Research on the selective interaction between photochromic molecules and metal vapor atoms

2008 Fiscal Year Final Research Report

• Project/Area Number: 18350098
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Functional materials/Devices
• Research Institution: Osaka Kyoiku University
• Principal Investigator: TSUJIOKA Tsuyoshi Osaka Kyoiku University, 教育学部, 教授 (30346225)
• Co-Investigator(Kenkyū-buntansha): UCHIDA Kingo 龍谷大学, 理工学部, 教授 (70213436)
• Project Period (FY): 2006 – 2008
• Keywords: フォトクロミズム / 真空蒸着 / 金属 / マグネシウム / 選択蒸着 / 微細電極

Research Abstract

フォトクロミック・ジアリールエテン分子(DAE)がその異性化状態に依存して示す金属マグネシウムに対する蒸着選択性の、原因解明及びエレクトロニクス分野への応用に関する研究を行った。この蒸着選択性の原因は、光異性化に伴うガラス転移点(Tg)変化(表面の分子運動状態変化)にある。低いTg 状態では活発な表面分子運動状態にあり、Mg 蒸気原子は表面に付着後、再離脱をおこす。この原理を用いて、マスクレス蒸着による有機EL の微細陰極メタルパターン形成を実証した。

Research Products

• [Journal Article] Metal atom behavior on photochromic diarylethene surfaces-deposition rate dependence of selective Mg deposition (2009)
  • Author(s): Tsuyoshi Tsujioka, Yusuke Sesumi,Satoshi Yokojima, Shinichiro Nakamura,Kingo Uchida
  • Journal Title: New Journal of Chemistry DOI:10.1039/B823040D Pages: 0
  • Peer Reviewed
• [Journal Article] Photo-induced Reversible Topographical Changes of Photochromic Dithienylethene Microcrystalline Surfaces (2009)
  • Author(s): Norikazu Izumi, Naoki Nishikawa,Satoshi Yokojima, Yuko Kojima, ShinichiroNakamura, Seiya Kobatake, Masahiro Irie,Kingo Uchida
  • Journal Title: New Journal of Chemistry 33 Pages: 0
  • Peer Reviewed
• [Journal Article] Selective metal deposition for a structurewith a thin intermediate layer on aphotochromic diarylethene film (2009)
  • Author(s): Kyoko Masui, Rie Takagi, Yusuke Sesumi, Shinichiro Nakamura, Tsuyoshi Tsujioka
  • Journal Title: Journal of Material Chemistry 19 Pages: 3176-3180
  • Peer Reviewed
• [Journal Article] Light-controlled selective metal deposition on photopolymer films (2009)
  • Author(s): Tsuyoshi Tsujioka, Ai Matsui
  • Journal Title: Applied Physics Letters 94 Pages: 013302 - 1-3
  • Peer Reviewed
• [Journal Article] Metal patterning using maskless vacuum evaporation process based on selective deposition of photochromic diarylethene (2008)
  • Author(s): Rie Takagi, Kyoko Masui, Shinichiro Nakamura, Tsuyoshi Tsujioka
  • Journal Title: Applied Physics Letters 93 Pages: 213304-1 -3
  • Peer Reviewed
• [Journal Article] Selective Metal Deposition on Photo-switchable Molecular Surfaces (2008)
  • Author(s): Tsuyoshi Tsujioka, Yusuke Sesumi, Rie Takagi, Kyoko Masui, Satoshi Yokojima,Kingo Uchida, Shinichiro Nakamura
  • Journal Title: Journal of American Chemical Society 130 Pages: 10740-10747
  • Peer Reviewed
• [Journal Article] Photoresponsive Rolling and Bending of Thin Crystals of Chiral Diarylethenes (2008)
  • Author(s): Kingo Uchida, Shin-ichiro Sukata, Yuji Matsuzawa, Masako Akazawa, Jaap J. D.de Jong, Nathalie Katsonis, Yuko Kojima,Shinichiro Nakamura, Jetsuda Areephong,Auke Meetsma, and Ben L. Feringa
  • Journal Title: Chemical Communications Pages: 326-328
  • Peer Reviewed
• [Journal Article] Photoresponsive Dithienylethene-ureaBased Organogels with "Reversed"Behavior (2008)
  • Author(s): Masako Akazawa, Kingo Uchida, Jaap J. D. de Jong, Jetsuda Areephong, Marc Stuart, Giuseppe Caroli, Wesley R. Browne,Ben L. Feringa
  • Journal Title: Organic and Biomolecular Chemistry 6 Pages: 1544-1547
  • Peer Reviewed
• [Journal Article] Photochromic Properties of Diarylethene Derivatives Having Benzofuran and Benzothiophene Rings Based onRegioisomers (2008)
  • Author(s): Tadatsugu Yamaguchi, Kingo Uchida,Masahiro Irie
  • Journal Title: Bulletin of the Chemical Society of Japan 81/5 Pages: 644-652
  • Peer Reviewed
• [Journal Article] Super Water-Repellent Fractal Surfaces of a Photochromic Diarylethene Induced by UV Light (2008)
