Exploration of the method to control spontaneous superstructuring feature of organic molecules using atomic scale structure of the substrate as templates

2008 Fiscal Year Final Research Report

• Project/Area Number: 18310084
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Nanomaterials/Nanobioscience
• Research Institution: National Institute of Information and Communications Technology
• Principal Investigator: TANAKA Shukichi National Institute of Information and Communications Technology, 未来ICT研究センター・ナノICTグループ, 主任研究員 (40284608)
• Co-Investigator(Renkei-kenkyūsha): SUZUKI Hitoshi 広島大学, 大学院・先端物質科学研究科, 准教授 (60359099) ; ABE Masayuki 大阪大学, 工学系研究科, 准教授 (00362666) ; 森田 清三 大阪大学, 工学系研究科, 教授 (50091757)
• Project Period (FY): 2005 – 2008
• Keywords: ナノ構造形成 / 制御

Research Abstract

一連のファインプロセス、熱履歴処理、プローブ顕微手法等によって原子レベルにて加工、調整された基板表面の局所構造を有機分子の自己組織化現象を制御する「原子テンプレート」として利用しつつ、従来行われてきた化学合成手法によって有機分子超構造の自立形成を意図的に制御する「プログラム自己組織化」の自由度を高めた。これにより、これまでの手法では実現困難な有機分子超構造の作成手法に道を開いた。

Research Products

• [Journal Article] STM Observation of Zinc(II) bridled chiroporphyrin molecules on titanium dioxide surface (2008)
  • Author(s): M. Inada, S. Tanaka, H. Suzuki, S. Mashiko, L. Scifo, B. Grevin,A. Castaings, J.-C. Marchon
  • Journal Title: Thin Solid Films 516 Pages: 2582-2585
  • Peer Reviewed
• [Journal Article] Atom-by-Atom Chemical Coordination Effect Observed in Noncontact AFM Topography of Pb/Si(111)-(o3xo3) Mosaic Phase (2008)
  • Author(s): A. Ohiso, M. Hiragaki, K. Mizuta, Y. Sugimoto, M. Abe, S. Morita
  • Journal Title: e-Journal of Surface Science and Nanotechnology 6 Pages: 79-83
  • Peer Reviewed
• [Journal Article] 原子間力顕微鏡-超高分解能イメージングから原子操作,原子識別のツール- (2008)
  • Author(s): 阿部真之、杉本宜昭、森田清三
  • Journal Title: 未来材料 8 Pages: 6-9
• [Journal Article] 有機分子によるナノ構造の形成とその評価 (2007)
  • Author(s): 鈴木仁、山田俊樹、田中秀吉、三木秀樹、上門敏也、奥野好成、益子信郎
  • Journal Title: 機能材料 27 Pages: 11-16
• [Journal Article] Drift-compensated data acquisition performed at room temperature with frequency modulation atomic force microscopy (2007)
  • Author(s): M. Abe, Y. Sugimoto, T. Namikawa, K. Morita, N. Oyabu, S. Morita
  • Journal Title: Applied Physics Letters 90 Pages: 203103-1-3
  • Peer Reviewed
• [Journal Article] Tip-Induced Local Reconstruction on the Pb/Ge(111) Surface Using Frequency Modulation Atomic Force Microscopy (2007)
  • Author(s): A. Ohiso, Y. Sugimoto, M. Abe, S. Morita
  • Journal Title: Japanese Journal of Applied Physics 19 Pages: 5582-5585
  • Peer Reviewed
• [Journal Article] Dynamic force spectroscopy using cantilever higher flexural modes (2007)
  • Author(s): Y. Sugimoto, S. Innami, M. Abe, O. Custance, S. Morita
  • Journal Title: Applied Physics Letters 91 Pages: 931200-931202
  • Peer Reviewed
• [Journal Article] 原子の指紋-原子間力顕微鏡による元素識別- (2007)
  • Author(s): 阿部真之、杉本宜昭、森田清三
  • Journal Title: 現代化学 11 Pages: 22-26
• [Journal Article] 原子分解能を有する原子間力顕微鏡法の新展開 (2007)
  • Author(s): 阿部真之、杉本宜昭、森田清三
  • Journal Title: 日本物理学会誌 62 Pages: 829-837
• [Journal Article] 基板上ポルフィリン系分子構造体のナノスケールにおける観察と配置制御 (2006)
  • Author(s): 田中秀吉、鈴木仁、上門敏也、奥野好成、益子信郎
  • Journal Title: 表面科学 27 Pages: 72-78
