizer: 2008 APEC Clean Development Conference in Taiwan Conference
  • Place of Presentation: Sinchu, TAIWAN
  • Year and Date: 20081215-16
• [Presentation] Invited lecture : Hydrolysis of cellulose into glucose by using a carbon material (2008)
  • Author(s): M. Hara
  • Organizer: CRC International Symposium on Bio-interface and Biomass Conversion
  • Place of Presentation: Sapporo, JAPAN
  • Year and Date: 20081029-31
• [Remarks] 「触媒の最先端研究」-世の中進歩堂(BSジャパン : 30分中22分間)-2009年1月17日放映
• [Remarks] 「爆笑学問FILE69 : 永久エネルギー誕生!」NHK 総合テレビ、23 : 00~23 : 30、平成21年4月21日放映
• [Patent(Industrial Property Rights)] 高級脂肪酸エステルの製造方法 (2006)
  • Inventor(s): 原亨和
  • Industrial Property Rights Holder: 国立大学法人東京工業大学
  • Industrial Property Number: 特許2007-523402
  • Filing Date: 2006-06-20