  • Author(s): Norikazu Izumi, Takayuki Minami,Hiroyuki Mayama, Atsushi Takata,Shinichiro Nakamura, Satoshi Yokojima,Kaoru Tsujii, Kingo Uchida
  • Journal Title: Japanese Journal of Applied Physics 47 Pages: 7298-7302
  • Peer Reviewed
• [Journal Article] Dynamic Chirality, Chirality Transfer and Aggregation Behavior of Dithienylethene Switches (2008)
  • Author(s): J.D. de Jaap Jong, Patrick van Rijn,Theodora D. Tiemersma-Wegeman, Linda N. Lucas, Wesley. R. Browne, Richard M.Kellogg, Kingo Uchida, Jan H. van Eschand Ben. L. Feringa
  • Journal Title: Tetrahedron 64 Pages: 8324-8335
  • Peer Reviewed
• [Journal Article] Photodimerization and Polymerization of PEG Derivatives through Radical Coupling using Photochemistry of Dithiocarbamate (2008)
  • Author(s): Yasuhide Nakayama, Ayaka Ishikawa,Ryo Sato, Kingo Uchida, Nobuaki Kambe
  • Journal Title: Polymer Journal 40 Pages: 1060-1066
  • Peer Reviewed
• [Journal Article] Quantum Yields and Potential Energy Surfaces: a Theoretical Study (2007)
  • Author(s): Shinichiro Nakamura, Takao Kobayashi, Atsushi Takata, Kingo Uchida,Yukako Asano, Akinori Murakami,Alexander Goldberg, Dominique Guillaumont, Satoshi Yokojima, Seiya Kobatake, Masahiro Irie
  • Journal Title: Journal of Physical Organic Chemistry 20 Pages: 821-829
  • Peer Reviewed
• [Journal Article] Substituent Effect of Diarylethenes on IR Spectra for Application of Non-destructive Readout of Photochromic Recording (2007)
  • Author(s): Atsushi Takata, Satoshi Yokojima,Hirotomo Nakagawa, Yuji Matsuzawa,Akinori Murakami, Shinichiro Nakamura,Masahiro Irie, Kingo Uchida
  • Journal Title: Journal of Physical Organic Chemistry 20 Pages: 998-1006
  • Peer Reviewed
• [Journal Article] Deposition transfection technology using a DNA complex with a thermoresponsive cationic star polymer (2007)
  • Author(s): Yue-Min Zhou, Ayaka Ishikawa,Ryohei Okahashi, Kingo Uchida, Yasushi Nemoto, Mitsuko Nakayama, YasuhideNakayama
  • Journal Title: Journal of Controlled Release 123 Pages: 239-246
  • Peer Reviewed
• [Journal Article] Synthesis and in Vitro Evaluation of Novel Star-Shaped Block Copolymers (Blocked Star Vectors) for Efficient GeneDelivery (2007)
  • Author(s): Yasuhide Nakayama, Chiaki Kakei,Ayaka Ishikawa, Yue-Min Zhou, Yasushi Nemoto, Kingo Uchida
  • Journal Title: Bioconjugate Chemistry Pages: 2037-2044
  • Peer Reviewed
• [Journal Article] Photochromism of 1,2-bis(3-n-alkyl-1-benzothiophen-2-yl)perf luorocyclopentene derivatives (2007)
  • Author(s): Tadatsugu Yamaguchi, Kingo Uchida,Masahiro Irie
  • Journal Title: Molecular Crystals and Liquid Crystals 474 Pages: 111-118
  • Peer Reviewed
• [Journal Article] Heparin Bioconjugate with a Thermoresponsive Cationic Branched Polymer: A Novel Aqueous Antithrombogenic Coating Material (2007)
  • Author(s): Yasuhide Nakayama, Ryohei Okahashi, Ryosuke Iwai, Kingo Uchida
  • Journal Title: Langmuir 23 Pages: 8206-8211
  • Peer Reviewed
• [Journal Article] Hole-injection isomerizatio of photochromic diarylethene for organic molecular memory (2006)
  • Author(s): Tsuyoshi Tsujioka, Natsuko Iefuji, Aini Jiapaer, Masahiro Irie, Shinichiro Nakamura
  • Journal Title: Applied Physics Letters 89 Pages: 222102
  • Peer Reviewed
• [Journal Article] Photoinduced Reversible Formation of Microfibrils on a Photochromic Diarylethene Microcrystalline Surface (2006)
  • Author(s): Kingo Uchida, Norikazu Izumi, Shin-ichiro Sukata, Yuko Kojima,Shinichiro Nakamura, Masahiro Irie
  • Journal Title: Angewandte Chemie International Edition 45 Pages: 6470-6473
  • Peer Reviewed
• [Journal Article] Micrometer-Scale Photochromic Recording on an Amorphous Diarylethene Film and Nondestructive Readout usingNear- Field IR Light (2006)
