フラーレン誘導体による多彩なナノ・メゾスコピック構造の作製と機能開拓

2006 Fiscal Year Annual Research Report

• Project/Area Number: 18310081
• Research Institution: National Institute for Materials Science
• Principal Investigator: 有賀 克彦 独立行政法人物質・材料研究機構, ナノ有機センター, グループリーダー (50193082)
• Keywords: ナノチューブ・フラーレン / 自己組織化 / 超分子化学 / ナノ材料 / マイクロ・ナノデバイス

Research Abstract

本研究では、超分子・高分子の概念から同一フラーレン誘導体を素材としてその超分子自己組織化構造体をベースとした、ナノ・メゾスコピックオーダーの球状、ファイバー状、単層二分子膜、コーン状などの多種多様なナノカーボン集合体新素材の開発を提案する。有機・超分子化学を出発とするために、分子レベルにおける組織化形態を予測、制御でき、これまでにないナノ・メゾスコピックカーボンをセレンディピティー的に開発できる可能性を秘めている。さらに、本研究提案では、フラーレン超分子からなる次元規制型新素材の次世代カーボンマテリアルへの可能性を検討すると共に、デバイス上へのファイバー、ナノシートなどの位置選択的な配置及び実用化を視野に入れたナノデバイスの構築に取り組む。本年度の具体的な成果としては、フラーレンにアルキル鎖が3本導入された分子を合成し、それらを各種溶媒中で自己組織化することによって、様々な形態の物質を得たことが挙げられる。例えば、フラーレン二分子膜を単位構造としたディスク構造の作製に成功した。XRD、FT-IR, DSC、AFMなどの分析手法を用い、アルキル鎖部分が相互に入り組んで貫入した形の二分子膜構造を撮っていることが明らかとなった。また、溶媒を変えるだけで、ファイバー状構造、ベシクル状構造、コーン状構造が得られることも明らかとなった。さらに、スピンコート法によってHOPGなどの基板上に塗布することによって、単分子ワイアー状構造が得られることも確かめられた。さらに、分子構造の改変によって、これまでに得られたことがない室温液状のフラーレン物質が得られることも実証された。

Research Products

• [Journal Article] Lysozyme Adsorption onto Mesoporous Mateirials : Effect f Pore Geometry and Stability of Adsorbets (2007)
  • Author(s): Vinu, Ajayan, Miyahara, Masahiko, Hossain, Kazi Zakir, Takahashi, Motoi, Balasubramanian, Veerappan Vaithilingam, Mori, Toshiyuki, Ariga, Katsuhiko
  • Journal Title: J. Nanosci. Nanotechnol. 7(3) Pages: 828-832
• [Journal Article] Catalysis of a Peptidic Micellar Assembly Covalently Immobilized within Mesoporous Silica Channels : Importance of Amphiphilic Spatial Design (2007)
  • Author(s): Otani, Wataru, Kinbara, Kazushi, Zhang, Qingmin, Ariga, Katsuhiko, Aida, Takuzo
  • Journal Title: Chem. Eur.J. 13(6) Pages: 1731-1736
• [Journal Article] adsorption Myoglobin over Mesoporous Silica Molecular Sieves : Pore Size Effect and Pore-Filling Model (2007)
  • Author(s): Miyahara, Masahiko, Vinu, Ajayan, Ariga, Katsuhiko
  • Journal Title: Mater. Sci. Eng. C 27(2) Pages: 232-236
• [Journal Article] controlling the Textural Parameters of Mesoporous Carbon Materials (2007)
  • Author(s): Vinu, A, Srinivasu, P, Takahashi, M, T.Mori, T, Balasubramanian, V.V, Ariga, K.
  • Journal Title: Microporous Mesoporous Mater. 100(1-3) Pages: 20-26
• [Journal Article] Halogen-Ferr Acylation of Toluene over FeSBA-1 Molecular Sieves (2007)
  • Author(s): Vinu, A, Krithiga, T, Gokulakrishnan, N, Srinivasua, P, Anandana, S, Ariga, K, Murugesan, V, Balasubramaniand, V. V, Mori, T.
