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2008 Fiscal Year Final Research Report

Effect of flow history on higher order structure development in melt-processing of fibers and films

Research Project

  • PDF
Project/Area Number 18350113
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionTokyo Institute of Technology

Principal Investigator

KIKUTANI Takeshi  Tokyo Institute of Technology, 大学院・理工学研究科, 教授 (70153046)

Co-Investigator(Kenkyū-buntansha) SHIOYA Masatoshi  東京工業大学, 大学院・理工学研究科, 教授 (10196363)
ITO Hiroshi  山形大学, 大学院・理工学研究科, 准教授 (20259807)
TAKARADA Wataru  東京工業大学, 大学院・理工学研究科, 助教 (50467031)
Co-Investigator(Renkei-kenkyūsha) ITO Hiroshi  山形大学, 大学院・理工学研究科, 准教授 (20259807)
Project Period (FY) 2006 – 2008
Keywords分子配向 / 絡み合い / 3次元複屈折 / レーザー加熱紡糸 / 二軸延伸
Research Abstract

本研究では、溶融成形過程における温度・応力場の制御を、特に長緩和時間を有する構造の形成や緩和挙動に注目して行い、分子差の絡み合い構造の変化に関する検討を通じた、成形品の構造・物性変化の発現機構を明らかにすることを試みた。
絡み合いの状態は、高次構造解析で確認することができないため、絡み合い制御の直接的証拠は得られないが、さまざまな間接情報、数値解析の併用により、絡み合い制御の有用性の一端を明らかにすることができた。

  • Research Products

    (59 results)

All 2009 2008 2007 2006 2005 Other

All Journal Article (18 results) (of which Peer Reviewed: 18 results) Presentation (20 results) Book (20 results) Remarks (1 results)

  • [Journal Article] 溶融紡糸ポリエチレンテレフタレート繊維の力学特性に対するノズル径の影響2009

    • Author(s)
      増田正人、宝田亘、鞠谷雄士
    • Journal Title

      繊維学会誌 64, 4

    • Peer Reviewed
  • [Journal Article] Carbonaceous adsorbents produced from coffee lees2009

    • Author(s)
      K. Yamamoto, Y. Kawahara, M. Shioya
    • Journal Title

      Journal of Material Science 44, 4

      Pages: 1137-1139

    • Peer Reviewed
  • [Journal Article] High-speed Melt Spinning of Nanoparticle-filled High Molecular Weight Poly(ethylene terephthalate)2009

    • Author(s)
      K.H.Jang, B.C.Kim, W.G.Hahm, T.Kikutani
    • Journal Title

      Int. Polymer Processing 23, 2

      Pages: 370-376

    • Peer Reviewed
  • [Journal Article] Small-Angle X-ray Scattering Study on the Tensile Fracture Process of Poly(ethylene terephthalate)Fiber2008

    • Author(s)
      M. Shioya, T. Kawazoe, R. Okazaki, T.Suei, S. Sakurai, K. Yamamoto, T.Kikutani
    • Journal Title

      Macromolecules 41,13

      Pages: 4758-4765

    • Peer Reviewed
  • [Journal Article] Fiber Structure Development in High-Speed Melt Spinning of Poly(trimethylene terephthalate)(PTT)-On-line Measurement of Birefringence-2008

    • Author(s)
      K. H. Kim, H. H. Cho, H.Ito, T.Kikutani,
    • Journal Title

      Journal of Polymer Science, Part B, Polym. Physics. 46, 9

      Pages: 847-856

    • Peer Reviewed
  • [Journal Article] Development of Bicomponent Spunbond Nonwoven Webs Consisting of Ultra-fine Splitted Fibers2008

    • Author(s)
      C. Prahsarn, A. matsubara, S. Motomura, T. Kikutani
    • Journal Title

