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2008 Fiscal Year Annual Research Report

アジア圏におけるバイオコールコプロダクションシステムの開発

Research Project

Project/Area Number 18206092
Research InstitutionKyushu University

Principal Investigator

平島 剛  Kyushu University, 工学研究院, 教授 (00175556)

Co-Investigator(Kenkyū-buntansha) 笹木 圭子  九州大学, 工学研究院, 准教授 (30311525)
野中 壯泰  九州大学, 工学研究院, 助教 (60271102)
古山 隆  九州大学, 工学研究院, 助教 (90284546)
林 信行  佐賀大学, 農学部, 教授 (50173018)
福嶋 正巳  北海道大学, 工学研究科, 准教授 (40344113)
Keywordsアジア / バイオコール / 環境修復 / 水熱処理
Research Abstract

オートクレーブを用いた水熱処理により低品位炭の改質試験を行ったところ、改質温度が高くなるに従い、芳香族成分が増加するとともに含水率が減少し、これら2つの間には良い相関が見られた。また、ろ過時の水分に比べて平衡水分が低くなることから、疎水化が進行したことが分かった。改質の際、アルカリを添加することにより高濃度で水素が回収された。稲わらに対して加圧熱水処理と酵素処理をシーケンシャルに行い、稲わらセルロースの80%をグルコースに変換した。比較のために希硫酸処理後に酵素糖化を行ったところ、グルコース収率は原料セルロースの65%程度に留まり、加圧熱水処理の優位性が示された。また、加圧熱水処理の方が発酵阻害物質の生成量も少なく、微生物を利用した変換に適することを明らかにした。また、竹の加圧熱水処理により得られた水溶性高重合度キシランオリゴ糖をβ-グリコシダーゼ活性が低いヘミセルラーゼで処理し、高収率でキシロビオースを生産できることを示した。また、カテコール類を構造の一部に持つ腐植酸が、有害有機塩素化合物を酸化する際に酸化重合でこれらを取り込み無害化することが明らかになった。改質産物を燃焼させると、灰分由来のフライアッシュが生成し一部は粒径100μm程度の有用なセノスフェアとなる。湿式サイクロン、MGSおよび乾式風力選別の組み合わせにより、このセノスフェアを効率よく選別回収できた。九州大およびガジャマダ大学(インドネシア)において、相互に連携した研究体制を敷くことでエネルギー資源および環境修復に関するネットワークを築くことができた。

  • Research Products

    (60 results)

All 2009 2008 Other

All Journal Article (41 results) (of which Peer Reviewed: 40 results) Presentation (16 results) Book (1 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Journal Article] Generation and Prevention of Acid Mine Drainages from Mine Tailings2009

    • Author(s)
      Keiko SASAKI
    • Journal Title

      Proc. 2^<nd> International Symposium of Novel Carbon Resource Science, Earth Resource Science and Technology

      Pages: IV5-IV11

    • Peer Reviewed
  • [Journal Article] Immobilization of Manganese From Groundwater Using Low Cost Materials2009

    • Author(s)
      Wahyu WILOPO, Keiko SASAKI, Tsuyoshi HIRAJIMA
    • Journal Title

      Proc. 2^<nd> International Symposium of Novel Carbon Resource Science, Earth Resource Science and Technology

      Pages: IV43-IV47

    • Peer Reviewed
  • [Journal Article] Upgrading Mechanism of Solid Waste of Palm Oil Mill Using Hydrothermal Treatment2009

    • Author(s)
      Ahmad T. YULIANSYAH, Tsuyoshi HIRAJIMA, Keiko SASAKI
    • Journal Title

      Proc. 2^<nd> International Symposium of Novel Carbon Resource Science, Earth Resource Science and Technology

      Pages: V9-V16

    • Peer Reviewed
  • [Journal Article] Product Characterization of Raw Peat and Low Quality Coal Treated by Alkaline Hydrothermal : A Novel Method of CO2 Capturing and Hydrogen Generation2009

    • Author(s)
      Anggoro Tri MURSITO, Tsuyoshi HIRAJIMA, Keiko SASAKI
    • Journal Title