  • Journal Title: Microporous Mesoporous Mater. 100(1-3) Pages: 87-94
• [Journal Article] Mesoporous Nitrides through Nano-Hard Templating Techniches (2007)
  • Author(s): Vinu, Ajayan, Anandan, Srinivasan, Gokulakrishnan, Narasimhan, Srinivasu, Pavuluri, Mori, Toshiyuki, Ariga, Katsuhiko
  • Journal Title: Solid State Phenom. 119 Pages: 291-294
• [Journal Article] Photocatalytic Activity of La-Doped ZnO for the Degradation of Monocrotophos in Aqueous Suspension (2007)
  • Author(s): Anandan, S, Vinu, A, Sheeja Lovely, K.P.L, Gokulakrishnan, N, Srinivasu, P, Mori, T, Murugesan, V, Sivamurugan, V, Ariga, K.
  • Journal Title: J. Mol. Catal. A-Chem. 266(1-2) Pages: 149-157
• [Journal Article] Adsorption of L-Histidine over Mesoporous Carbon Molecular sieves (2006)
  • Author(s): Vinu, A, Hossain, K.Z, Satish Kumar, G, Ariga, K.
  • Journal Title: carbon 44(3) Pages: 530-536
• [Journal Article] Preparation and Catalytic Performances of Ultra Large Pore TiSBA-15 Mesoporous Molecular Sieves with Very High Ti Content (2006)
  • Author(s): Vinu, A, Srinivasu, P, Miyahara, M, Ariga, K.
  • Journal Title: J. Phys. Chem. B. 110(2) Pages: 801-806
• [Journal Article] A Novel Bis Zinc Porphyrin-Oxoporphyrinogen Donor-Acceptor Triad : Synthesis, Electrochemical, computational and Photochemical Studies (2006)
  • Author(s): Hill, Jonathan P, Sandanayaka, Atula S.D, Mc Carty, Amy Lea, Karr, Paul A, Zandler, Melvin E, Charvet, Richard, Ariga, Katsuhiko, Araki, Yasuyuki, Ito, Osamu, D'Souza, Francis
  • Journal Title: Eur. J. Org. Chem.. (3) Pages: 595-603
• [Journal Article] Adsorption Study of Heme-Proteins on SBA-15 Mesoporous Silica with Pore-Filling Models (2006)
  • Author(s): Miyahara, Masahiko, Vinu, Ajayan, Hossain, Kazi Zakir, Nakanishi, Takashi, Arga, Katsuhiko
  • Journal Title: Thin Solid Films 499(1-2) Pages: 13-18
• [Journal Article] ナノ素材「フラーレン」の形を自在に変える (2006)
  • Author(s): 中西尚志, 有賀克彦
  • Journal Title: Science ＆ Technology Journal 15(2) Pages: 30-31
• [Journal Article] Regulation of Film Electrochemistry and CO Binding of a Diruthenium Complex Embedded in Artificial Lipids on an Electrode (2006)
  • Author(s): Nakanishi, Takashi, Ariga, Katsuhiko, Thuriere, Antoine, Bear, John L, Kadish, Karl M.
  • Journal Title: Thin Solid Films 499(1-2) Pages: 349-353
• [Journal Article] Control of Morphology and Helicity of Chiral Mesoporous Silica (2006)
  • Author(s): Jin, Haiying, Liu, Zheng, Ohsuna, Tetsu, terasaki, Osamu, Inoue, Yoshihisa, Sakamoto, Kazutami, Nakanishi, Takashi, Ariga, Katsuhiko, Che, Shunai
  • Journal Title: Adv. Mater. 18(5) Pages: 593-596
• [Journal Article] Perfectly Straight Nanowires of Fullerenes Bearing Long Alkyl-Chains on Graphite (2006)
  • Author(s): Nakanishi, Takashi, Miyashita, Naoko, Michinobu, Tsuyoshi, Wakayama, Yutaka, Tsuruoka, Tohru, Ariga, Katsuhiko, Kurth, Dirk G.
  • Journal Title: J. Am. Chem. Soc. 128(19) Pages: 6328-6329
• [Journal Article] A Paradigm Shift in the Field of Molecular Recognition at the Air-Water Interface : from Static to Dynamic (2006)
  • Author(s): Ariga, Katsuhiko, Nakanishi, Takashi, Hill, Jonathan P.