• [Journal Article] Conformational studies of self-organized regioregular poly (3-dodecylthiophene)s using NC-AFM in UHV condition (2006)
  • Author(s): S. Tanaka, B. Grevin, P. Rannou, H. Suzuki, S. Mashiko
  • Journal Title: Thin Solid Films 499 Pages: 168-173
  • Peer Reviewed
• [Journal Article] Frequency-Modulated Non-Contact Atomic Force Microscopy Study of Heat-Treated Oxide Surface with Organic Molecules (2006)
  • Author(s): S. Tanaka, H. Suzuki, M. Inada, T. Kamikado, S. Mashiko
  • Journal Title: Japanese Journal of Applied Physics 45 Pages: 2045-2048
  • Peer Reviewed
• [Journal Article] Scanning Tunneling Microscopy of Porphyrin-Based Molecules on TiO2 Surfaces (2006)
  • Author(s): M. Inada, L. Scifo, S. Tanaka, B. Grevin, H. Suzuki, S. Mashiko
  • Journal Title: Japanese Journal of Applied Physics 45 Pages: 2103-2105
  • Peer Reviewed
• [Presentation] Conformational Change of Porphyrin Derivative Adsorbed on Au(111) (2008)
  • Author(s): H.Yoshida, H.Sakagami, T.Takahagi, S.Tanaka, T.Kamikado, A.Otomo, H.Suzuki
  • Organizer: 8th International Conference on Nano-Molecular Electronics (ICNME 2008)
  • Place of Presentation: Kobe, Japan
  • Year and Date: 2008-12-18
• [Presentation] Fabrication of Magnetic Nanowires Sandwiched with Gold For Self-Assembling of NW sensors (2008)
  • Author(s): M.Yamanaka, M.Hori, Y.Ohya, S.Tanaka, K.Ijiro, S.Shingubara
  • Organizer: 8th International Conference on Nano-Molecular Electronics (ICNME 2008)
  • Place of Presentation: Kobe, Japan
  • Year and Date: 2008-12-17
• [Presentation] Mutual recognition and orientation of porphyrin-based molecules confined in 1-dimensional structures on a substrate (2008)
  • Author(s): S.Tanaka, T.Kamikado
  • Organizer: 4th International Meeting on Molecular Electronics(ElecMol08)
  • Place of Presentation: Grenoble, France
  • Year and Date: 2008-12-10
• [Presentation] Recognition and self-orientation of porphyrin-based molecules confined in 1-dimensional structures on a substrate (2008)
  • Author(s): S.Tanaka, T.Kamikado, A.Otomo
  • Organizer: 8th International Conference on Nano-Molecular Electronics (ICNME 2008)
  • Place of Presentation: Kobe, Japan
  • Year and Date: 2008-12-08
• [Presentation] 基板上ポルフィリン分子のSTM/AFM/KFM単一分子スケール観測 (2008)
  • Author(s): 田中秀吉、上門敏也、大友明、鈴木仁
  • Organizer: 日本物理学会年次大会
  • Place of Presentation: 岩手大学(岩手県)
  • Year and Date: 2008-09-22
• [Presentation] What factors determine SPM imaging features of organic molecules? (2008)
  • Author(s): S.Tanaka, T.Kamikado, H.Suzuki, S.Kitamura
  • Organizer: 11th International Conference on Non-Contact Atomic Force Microscopy
  • Place of Presentation: Madrid, Spain
  • Year and Date: 2008-09-17
• [Presentation] Au(111)基板上のポルフィリン誘導体分子構造の超高真空走査トンネル顕微鏡による観察 (2008)
  • Author(s): 吉田博史、坂上弘之、高荻隆行、田中秀吉、上門敏也、大友明、鈴木仁
  • Organizer: 応用物理学会学術講演会
  • Place of Presentation: 中部大学(愛知県)
  • Year and Date: 2008-09-03
• [Presentation] Frequency Modulation Atomic Force Microscopy for High-resolution Imaging in Liquids (2008)
  • Author(s): K.Suzuki, S.Kitamura, S.Tanaka, K.Kobayashi, H.Yamada