      Proc. 2^<nd> International Symposium of Novel Carbon Resource Science, Earth Resource Science and Technology

      Pages: I10-I17

    • Peer Reviewed
  • [Journal Article] Upgrading of Low Rank Coal and Woody Biomass by Hydrothermal Treatment2009

    • Author(s)
      Tsuyoshi HIRAJIMA, Moriyasu NONAKA
    • Journal Title

      Proc. 2^<nd> International Symposium of Novel Carbon Resource Science, Earth Resource Science and Technology

      Pages: I1-I9

    • Peer Reviewed
  • [Journal Article] Effects of the maturity of wood-waste compost on the structural features of humic acids2009

    • Author(s)
      M. Fukushima, K. Yamamoto, K. Ohtsuka, T. Aramaki, T. Komai, S. Ueda, K. Horiya
    • Journal Title

      Bioresource Technology 100

      Pages: 791-797

    • Peer Reviewed
  • [Journal Article] Effect of an allophanic soil on humification reactions between catechol and glycine : spectroscopic investigations of reaction products2009

    • Author(s)
      M. Fukushima, A. Miura, M. Sasaki, K. Izumo
    • Journal Title

      Journal of Molecular Structure 917

      Pages: 142-147

    • Peer Reviewed
  • [Journal Article] Recent progress in Indonesian Peat Utilization Research2008

    • Author(s)
      Anggoro Tri Mursito Tsuyoshi Hirajima
    • Journal Title

      Journal of MMIJ 124

      Pages: 871-877

    • Peer Reviewed
  • [Journal Article] Removal of Arsenate in Acid Mine Drainage by a Permeable Reactive Barrier Bearing Granulated Blast Furnace Slag : Column Study2008

    • Author(s)
      Keiko SASAKI, Shunsuke NUKINA, Wahyu WILOPO, Tsuyoshi HIRAJIMA
    • Journal Title

      Materials Transactions 49

      Pages: 835-844

    • Peer Reviewed
  • [Journal Article] Identification of Sulfate-and Arsenate-Reducing Bacteria in Sheep Manure As Permeable Reactive Materials after Arsenic Immobilization in Groundwater2008

    • Author(s)
      Wahyu WILOPO, Keiko SASAKI, Tsuyoshi HIRAJIMA
    • Journal Title

      Materials Transactions 49

      Pages: 2275-2282

    • Peer Reviewed
  • [Journal Article] Effective Utilization of Biomass Waste Using Hydrothermal2008

    • Author(s)
      Moriyasu NONAKA, Tsuyoshi HIRAJIMA, Keiko SASAKI
    • Journal Title

      Proc. XXIV International Mineral Processing Congress 3

      Pages: 3625-3629

    • Peer Reviewed
  • [Journal Article] Hydrothermal Treatment of Oil Palm Fiber and Shell -Characterization of Solid Products2008

    • Author(s)
      Ahmad T. YULIANSYAH, Tsuyoshi HIRAJIMA, Moriyasu NONAKA, Keiko SASAKI
    • Journal Title

      Proc. International Symposium on Earth Science and Technology

      Pages: 129-134

    • Peer Reviewed
  • [Journal Article] 湿式選別法を用いた石炭燃焼灰からの中空球形粒子の回収2008

    • Author(s)
      平島剛, 大迫雄司, 野中壯泰, H. T. B. M. PETRUS, 笹木圭子, 安藤隆
    • Journal Title

      Journal of MMIJ 124

      Pages: 878-884

    • Peer Reviewed
  • [Journal Article] Adsorption of SIP E. coli onto Quartz and Its Applications in Froth Flotation2008

    • Author(s)
      Mohsen FARAHAT, Tsuyoshi HIRAJIMA, Keiko SASAKI, Yuuki AIBA, Katsumi DOI
    • Journal Title

      Minerals Engineering 21

      Pages: 389-395

    • Peer Reviewed
  • [Journal Article] Immobilization of Selenate in Mine Drainage by Permeable Reactive Barriers : Column Performance2008

    • Author(s)
      Keiko SASAKI, David W. BLOWES, Carol J. PTACEK
    • Journal Title