      International Polymer Processing 23, 2

      Pages: 178-182

    • Peer Reviewed
  • [Journal Article] ポリプロピレンの高速溶融紡糸における低立体規則性成分ブレンドの効果2008

    • Author(s)
      郡洋平、宝田亘、伊藤浩志、武部智明、南裕、金井俊孝、鞠谷雄士
    • Journal Title

      成形加工 20, 11

      Pages: 831-839

    • Peer Reviewed
  • [Journal Article] New insights into lamellar structure development and SAXSA/WAXD sequence appearance during uniaxial stretching of amorphous polyethylene terephthalate above glass transition temperature2008

    • Author(s)
      D. Kawakami, C. Burger, S. Ran, C. Avila-Orta, I. Sics, B. Chu, S. M. Chiao, B. S. Hsiao, T. Kikutani
    • Journal Title

      Macromolecules 41, 8

      Pages: 2859-2867

    • Peer Reviewed
  • [Journal Article] Carbonization behavior of L-tryptophan and gluten2008

    • Author(s)
      G. Nishikawa, M. Shioya, N. Iwashita, Y. Kawahara
    • Journal Title

      Journal of Materials Science 42, 6

      Pages: 2076-2080

    • Peer Reviewed
  • [Journal Article] Effects of Process Conditions on Surface Replication and Higher-order Structure Formation in Micromolding2007

    • Author(s)
      H. Ito, K. Kazama, T. Kikutani
    • Journal Title

      Macromolecular Symposia 249, 250

      Pages: 628-634

    • Peer Reviewed
  • [Journal Article] 化学処理及び高温熱処理によって得られるPVDF系炭素フィルムに含まれる細孔の形成機構2007

    • Author(s)
      小林治樹, 塩谷正俊, 山下順也, 平野豊成
    • Journal Title

      繊維学会誌 63, 6

      Pages: 152-158

    • Peer Reviewed
  • [Journal Article] Synchrotron radiation small-angle X-ray scattering study on fracture process of carbon nanotube/poly(ethylene terephthalate)composite films2007

    • Author(s)
      H. Kobayashi, M. Shioya, T. Tanaka, T. Irisawa
    • Journal Title

      Composites Science and Technology 67, 15-16

      Pages: 3209-3218

    • Peer Reviewed
  • [Journal Article] 回収PETボトルを原料とする複合繊維における繊維構造形成と捲縮の発現2006

    • Author(s)
      山本清志, 片桐正博, 古田博一, 伊藤浩志,鞠谷雄士
    • Journal Title

      成形加工 18, 1

      Pages: 80-86

    • Peer Reviewed
  • [Journal Article] Oligomer Deposition on the Surface of PET Fiber in Supercritical Carbon Dioxide Fluid2006

    • Author(s)
      Y. Kawahara, M. Kamo, K. Yamamoto, S. Ogawa, D. Terada, T. Kikutani, M. Tsuji
    • Journal Title

      Macromolecular Materials and Engineering 291, 1

      Pages: 11-15

    • Peer Reviewed
  • [Journal Article] Analysis of Necking Deformation Behavior in High-Speed In-Line Drawing Process of PET by On-Line Diameter and Velocity Measurements2006

    • Author(s)
      W. G. Hahm, H. Ito, T. Kikutani
    • Journal Title

      International Polymer Processing 21, 5

      Pages: 536-543

    • Peer Reviewed
  • [Journal Article] Structural Development and Properties of Melt Spun Poly(butylene succinate)and Poly(butylene terephthalate-co-succinate-co-adipate)Biodegradable Fibers2006

    • Author(s)
      X.Q.Shi, M. Takasaki, H. Ito, T. Kikutani
    • Journal Title

      International Polymer Processing 21, 1

      Pages: 64-69

    • Peer Reviewed
  • [Journal Article] Superstructure Evolution in Poly(ethylene terephthalate)during Uniaxial Deformation above Glass Transition Temperature2006

    • Author(s)
      D. Kawakami, S. Ran, C. Burger, C. Avila-Orta, I. Sics, B. Chu, B. S. Hsiao, T.Kikutani
    • Journal Title

      Macromolecules 39

      Pages: 909-2920

    • Peer Reviewed
  • [Journal Article] Small-angle X-ray scattering of long period structures forming bundles2006

