Ion and water transport in porous three-phase membrane electrode assembly of fuel cell

2008 Fiscal Year Final Research Report

• Project/Area Number: 18360371
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Properties in chemical engineering process/Transfer operation/Unit operation
• Research Institution: Shizuoka University
• Principal Investigator: SUDOH Masao Shizuoka University, 工学部, 教授 (80154615)
• Co-Investigator(Kenkyū-buntansha): OKANO Yasunori 静岡大学, 創造科学技術大学院, 教授 (90204007) ; TAKEDA Kazuhiro 静岡大学, 工学部, 准教授 (60274502)
• Co-Investigator(Renkei-kenkyūsha): KANAMORI Toshiyuki 産業技術総合研究所, バイニクス研究センター, 研究チーム長 (50356797)
• Project Period (FY): 2006 – 2008
• Keywords: 膜分離

Research Abstract

本研究では常温・常圧および燃料供給動力を用いないパッシブ形DMFC において放電評価、カソードインピーダンス解析及び膜電極接合体(MEA)内部の水・メタノールの透過流束の測定によりパッシブ形DMFC の水挙動を評価した。直接メタノール形燃料電池の最適起動シーケンスを求めるために動的シミュレータを作成し、モデル予測制御により起動時間を短縮することが可能となった。さらに、直接メタノール形燃料電池運転時の環境性能を評価するために、移動体に搭載した場合のLCA を行った。