      Applied Geochemistry 23

      Pages: 1012-1022

    • Peer Reviewed
  • [Journal Article] Spectroscopic Study of Precipitates Formed during Removal of Selenium from Mine Drainage Spiked with Selenate using Permeable Reactive Materials2008

    • Author(s)
      Keiko SASAKI, David W. BLOWES, Carol J. PTACEK
    • Journal Title

      Geochemical Journal 42

      Pages: 283-294

    • Peer Reviewed
  • [Journal Article] Immobilization of Arsenic and Manganese in Contaminated Groundwater by Permeable Reactive Barrier Using Zero Valence Iron and Sheep Manure2008

    • Author(s)
      Wahyu WILOPO, Keiko SASAKI, Tsuyoshi HIRAJIMA, Toshiro YAMANAKA
    • Journal Title

      Materials Transactions 49

      Pages: 2265-2274

    • Peer Reviewed
  • [Journal Article] Raman Characterization of Secondary Minerals Formed during Chalcopyrite Leaching with Acidithiobacillus ferrooxidans2008

    • Author(s)
      Keiko SASAKI, Yousuke NAKAMUTA, Tsuyoshi HIRAJIMA, Olli H. TUOVINEN
    • Journal Title

      Hydrometallurgy 95

      Pages: 153-158

    • Peer Reviewed
  • [Journal Article] Precipitation of Cu-sulfides by Copper-tolerant Desulfovibrio Isolates2008

    • Author(s)
      Olia V. KARNACHUK, Keiko SASAKI, Anna L. GERASIMCHUK, Olga SUKHANOVA, Denis A. IVASENKO, Anna H. KAKSONEN, Jaakko A. PUHAKKA, Olli H. TUOVINEN
    • Journal Title

      Geomicrobiology Journal 25

      Pages: 1-8

    • Peer Reviewed
  • [Journal Article] Sorption of Co^<2+> Ions on the Biogenic Mn Deposits by a Mn-Oxidizing Fungus, Paraconiothyrium sp. -Like Strain WL-22008

    • Author(s)
      Keiko SASAKI, Minoru MATSUDA, Tomohiro URATA, Tsuyoshi HIRAJIMA, H. KONNO
    • Journal Title

      Materials Transactions 49

      Pages: 605-611

    • Peer Reviewed
  • [Journal Article] Surface Characterization of As-Bearing Copper Sulfides Oxidized at Different pHs2008

    • Author(s)
      Keiko SASAKI, Koichiro TAKATSUGI, Kazuhiro ISHIKURA, Tsuyoshi HIRAJIMA
    • Journal Title

      Proc. International Symposium on Earth Science and Technology

      Pages: 687-694

    • Peer Reviewed
  • [Journal Article] Mechanism in Sorption of Fluoride Ions onto Several Types of Natural Zeolites2008

    • Author(s)
      Tomohiro URATA, Keiko SASAKI, Tsuyoshi HIRAJIMA, Robert S. BOWMAN
    • Journal Title

      Proc. International Symposium on Earth Science and Technology

      Pages: 165-172

    • Peer Reviewed
  • [Journal Article] Sorption Mechanism of Co^<2+> and Ni^<2+> Ions on the Biogenic Mn Oxide in the Binary Solute System2008

    • Author(s)
      Takuya KASEYAMA, Keiko SASAKI, Tsuyoshi HIRAJIMA
    • Journal Title

      Proc. International Symposium on Earth Science and Technology

      Pages: 157-164

    • Peer Reviewed
  • [Journal Article] Biosorption of Some Heavy Metals Using Microorganisms2008

    • Author(s)
      Takehiko TSURUTA, Yuki AIBA, Tsuyoshi HIRAJIMA, Keiko SASAKI
    • Journal Title

      Proc. the 5th of international Conference of Interface Against Pollution

      Pages: 47

    • Peer Reviewed
  • [Journal Article] Indonesian Palm Oil Industry, Solid Waste and Its Potential Utilization2008

    • Author(s)
      Ahmad T. YULIANSYAH, Tsuyoshi HIRAJIMA, ROCHMADI
    • Journal Title