  • Journal Title: Soft Matter 2(6) Pages: 465-477
• [Journal Article] Regulating the stability of 2D crystal structures using an oxidation state-dependent molecular conformation (2006)
  • Author(s): Hill, Jonathan P, Wakayama, Yutaka, Schmitt, Wolfgang, Tsuruoka, Tohru, Nakanishi, Takashi, Zandler, Melvin L, Mc Carty, Amy L, D'Souza, Francis, Milgrom, Lionel R, Ariga, Katsuhiko
  • Journal Title: Chem. Commun. (22) Pages: 2320-2322
• [Journal Article] Carbon nanocage : a large pore cage-type mesoporous carbon material as an adsorbent for biomolecules (2006)
  • Author(s): vinu, Ajayan, Miyahara, Masahiko, Mori, Toshiyuki, Ariga, Katsuhiko
  • Journal Title: J. Porous Mater. 13(3) Pages: 379-383
• [Journal Article] 超分子的手法によるフラーレンのナノ・マイクロ加工技術-燃料電池素材に向けて- (2006)
  • Author(s): 中西尚志, 有賀克彦
  • Journal Title: 月刊ディスプレイ 12(6) Pages: 67-71
• [Journal Article] Assemblies of Biomaterials in Mesoporous Media (2006)
  • Author(s): Vinu, Ajayan, Miyahara, Masahiko, Ariga, Katsuhiko
  • Journal Title: J. Nanosci. Nanotechnol 6(6) Pages: 1510-1532
• [Journal Article] Remarkable Difference of Phase Transition Behaviors between Langmuir Monolayers and Aqueous Bilayer Vesicles of Oligopeptide-Carrying Lipids (2006)
  • Author(s): Ariga, Katsuhiko, Nakanishi, Takashiあ Kawanami, Shin-ichi, Kosaka, Takatoshi, Kikuchi, Jun-ichi
  • Journal Title: J. Nanosci. Nanotechnol. 6(6) Pages: 1718-1730
• [Journal Article] Immobilization of Lysozyme onto Pore-Engineered Mesoporous A1SBA-15 (2006)
  • Author(s): Miyahara, Miyahara, Vinu, Ajayan, Ariga, Katsuhiko
  • Journal Title: J. Nanosci. Nanotechnol. 6(6) Pages: 1765-1771
• [Journal Article] Construction and Electrochemistryof Langmuir-Blodgett Films of Fullerene Lipid Composite/Hybrid Materials (2006)
  • Author(s): Nakanishi, Takashi, Kouzai, Hidetoshi, Morita, Makoto, Murakami, Hiroto, Sagara, Takamasa, Ariga, Katsuhiko, Nakashima, Naotoshi
  • Journal Title: J. Nanosci. Nanotechnol. 6(6) Pages: 1779-1785
• [Journal Article] Two-Dimensional Molecular Patterns and Their Dynamic Functions : Molecular Recognition of Aqueous Guest by Mixed Monolayer of Alkyl Cyclophane and Amphiphilic Guanidinium (2006)
  • Author(s): Ariga, Katsuhiko, Nakanishi, Takashi, Takagi, Naoko, Tanaka, Ryutaro, Kikuchi, Jun-ichi
  • Journal Title: Colloid surf. A-Physicochem. Eng. Asp. 284/285 Pages: 499-504
• [Journal Article] Electrochemistry of Fullerene C_<60> Embedded in Langmuir-Blodgett Films of Artificial Lipids on Electrodes (2006)
  • Author(s): Nakanishi, Takashi, Ariga, Katsuhiko, Morita, Makoto, Kozai, Hideaki, Taniguchi, Naoya, Murakami Hiroto, Sagara, Takamasa, Nakashima, Naotoshi
  • Journal Title: Colloid Surf. A-Physicochem. Eng. Asp. 284/285 Pages: 607-612
• [Journal Article] Characterization and Catalytic Performances of Three Dimensional Mesoporous FsSBA-1 Catalysts (2006)
  • Author(s): Vinu, Ajayan, Krithiga, Thangavelu, Balasubramanian, Veerappan V, Asthana, Anjana, Srinivasu, Pavuluri, Mori, Toshiyuki, Ariga, Katsuhiko, Ramanath, Ganapathiraman, Ganesan, Pcthuraja G.