    • Author(s)
      M.Shioya, T.Kawazoe, J.Kojima, S.Sakurai, K.Yamamoto, T.Kikutani
    • Journal Title

      Polymer 47, 10

      Pages: 3616-3628

    • Peer Reviewed
  • [Presentation] Fiber Structure Development in Melt Spinning of Polyether-ester Elastomer2009

    • Author(s)
      M. Kitayama, W. Takarada, H. Ito, T. Kikutani
    • Organizer
      Polymer Fibres 2008
    • Place of Presentation
      Manchester, UK
    • Year and Date
      20090709-11
  • [Presentation] Effect of the Blending of Low Stereoregularity Component on Spinnability and Fiber Property Development in High-speed Melt Spinning of Polypropylene2008

    • Author(s)
      Y. Kohri, W. Takarada, H. Ito, T.Kikutani, T. Takebe, H. Minami, T. Kanai
    • Organizer
      Polymer Processing Society American Regional Meeting
    • Place of Presentation
      Charleston, USA
    • Year and Date
      20081026-29
  • [Presentation] Effect of Laser-irradiation Heating on Fiber Structure Development in Melt Spinning of Polyoxymethylene2008

    • Author(s)
      Q. Yuan, W.Takarada, H. Ito, T. Kikutani
    • Organizer
      Polymer Processing Society American Regional Meeting
    • Place of Presentation
      Charleston, USA
    • Year and Date
      20081026-29
  • [Presentation] "Melt Spinning of Elastomeric Fibers", Book of Extended Abstracts2008

    • Author(s)
      X. Shi, Y. Kohri, M. Kitayama, W.Takarada, H. Ito, T. Kikutani
    • Organizer
      Asian Workshop on Polymer Processing
    • Place of Presentation
      Tokyo Japan(Keynote)(21-22)
    • Year and Date
      20080826-29
  • [Presentation] Effect of Drawing History on Higher-structure Development in Sequential Biaxial Stretching of PET Film2008

    • Author(s)
      R. Aoki, S.Yang, S.Nakai, W. Takarada, T.Kikutani
    • Organizer
      Book of Extended Abstracts, Asian Workshop on Polymer Processing
    • Place of Presentation
      Tokyo Japan(179-180)
    • Year and Date
      20080826-29
  • [Presentation] Effect of Laser-irradiation Heating in Melt Spinning Process of Polyoxymethylene2008

    • Author(s)
      Q. Yuan, W. Takarada, H. Ito, T.Kikutani
    • Organizer
      Polymer Fibres 2008
    • Place of Presentation
      Manchester, UK
    • Year and Date
      20080709-11
  • [Presentation] Development of Highstrength Polyester Fibers2008

    • Author(s)
      T. Kikutani
    • Organizer
      IUPAC Macro 2008
    • Place of Presentation
      Taipei, Taiwan(Invited)
    • Year and Date
      20080629-0704
  • [Presentation] Mechanism of Fiber Formation in Melt Spinning of Polyester ether Elastomer2008

    • Author(s)
      M. Kitayama, W. Takarada, H. Ito, T.Kikutani
    • Organizer
      Polymer Processing Society 24th Annual Meeting
    • Place of Presentation
      Salerno, Italy
    • Year and Date
      20080615-19
  • [Presentation] Fiber Structure Development in High-Speed Melt Spinning of PP/Thermo-plastic PVA Bicomponent Fibers2007

    • Author(s)
      T.Kikutani
    • Organizer
      1st International Aachen-Dresden International Textile Conference
    • Place of Presentation
      Aachen, Germany
    • Year and Date
      20071129-30
  • [Presentation] Waterquenching Melt Spinning of Poly(ethylene terephthalate)with Extraordinary Short Air Gap2007

    • Author(s)
      T.Enya, H.Ito, T.Kikutani
    • Organizer
      The Asian Workshop on Polymer Processing
    • Place of Presentation
      Daejon ,Korea
    • Year and Date
      20071021-24
  • [Presentation] Fundamental Study on Fabrication of GI-Optical Fibers Utilizing Diffusion of Low Molar Mass Additives in Melt Spinning Process2007