  • Organizer: International Conference on Nanoscience+Technology(ICN+T)2008
  • Place of Presentation: Keystone, Colorado
  • Year and Date: 2008-07-22
• [Presentation] 有機分子ユニットの逐次蒸着による超分子構造作成 (2008)
  • Author(s): 田中秀吉、上門敏也、照井通文、鈴木仁
  • Organizer: 日本物理学会第63回年次大会
  • Place of Presentation: 近畿大学
  • Year and Date: 2008-03-24
• [Presentation] High resolutional imaging and conformational control of nano-meter scale organic molecules using FM-NCAFM (2007)
  • Author(s): 田中秀吉、上門敏也、 鈴木仁
  • Organizer: 10th International Conference on Non-Contact Atomic Force Microscopy
  • Place of Presentation: Antalya, Turkey
  • Year and Date: 2007-09-18
• [Presentation] 基板上ナノスケール有機分子構造体の精密観測と制御-より現実的なボトムアッププロセスを目差して- (2007)
  • Author(s): 田中秀吉
  • Organizer: 応用物理学会学術講宴会
  • Place of Presentation: 北海道工業大学
  • Year and Date: 2007-09-05
• [Presentation] 酸化物基板上における単一有機分子コンフォメーションの精密観測と制御 (2006)
  • Author(s): 田中秀吉、鈴木仁、上門敏也、横山士吉、益子信郎
  • Organizer: 日本物理学会2006 年秋の分科会
  • Place of Presentation: 千葉
  • Year and Date: 20060000
• [Presentation] STM Observation of Chiral-Porphyrin molecules on titanium dioxide surface (2006)
  • Author(s): M. Inada, S. Tanaka, H. Suzuki, S. Mashiko, L. Scifo, B. Grevin, A. Castaing, J. C. Marhon
  • Organizer: The 7th Internatonal Conference on nano-molecular Electronics (ICNME 2006)
  • Place of Presentation: Kobe
  • Year and Date: 2006-12-14
• [Presentation] STM Studies of Metal-Bridged Chiroporphyrin Molecules on Reconstructed Surface (2006)
  • Author(s): H. Suzuki, S. Tanaka, S. Mashiko, M. Inada, L. Scifo, B. Grevin, A. Castaing, J. Marchon
  • Organizer: The 7th Internatonal Conference on nano-molecular Electronics (ICNME 2006)
  • Place of Presentation: Kobe
  • Year and Date: 2006-12-13
• [Presentation] FM-NCAFM Studies of Single Organic Molecules on Insulating Substrate (2006)
  • Author(s): S. Tanaka, H. Suzuki, M. Inada, T. Kaimkado, S. Mashiko,
  • Organizer: The 7th Internatonal Conference on nano-molecular Electronics (ICNME 2006)
  • Place of Presentation: Kobe
  • Year and Date: 2006-12-13
• [Presentation] FM-NCAFM Investigation of Individual Organic Molecules on Insulating Substrates (2006)
  • Author(s): 田中秀吉
  • Organizer: 応用物理学会第5回NICE討論会
  • Place of Presentation: 大阪産業大学梅田サテライト
  • Year and Date: 2006-10-31
• [Presentation] パルスレーザーアブレーション法を用いて作製した水素終端Siナノチェーンにおけるホッピング伝導 (2006)
  • Author(s): 山本裕、稲田貢、上田里永子、梅津郁朗、田中秀吉、齊藤正、杉村陽
  • Organizer: 2006年秋季第67回応用物理学会学術講演会
  • Place of Presentation: 立命館大学
  • Year and Date: 2006-09-30
• [Presentation] FM-NCAFM Investigation of Individual Organic Molecules on Insulating Substrates (2006)
  • Author(s): S. Tanaka, H. Suzuki, M. Inada, T. Kamikado, S. Mashiko
  • Organizer: Trends in Nanotechnology 2006 (TNT2006)
  • Place of Presentation: France
  • Year and Date: 2006-09-05
• [Presentation] NCAFM Studies of Nano-meter Scale Organic Molecules on Oxide Surfaces (2006)
  • Author(s): S. Tanaka, H. Suzuki, M. Inada, T. Kamikado, S. Mashiko
  • Organizer: ICN+T2006
  • Place of Presentation: Basel
  • Year and Date: 2006-08-02
• [Presentation] STM studies of metal-bridged chiroporphyrin molecules on reconstructed surfaces (2006)