  • Author(s): Atsushi Takata, Masaaki Saito,Satoshi Yokojima, Akinori Murakami,Shinichiro Nakamura, Masahiro Irie,Kingo Uchida
  • Journal Title: Japanese Journal of Applied Physics 45 Pages: 7114-7120
  • Peer Reviewed
• [Journal Article] Diastereoselective Cyclisation of a Dithienylethene Switch through Single Crystal Confinement (2006)
  • Author(s): Kingo Uchida, Martin Walko, Jaap J.D. Jong, Shin-ichiro Sukata, Seiya Kobatake, Auke Meetsma, Jan H. van Esch,Ben L. Feringa
  • Journal Title: Organic & Biomolecular Chemistry 4 Pages: 1002-1006
  • Peer Reviewed
• [Presentation] Light-controllable selective metal deposition onphotochromic surfaces (2009)
  • Author(s): Yusuke Sesumi, Tsuyoshi Tsujioka
  • Organizer: Fifth International Conference on Molecular Electronics and Bioelectronics
  • Place of Presentation: 宮崎
  • Year and Date: 2009-03-17
• [Presentation] Selective metal deposition on photopolymerfilms (2009)
  • Author(s): Ai Matsui, Tsuyoshi Tsujioka
  • Organizer: Fifth International Conference on Molecular Electronics and Bioelectronics
  • Place of Presentation: 宮崎
  • Year and Date: 2009-03-17
• [Presentation] Selective Metal Deposition on PhotochromicDiarylethene Surfaces (2008)
  • Author(s): Tsuyoshi Tsujioka, Yusuke Sesumi, Kingo Uchida, Satoshi Yokojima, Shinichiro Nakamura
  • Organizer: JSPS-CNRS Seminar,New Horizons of Photochromism -from design of moleculaes to applications
  • Place of Presentation: Arras, France
  • Year and Date: 2008-10-15
• [Presentation] Fine Metal Patterning with a Mask-lessDeposition Method for Organic Electronics (2008)
  • Author(s): Yusuke Sesumi, Rie Takagi, Kyoko Masui,Satoshi Yokojima, Kingo Uchida, Shinichiro Nakamura, Tsuyoshi Tsujioka
  • Organizer: 2008 International Conference on Solid State Devices and Materials (SSDM 2008)
  • Place of Presentation: 茨城
  • Year and Date: 2008-09-25
• [Presentation] Photochromic Memory with Electronic Functions II (2008)
  • Author(s): Tsuyoshi Tsujioka
  • Organizer: International Symposiumon Optical Memroy and Optical Data Storage
  • Place of Presentation: Hawaii, USA
  • Year and Date: 2008-07-14
• [Presentation] Selective Metal Deposition/Reflection Propertyof an Amorphous Diaryethene Film (2007)
  • Author(s): Tsuyoshi Tsujioka, Satoshi Yokosima,Shinichiro Nakamura
  • Organizer: International Symposium on Organic Photochromism
  • Place of Presentation: Vancouver, Canada
  • Year and Date: 2007-10-09
• [Presentation] Metal Vapor Selective Deposition by UsingPhoto-Isomerization of PhotochromicDiarylethenes (2006)
  • Author(s): Tsuyoshi Tsujioka, Rie Takagi, Kyoko Masui,Yasushi Shiga, Shuichi Maeda, Shinichiro Nakamura
  • Organizer: IUPAC Photochemistry
  • Place of Presentation: 京都
  • Year and Date: 2006-04-04
• [Book] 次世代光メモリとシステム技術 (2009)
  • Author(s): 辻岡強(分担執筆)
  • Total Pages: 249-262.
  • Publisher: (株)シーエムシー出版
• [Book] 最新 機能性色素大全集 (2007)
  • Author(s): 辻岡強(分担執筆)
  • Total Pages: 207-221
  • Publisher: (株)技術情報協会
• [Book] 光応用技術・材料事典 (2006)
  • Author(s): 辻岡強(分担執筆)
  • Total Pages: 552-560
  • Publisher: (株)産業技術サービスセンター
• [Remarks] 新聞報道:日刊工業新聞(2007 年7 月24 日)「ジアリールエテンの特性活用:アモルファス膜にマグネ蒸着」ホームページ:大阪教育大学リポジトリ
  • URL: http://ir.lib.osaka-kyoiku.ac.jp:8080/dspace/handle/123456789/2549
• [Remarks]
  • URL: http://ir.lib.osaka-kyoiku.ac.jp:8080/dspace/handle/123456789/2178
• [Remarks]
  • URL: http://ir.lib.osaka-kyoiku.ac.jp:8080/dspace/handle/123456789/2179
• [Remarks]
  • URL: http://ir.lib.osaka-kyoiku.ac.jp:8080/dspace/handle/123456789/2180
• [Patent(Industrial Property Rights)] 有機半導体メモリとその情報記録、再生、消去方法 (2006)
  • Inventor(s): 辻岡 強 他2名
  • Industrial Property Rights Holder: 国立大学法人 大阪教育大学 他1名
  • Industrial Property Number: 特許出願2006-243230
  • Filing Date: 2006-09-07