    • Author(s)
      T. Kikutani
    • Organizer
      International Conference on Advanced Fibers and Polymer Materials
    • Place of Presentation
      Shanghai, China(Plenary)
    • Year and Date
      20071015-17
  • [Presentation] Development of high-strength PET fibers using spin-line drawing system2007

    • Author(s)
      K. Nakahara, T. Kikutani
    • Organizer
      The Fiber Society Fall Annual Meeting and Technical Conference
    • Place of Presentation
      Davis, CA,USA
    • Year and Date
      20071009-11
  • [Presentation] Variation of drawability with storing time for melt-spun poly(ethylene terephthalate)fibers2007

    • Author(s)
      A. Hamano, T. Kikutani
    • Organizer
      The Fiber Society Fall Annual Meeting and Technical Conference
    • Place of Presentation
      Davis, CA,USA
    • Year and Date
      20071009-11
  • [Presentation] Melt spinning of poly(ethylene terephthalate)using water quenching bath placed at extremely short air-gap length2007

    • Author(s)
      T. Enya, H. Ito, T. Kikutani
    • Organizer
      The Fiber Society Fall Annual Meeting and Technical Conference
    • Place of Presentation
      Davis, CA,USA
    • Year and Date
      20071009-11
  • [Presentation] Fiber Structure Development in Melt Spinning of Thermoplastic Poly(vinyl alcohol)2007

    • Author(s)
      H. Ito, T. Kikutani
    • Organizer
      Polymer Processing Society Asia/Australia Meeting
    • Place of Presentation
      Shanghai, China
    • Year and Date
      20070712-14
  • [Presentation] Analysis of fiber formation behavior during high-speed in-line drawing process of poly(ethylene terephthalate)2007

    • Author(s)
      T. Kikutani
    • Organizer
      The 9th Asian Textile Conference
    • Place of Presentation
      Taichung, Taiwan
    • Year and Date
      20070628-30
  • [Presentation] Control of higher-order structure of fibers through modification of melt spinning process2007

    • Author(s)
      T. Kikutani
    • Organizer
      The Polymer Processing Society 23rd Annual Meeting
    • Place of Presentation
      Salvador, Brazil(Plenary)
    • Year and Date
      20070527-31
  • [Presentation] Surface properties and internal structure of micro/nano molded plastics for application to optical devices2007

    • Author(s)
      H. Ito, K. Kazama, T. Kikutani
    • Organizer
      The Polymer Processing Society 23rd Annual Meeting
    • Place of Presentation
      Salvador, Brazil
    • Year and Date
      20070527-31
  • [Presentation] Simultaneous measurements of stress and birefringence development during extensional deformation of cyclic olefin copolymer2006

    • Author(s)
      Y. Yagisawa, H. Ito, T. Kikutani
    • Organizer
      IUPAC International Symposium on Advanced Polymer for Engineering Technologies
    • Place of Presentation
      Busan, Korea
    • Year and Date
      20061010-13
  • [Presentation] Fiber Formation in Melt Spinning of Elastomeric Polymers2005

    • Author(s)
      T. Kikutani
    • Organizer
      Polymer Processing Society 25th Annual Meeting
    • Place of Presentation
      Goa, India
    • Year and Date
      20050502-05
  • [Book] 高分子材料の極限加工(65, 1)2009

    • Author(s)
      鞠谷雄士
    • Total Pages
      2-4
    • Publisher
      繊維学会誌
  • [Book] 超高強度繊維(15, 2)2009

    • Author(s)
      鞠谷雄士
    • Total Pages
      50-51
    • Publisher
      工業材料
  • [Book] レーザ照射溶融紡糸による高強度ポリエステル繊維の開発(15, 2)2008

    • Author(s)
      鞠谷雄士、風間邦彦
    • Total Pages
      128-132
    • Publisher
      レーザ加工学会誌
  • [Book] 伸長プロセスにおける溶融構造制御(Plastics Age Encyclopedia進歩編2009)2008