      Proc. Annual Meeting (Fall) MMIJ 2008 B32-9

      Pages: 249-252

    • Peer Reviewed
  • [Journal Article] Development of On-Line Monitoring and Control System for Air Classification2008

    • Author(s)
      Satoru NAGAO, Atsunori TAYAOKA, Tsuyoshi HIRAJIMA, et al.
    • Journal Title

      Proc. International Symposium on Earth Science and Technology

      Pages: 397-402

    • Peer Reviewed
  • [Journal Article] upgrading of Biomass Using a Circulative Hydrothermal Equipment2008

    • Author(s)
      Syoutaro KAWADA, Tsuyoshi HIRAJIMA, Moriyasu NONAKA, Keiko SASAKI
    • Journal Title

      Proc. International Symposium on Earth Science and Technology

      Pages: 201-206

    • Peer Reviewed
  • [Journal Article] Role of Wood-chips in Permeable Reactive Barriers for Removal of Borate in Groundwaters2008

    • Author(s)
      Hitoshi TAKAMORI, Keiko SASAKI, Hitoshi YOSHIZAKA, Tsuyoshi HIRAJIMA
    • Journal Title

      Proc. International Symposium on Earth Science and Technology

      Pages: 181-188

    • Peer Reviewed
  • [Journal Article] Flocculation of Quartz by Microorganisms2008

    • Author(s)
      Tsuyoshi HIRAJIMA, Yuki AIBA, Mohsen FARAHAT, Keiko SASAKI, Takehiko TSURUTA, Katsumi DOI
    • Journal Title

      Proc. International Symposium on Earth Science and Technology

      Pages: 189-194

    • Peer Reviewed
  • [Journal Article] Hydrothermal Treatment of Solid Waste from Palm Oil Mill2008

    • Author(s)
      Ahmad T. YULIANSYAH, Tsuyoshi HIRAJIMA, Moriyasu NONAKA, Keiko SASAKI
    • Journal Title

      Proc. International Symposium on Earth Science and Technology

      Pages: 129-134

    • Peer Reviewed
  • [Journal Article] Catalytic Effects on Products of Alkaline Hydrothermal Treatment of Raw Peat2008

    • Author(s)
      Anggoro Tri MURSITO, Tsuyoshi HIRAJIMA, Keiko SASAKI
    • Journal Title

      Proc. International Symposium on Earth Science and Technology

      Pages: 35-42

    • Peer Reviewed
  • [Journal Article] Adsorption of Ferroplasma acidiphilum onto Pyrite and Its Affect on the Flotation of the Mineral2008

    • Author(s)
      Mohsen FARAHAT, Tsuyoshi HIRAJIMA, Keiko SASAKI
    • Journal Title

      Proc. International Symposium on Earth Science and Technology

      Pages: 389-396

    • Peer Reviewed
  • [Journal Article] Speciation of Arsenic in Treatment of Groundwaters spiked with Arsenite Using Permeable Reactive Materials2008

    • Author(s)
      Keiko SASAKI, Hironobu NAKANO, Wahyu WILOPO, Tsuyoshi HIRAJIMA
    • Journal Title

      Proc. the 5th International Conference of Interface Against Pollution

      Pages: 66

    • Peer Reviewed
  • [Journal Article] Sorption of Boric Acid on Magnesium Oxide in Permeable Reactive Barriers2008

    • Author(s)
      Keiko SASAKI, Hitoshi TAKAMORI, Hitoshi YOSHIZAKA, Tsuyoshi HIRAJIMA
    • Journal Title

      Proc. the 5th International Conference of Interface Against Pollution

      Pages: 140

    • Peer Reviewed
  • [Journal Article] Multiple polar components in poorly-humified humic acids stabilizing freeradicals : Carboxyl and nitrogen-containing carbons2008

    • Author(s)
      H. Yabuta, M. Fukushima, et al
    • Journal Title

      Organic Geochemistry 39

      Pages: 1313-1335

    • Peer Reviewed
  • [Journal Article] 有明海由来のキシロース資化性乳酸菌の分離2008

    • Author(s)
      小林元太, 岡宏圭, 田代幸寛, 加藤富民雄, 神田康三, 林信行
    • Journal Title

      生物工学会誌 86

      Pages: 217-220

    • Peer Reviewed
  • [Journal Article] 加圧熱水処理による大麦わらの可溶化および糖化2008

    • Author(s)
      熊谷聡, 太田真由美, 中野寿美, 林信行, 坂木剛
    • Journal Title

      日本食品工学会誌 9

      Pages: 115-119

    • Peer Reviewed
  • [Journal Article] Elution Behavior of Metals during Hydrothermal Decomposition of Lignocellulosic Biomass2008