  • Journal Title: J. Phys. Chem. B. 110(24) Pages: 11924-11931
• [Journal Article] Recent Progresses on Bio-Inorganic Nanohybrids (2006)
  • Author(s): Ariga, Katsuhiko, Vinu, Ajayan, Miyahara, Masahiko
  • Journal Title: Curr. Nanosci. 2(3) Pages: 197-210
• [Journal Article] Immobilization of Biomaterials to Nano-Assembled Films (Self-Assembled Monolayers, Langmuir-Blodgett Films, and Layer-by-Layer Assemblies) and Their Related Functions (2006)
  • Author(s): Ariga, Katsuhiko, Nakanishi, Takashi, Michinobu, Tsuyoshi
  • Journal Title: J. Nanosci. Nanotechnol. 6(8) Pages: 2278-2301
• [Journal Article] Chemically Non-equvalent Sites in Mesoporous BCN Revealed by Solid State NMR at 21.8 T (2006)
  • Author(s): Murakami, Miwa, Shimizu, Tadashi, Tansho, Masataka, Vinu, Ajayan, Ariga, Katsuhiko, Takegoshi, Kiyonori
  • Journal Title: Chem. Lett. 35(9) Pages: 986-987
• [Journal Article] a Chromogenic Indicator for Anion Reporting Based on an N-Substituted Oxoporphyrinogen (2006)
  • Author(s): Hill, Jonathan P, McCarty, Amy Lea, D'Souza, Francis, Labuta, Jan, Redshaw, Carl, Elsegood, Mark R. J, Aoyagi, Masaru, Nakanishi, Takashi, Ariga, Katsuhiko
  • Journal Title: Inorg. Chem. 45(20) Pages: 8288-8296
• [Journal Article] ナノテクに貢献する超分子の技 (2006)
  • Author(s): 有賀克彦
  • Journal Title: 化学と教育 54(9) Pages: 492-493
• [Journal Article] How Molecules Accommodate a 2D Crystal Lattice Mismatch : an Unusual 'Mixed' conformation of Tetraphenylporphyrin (2006)
  • Author(s): Hill, Jonathan P, Wakayama, Yutaka, Ariga, Katsuhiko
  • Journal Title: Phys. Chem. Chem. Phys. 8(43) Pages: 5034-5037
• [Journal Article] Mechanical Control of Enantioselectivity of Amino acid Recognition by Cholesterol-Armed Cyclen Monolayer at the Air-Water Interface (2006)
  • Author(s): Michinobu, Tsuyoshi, Shinoda, Satoshi, Nakanishi, Takashi, Hill, Jonathan P, Fujii, Kazuko, Player, Tomoko N, Tsukube, Hiroshi, Ariga, Katsuhiko
  • Journal Title: J. Am. Chem. Soc. 128(45) Pages: 14478-14479
• [Journal Article] 二次元分子パターニング (2006)
  • Author(s): 中西尚志, 有賀克彦
  • Journal Title: 表面 44(11) Pages: 415-432
• [Journal Article] New Families of Mesoporous Materials (2006)
  • Author(s): Vinu, Ajayan, Mori, Toshiyuki, Ariga, Katsuhiko
  • Journal Title: Sci. Technol. Adv. Mater. 7(8) Pages: 753-771
• [Journal Article] Room Temperature Liquid Fullerenes : An Uncommon Morphology of C_<60> Derivatives (2006)
  • Author(s): Michinobu, Tsuyoshi, Nakanishi, Takashi, Hill, Jonathan P, Funabashi, MAsahiro, Ariga, Katsuhiko
  • Journal Title: J. Am. Chem. Soc. 128(32) Pages: 10384-10385
• [Book] Supramolecular Chemistry -Fundamentals and Applications- (2006)
  • Author(s): Arga, Katsuhiko, Kunitake, Toyoki
  • Total Pages: 208
  • Publisher: Springer-Verlag