    • Author(s)
      鞠谷雄士
    • Total Pages
      87-97
    • Publisher
      プラスチックスエージ
  • [Book] 総論 : 高強度繊維開発(精密高分子の基礎と実用化技術、中濱精一監修)2008

    • Author(s)
      鞠谷雄士
    • Total Pages
      56-65
    • Publisher
      シーエムシー出版
  • [Book] PETの高分子量化と劣化抑制押出(精密高分子の基礎と実用化技術、中濱精一監修)2008

    • Author(s)
      垰口信一、鞠谷雄士
    • Total Pages
      271-277
    • Publisher
      シーエムシー出版
  • [Book] PET繊維化に及ぼす添加剤の効果(精密高分子の基礎と実用化技術、中濱精一監修)2008

    • Author(s)
      山崎斉、 鞠谷雄士
    • Total Pages
      278-283
    • Publisher
      シーエムシー出版
  • [Book] PETマトリックス中での添加剤の挙動(精密高分子の基礎と実用化技術、中濱精一監修)2008

    • Author(s)
      山崎斉、三好利一、鞠谷雄士
    • Total Pages
      284-289
    • Publisher
      シーエムシー出版
  • [Book] レーザー照射溶融紡糸によるPET繊維の高強度化(精密高分子の基礎と実用化技術、中濱精一監修)2008

    • Author(s)
      高田悟史、増田正人、鞠谷雄士
    • Total Pages
      290-300
    • Publisher
      シーエムシー出版
  • [Book] 紡糸線制御によるPET繊維の高強度化(精密高分子の基礎と実用化技術、中濱精一監修)2008

    • Author(s)
      仲原健介、鞠谷雄士
    • Total Pages
      301-310
    • Publisher
      シーエムシー出版
  • [Book] PET繊維高強度化要因解析(精密高分子の基礎と実用化技術、中濱精一監修)2008

    • Author(s)
      濱野陽、鞠谷雄士
    • Total Pages
      311-321
    • Publisher
      シーエムシー出版
  • [Book] 紡糸・フィルム成形-10年間の科学・技術の進歩-(20, 8)2008

    • Author(s)
      鞠谷雄士
    • Total Pages
      509-513
    • Publisher
      成形加工
  • [Book] 成形品のオフライン複屈折計測法と計測事例(LCD/光学材料における偏光・複屈折の制御・測定と応用)2008

    • Author(s)
      鞠谷雄士
    • Total Pages
      76-90
    • Publisher
      技術情報協会
  • [Book] 成形プロセスにおけるオンライン複屈折計測法と計測事例(LCD/光学材料における偏光・複屈折の制御・測定と応用)2008

    • Author(s)
      鞠谷雄士
    • Total Pages
      91-105
    • Publisher
      技術情報協会
  • [Book] ひろがる繊維の世界(53, 2)2008

    • Author(s)
      鞠谷雄士
    • Total Pages
      24-32
    • Publisher
      洗濯の科学
  • [Book] 繊維構造の形成機構と高性能繊維の開発(63, 12)2007

    • Author(s)
      鞠谷雄士
    • Total Pages
      417-422
    • Publisher
      繊維学会誌
  • [Book] プラスチックの材料設計と成形加工性(44, 525)2007

    • Author(s)
      鞠谷雄士
    • Total Pages
      18-22
    • Publisher
      ポリファイル
  • [Book] シンクロトロン放射光小角散乱を用いた繊維・フィルムの変形・破壊過程の解析(19, 3)2007

    • Author(s)
      塩谷正俊
    • Total Pages
      143-149
    • Publisher
      成形加工
  • [Book] 基礎高分子科学2006

    • Author(s)
      鞠谷雄士
    • Total Pages
      175-179
    • Publisher
      高分子学会編
  • [Book] 図解プラスチック成形材料(社)2006

    • Author(s)
      鞠谷雄士、竹村憲二監修
    • Total Pages
      283
    • Publisher
      プラスチック成形加工学会
  • [Remarks]

    • URL

      http://kikutani.op.titech.ac.jp/

URL: 

Published: 2010-06-10   Modified: 2016-04-21  

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