  • Author(s): H. Suzuki, L. Scifo, M. Inada, S. Tanaka, B. Grevin, A. Castaing, J.-C. Marchon, S. Mashiko
  • Organizer: ICN+T2006
  • Place of Presentation: Basel
  • Year and Date: 2006-08-02
• [Presentation] Hopping Conduction in chain-like silicon nanowires (2006)
  • Author(s): M. Inada, S. Tanaka, H. Yamamoto, I. Umezu, A. Sugimura
  • Organizer: 28th International Conference on the Physics of Semiconductors (ICPS 2006)
  • Place of Presentation: Vienna
  • Year and Date: 2006-07-25
• [Presentation] FM-NCAFM investigation of incividual organic molecules on insulating substrates (2006)
  • Author(s): S. Tanaka, H. Suzuki, M. Inada, T. Kamikado. S. Mashiko,
  • Organizer: 9th International Conference on Non-Contact Atomic Force Microscopy
  • Place of Presentation: 神戸
  • Year and Date: 2006-07-17
• [Presentation] SPM applications on molecular technologies (2006)
  • Author(s): S. Tanaka
  • Organizer: International Symposium of SPM Roadmap 2006
  • Place of Presentation: 神戸
  • Year and Date: 2006-07-16
• [Book] Roadmap of Scanning Probe Microscopy (2006)
  • Author(s): S. Morita (Ed.)
  • Total Pages: 201
  • Publisher: Springer
• [Patent(Industrial Property Rights)] 試料変換アダプター方法及び機構・装置 (2008)
  • Inventor(s): 田中秀吉
  • Industrial Property Rights Holder: (独)情報通信研究機構
  • Industrial Property Number: PCT/JP2008/000227
  • Filing Date: 2008-02-14
  • Overseas
• [Patent(Industrial Property Rights)] イオンポンプ装置 (2008)
  • Inventor(s): 田中秀吉
  • Industrial Property Rights Holder: (独)情報通信研究機構
  • Industrial Property Number: PCT/JP2008/000225
  • Filing Date: 2008-02-14
  • Overseas
• [Patent(Industrial Property Rights)] イオンポンプシステム (2008)
  • Inventor(s): 田中秀吉
  • Industrial Property Rights Holder: 独立行政法人 情報通信研究機構
  • Industrial Property Number: 特願2008-33222
  • Filing Date: 2008-02-14
• [Patent(Industrial Property Rights)] プローブ (2008)
  • Inventor(s): 大友明、古海誓一、三木秀樹、鈴木仁、田中秀吉、益子信郎
  • Industrial Property Rights Holder: (独)情報通信研究機構
  • Industrial Property Number: 特許第4217794号
  • Acquisition Date: 2008-11-21
• [Patent(Industrial Property Rights)] イオンポンプ装置 (2007)
  • Inventor(s): 田中秀吉
  • Industrial Property Rights Holder: 独立行政法人 情報通信研究機構
  • Industrial Property Number: 特願2007-35568
  • Filing Date: 2007-02-18
• [Patent(Industrial Property Rights)] 試料変換アダプター方法及び機構・装置 (2007)
  • Inventor(s): 田中秀吉
  • Industrial Property Rights Holder: 独立行政法人 情報通信研究機構
  • Industrial Property Number: 特願2007-35570
  • Filing Date: 2007-02-18
• [Patent(Industrial Property Rights)] 顕微鏡及びその観測方法 (2007)
  • Inventor(s): 田中秀吉、瀧口義浩
  • Industrial Property Rights Holder: 独立行政法人 情報通信研究機構
  • Industrial Property Number: 特願2007-187560
  • Filing Date: 2007-07-18
• [Patent(Industrial Property Rights)] 精密ポジショナー (2007)
  • Inventor(s): 田中秀吉、瀧口義浩
  • Industrial Property Rights Holder: 独立行政法人 情報通信研究機構
  • Industrial Property Number: 特願2007-35571
  • Filing Date: 2007-02-18
• [Patent(Industrial Property Rights)] ポテンシャル特異点を用いたナノデバイスの製造方法 (2007)
  • Inventor(s): 田中秀吉、上門敏也、鈴木仁、益子信郎
  • Industrial Property Rights Holder: (独)情報通信研究機構
  • Industrial Property Number: 特許第3931236号
  • Acquisition Date: 2007-03-23