    • Author(s)
      S. Kumagai, M. Ota, S. Nakano, N. Hayashi, T. Sakaki, Y. Kaida
    • Journal Title

      Jpn. J. Food Eng. 9

      Pages: 109-113

    • Peer Reviewed
  • [Journal Article] 加圧熱水処理による籾殻中セルロースの成分分離と可溶化、および可溶化物の酵素糖化によるグルコース生産2008

    • Author(s)
      熊谷聡, 太田真由美, 岡宏圭, 林信行, 山田則行, 坂木剛
    • Journal Title

      化学工学論文集 34

      Pages: 458-462

    • Peer Reviewed
  • [Journal Article] 加圧熱水処理と酵素処理を組み合わせたケナフ茎芯からのキシロースおよびキシロオリゴ糖生産2008

    • Author(s)
      熊谷聡, 中野寿美, 緒方英博, 林信行, 坂木剛
    • Journal Title

      純真紀要 34

      Pages: 269-227

  • [Journal Article] Sorption and Speciation of Arsenic by Zero-Valent Iron

    • Author(s)
      Keiko SASAKI, Hironobu NAKANO, Wahyu WILOPO, Yoshinori MIURA, Tsuyoshi HIRAJIMA
    • Journal Title

      Colloids and Surfaces A : Physicochemical and Engineering Aspects (in press)

    • Peer Reviewed
  • [Presentation] Characterization of hydrothermally-treated products of peat2009

    • Author(s)
      Anggoro Tri Mursito, Tsuyoshi Hirajima, Keiko Sasaki
    • Organizer
      資源・素材学会平成21年度春季大会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-28
  • [Presentation] 水熱処理炭の熱分解特性の改善2009

    • Author(s)
      野中壯泰, 平島剛, 笹木圭子
    • Organizer
      資源・素材学会平成21年度春季大会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-28
  • [Presentation] Upgrading of oil palm residues by hydrothermal treatment2009

    • Author(s)
      Ahmad T. Yuliansyah, Tsuyoshi Hirajima, Moriyasu Nonaka, Keiko Sasaki
    • Organizer
      資源・素材学会平成21年度春季大会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-28
  • [Presentation] AEを用いた風力選別機のためのモデリングと制御2009

    • Author(s)
      太屋岡篤憲, 長尾諭, 平島剛, 笹木圭子
    • Organizer
      資源・素材学会平成21年度春季大会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-28
  • [Presentation] Separation performance of dry separation process in cenospheres recovery from coal fly ash2009

    • Author(s)
      Tsuyoshi Hirajima, Petrus, H. T. B. M., Yuji Oosako, Moriyasu Nonaka, Keiko Sasaki, Takashi Ando
    • Organizer
      資源・素材学会平成21年度春季大会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-26
  • [Presentation] 堆肥化過程における腐植酸の構造変化-熱分解ガスクロマトグラフィー/質量分析法による解析-2009

    • Author(s)
      福嶋正巳, 山本光夫, 駒井武
    • Organizer
      資源・素材学会2009年春季大会
    • Place of Presentation
      千葉工業大学(千葉)
    • Year and Date
      2009-03-26
  • [Presentation] アロフェン土壌によるカテコールとグリシンの縮重合反応の促進 : ヒューミン様物質の構造的特色2009

    • Author(s)
      岡部亮, 三浦亮貴, 出雲健司, 福嶋正巳, 佐々木正秀
    • Organizer
      日本化学会北海道支部2009年冬季研究発表会
    • Place of Presentation
      北海道大学(札幌)
    • Year and Date
      2009-02-04
  • [Presentation] カテコールとグリシン混合液の暗色化に及ぼす粘土鉱物の物理化学的特性の解明2008

    • Author(s)
      三浦亮貴, 岡部亮, 出雲健司, 福嶋正巳
    • Organizer
      第24回日本腐植物質学会講演会
    • Place of Presentation
      北海道大学(札幌)
    • Year and Date
      2008-11-05
  • [Presentation] Indonesian palm oil industry, solid waste, and its potential utilization2008

    • Author(s)
      Ahmad T. YULIANSYAH, Tsuyoshi HIRAJIMA, ROCHMADI
    • Organizer
      資源・素材2008(仙台)
    • Place of Presentation
      仙台
    • Year and Date
      2008-10-08
  • [Presentation] 流通式水熱処理装置を用いた糖類の分解によるHMFの生成2008

    • Author(s)
      川田章太郎, 平島剛, 野中壯泰, 笹木圭子
    • Organizer
      資源・素材2008(仙台)
    • Place of Presentation
      仙台
    • Year and Date
      2008-10-08
  • [Presentation] 酸化マグネシウムを活性物質とした透過型浄化壁による地下水中のホウ素の不動化に影響を与える因子の検討2008

    • Author(s)
      吉坂仁志, 笹木圭子, 高森仁, 平島剛
    • Organizer
      資源・素材2008(仙台)
    • Place of Presentation
      仙台
    • Year and Date
      2008-10-08
  • [Presentation] AE法による風力選別機の歩留まりモニタリングと制御2008

    • Author(s)
      長尾諭, 太屋岡篤憲, 平島剛, 笹木圭子
    • Organizer
      資源・素材2008(仙台)
    • Place of Presentation
      仙台
    • Year and Date
      2008-10-07
  • [Presentation] 押出し膨化米の酵素糖化性とエタノール発酵2008

    • Author(s)
      林信行, 吉田七美, 大西真紗代, 藤田修二, 熊谷 聡
    • Organizer
      日本エネルギー学会第17回大会
    • Place of Presentation
      工学院大学
    • Year and Date
      2008-08-04
  • [Presentation] Effect of an allophane-imogolite on the formation humic-like compounds from catechol and glycine2008

    • Author(s)
      Akitaka Miura, Masami Fukushima, Masahide Sasaki, Kenji Izumo
    • Organizer
      5th International Conference on Interface Against Pollution 2008
    • Place of Presentation
      京都大学(京都)
    • Year and Date
      2008-06-02
  • [Presentation] Detoxification of organic pollutant by multi-functionalities of humic substances2008

    • Author(s)
      Masami Fukushima
    • Organizer
      5th International Conference on Interface Against Pollution 2008
    • Place of Presentation
      京都大学(京都)
    • Year and Date
      2008-06-02
  • [Presentation] エクストルーダー処理した多収穫米の酵素糖化とエタノール発酵2008

    • Author(s)
      林 信行, 吉田 七美, 藤田 修二
    • Organizer
      日本農芸化学会2008年度大会
    • Place of Presentation
      名城大学
    • Year and Date
      2008-03-29
  • [Book] 環境中の腐植物質 : その特徴と研究法2008

    • Author(s)
      石渡良志, 米林甲陽, 宮島徹, 日下部武敏, 清水芳久, 高橋嘉夫, 辰巳憲司, 田中俊逸, 力石嘉人, 筒木潔, 寺島元基, 長尾誠也, 福嶋正巳, 藤嶽暢英, 山本修一, 渡辺彰
    • Total Pages
      291
    • Publisher
      三共出版
  • [Patent(Industrial Property Rights)] 国際特許2008

    • Inventor(s)
      安藤隆, 平島剛, 野中壮泰, 大迫雄司
    • Industrial Property Rights Holder
      出光興産(株), 九州大学
    • Industrial Property Number
      International Application No. PCT/JP2008/058386
    • Filing Date
      2008-05-20
    • Overseas
  • [Patent(Industrial Property Rights)] 特許2008

    • Inventor(s)
      林信行
    • Industrial Property Rights Holder
      林信行, ミゾタ
    • Industrial Property Number
      特願2008-036721
    • Acquisition Date
      2008-02-18

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Published: 2010-06-11   Modified: 2016-04-21  

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