Research Products

• [Journal Article] Numerical simulation of thermo-solutal Marangoni convection in the floating-zone under microgravity fields (2008)
  • Author(s): K. Hirata, A. Ishida, Y.Okano and S. Dost
  • Journal Title: J. Jpn. Soc. Microgravity, Appl 25 Pages: 333-338
• [Journal Article] Analysis of photo-induced hydration of a photochromic poly (N - isopropylacryl amide)-spiropyran copolumer thin layer by quartz crystal microbalance (2008)
  • Author(s): J. Edahiro, K.Sumaru, T. Takagi, T. Shinbo, T. Kanamori and M. Sudoh
  • Journal Title: European Polymer J 44 Pages: 300-307
• [Journal Article] LCA of the Various Vehicles in Environment and Safety Aspect (2008)
  • Author(s): K. Takeda, S. Sugioka, Y. Shimada, T. Hamaguchi, T. Kitajima and T. Fuchino
  • Journal Title: Lecture Notes in Computer Science Vol.5179 Pages: 9-16
• [Journal Article] Performance of sputterdeposited platinum cathode with Nafion and carbon loading for diret methanol fuel cells (2007)
  • Author(s): K. Makino, K. Furukawa, K. Okajima and M. Sudoh
  • Journal Title: J. Power Sources 166 Pages: 30-34
• [Journal Article] Synthesis of phospholipids contaiing perfluorooctyl group and their interfacial properties (2007)
  • Author(s): T. Kanamori, K. Sumaru, T. Takagi and T. Shinbo
  • Journal Title: J. Fluorine Chemistry 128 Pages: 133-138
• [Journal Article] Design of thin-layered membrane electrode assembly prepared by sputtering method for direct methanol fuel cells (2007)
  • Author(s): M. Sudoh, K. Nakase, M. Tauchi and K.Makino
  • Journal Title: ECS Transactions 11(1) Pages: 1397-1406
• [Journal Article] Surface modification of activated carbon with cold plasma treatment for high power capacitor (2007)
  • Author(s): S. Ohta, Y. Suzuki and M. Sudoh
  • Journal Title: Electrochemistry 75 Pages: 702-704
• [Presentation] Effect of co-existent gas in hydrogen gas through methanation of food waste on PEMFC performance (2009)
  • Author(s): S. Hoshino, and M. Sudoh
  • Organizer: Inter-Academia 2007
  • Place of Presentation: Lake Hamana
  • Year and Date: 2009-09-16
• [Presentation] 高性能電気二重層キャパシタのためのテンプレート法活性炭の細孔構造 (2009)
  • Author(s): 滝川、芹澤、鈴木、渡邊、須藤
  • Organizer: 電気化学会第76回大会
  • Place of Presentation: 京都
  • Year and Date: 2009-03-29
• [Presentation] 燃料電池作動型COセンサの応答特性 (2009)
  • Author(s): 望月、岩津、須藤
  • Organizer: 電気化学会第76回大会
  • Place of Presentation: 京都
  • Year and Date: 2009-03-29
• [Presentation] 新型食塩電解に用いる二室法Ag系触媒ガス電極の特性解析 (2009)
  • Author(s): 新井、須藤、井澤、鈴木、宇野、田中、錦
  • Organizer: 電気化学会第76回大会
  • Place of Presentation: 京都
  • Year and Date: 2009-03-29
• [Presentation] 電気二重層キャパシタの性能向上のための電極構造設計 (2009)
  • Author(s): 渡邊、滝川、小西、須藤
  • Organizer: 化学工学会第74年会
  • Place of Presentation: 横浜
  • Year and Date: 2009-03-20
• [Presentation] 電気二重層キャパシタの細孔構造を考慮したモデリング (2009)
  • Author(s): 芹澤、渡邊、須藤
  • Organizer: 化学工学会第74年会
  • Place of Presentation: 横浜
  • Year and Date: 2009-03-20
• [Presentation] プラズマ重合アニオン膜のDMFC 発電特性 (2009)
  • Author(s): 高岡、新美、須藤
  • Organizer: 化学工学会第74年会
  • Place of Presentation: 横浜
  • Year and Date: 2009-03-19
• [Presentation] 燃料電池触媒量低減のための多層化アノードの設計 (2009)
  • Author(s): 斎藤、中嶋、須藤、福原
  • Organizer: 化学工学会第74年会
  • Place of Presentation: 横浜
  • Year and Date: 2009-03-18
• [Presentation] Surface modification of sheet electrodes by CO2 cold plasma treatment for high power capacitor (2008)
  • Author(s): M. Watanabe, Y. Serizawa, T. Takikawa, K. Konishi, Y. Suzuki and M. Sudoh
  • Organizer: ACEP-3 Seoul
  • Place of Presentation: KOREA
  • Year and Date: 2008-11-11
• [Presentation] The effect of carbon dioxide in reformed anode gas on PEMFC performance (2008)
  • Author(s): A. Yamamoto, K. Arai, M. Sudoh, S. Sakai and Y. Matsmoto
  • Organizer: ACEP-3 Seoul
  • Place of Presentation: KOREA
  • Year and Date: 2008-11-11
• [Presentation] 直接メタノール形燃料電池に及ぼす二酸化炭素の影響に関する数値解析 (2008)
  • Author(s): 安藤、岡野、須藤、古川、村松、安達
  • Organizer: 日本機械学会・第21回計算力学講演会
  • Place of Presentation: 沖縄
  • Year and Date: 2008-11-01
• [Presentation] 水溶性切削油の腐敗防止のための過酸化水素生成装置の開発 (2008)
  • Author(s): 須藤、加藤
  • Organizer: 電気化学会第32回電解技術討論会
  • Place of Presentation: 上田
  • Year and Date: 2008-10-30
• [Presentation] 液供給DMFCの多層構造低触媒アノード設計法 (2008)
  • Author(s): 斎藤、中瀬、須藤
  • Organizer: 化学工学会第40回秋季大会
  • Place of Presentation: 仙台
  • Year and Date: 2008-09-26
• [Presentation] アノードガス中の二酸化炭素のPEMFC 発電性能に及ぼす影響 (2008)
  • Author(s): 新井、山本、星野、酒井、松本、須藤
  • Organizer: 化学工学会第40回秋季大会
  • Place of Presentation: 仙台
  • Year and Date: 2008-09-26
• [Presentation] テンプレート法活性炭の細孔構造制御とキャパシタ特性 (2008)
  • Author(s): 滝川、鈴木、芹澤、渡邊、須藤
  • Organizer: 化学工学会第40回秋季大会
  • Place of Presentation: 仙台
  • Year and Date: 2008-09-24
• [Presentation] Mathematical Model of the Direct Methanol Fuel Cells on Vehicle for Minimization of Start- Up Time Inter-Academia 2008 (2008)
  • Author(s): H. Nagaya, K.Takeda, M. Sudoh, Y. Okano and C. Fukuhara
  • Organizer: Pecs
  • Place of Presentation: Hungary
  • Year and Date: 2008-09-16
• [Presentation] Interface module design of hybrid simulation for a DMFC system, Inter-Academia 2008 (2008)
  • Author(s): H. Hamanaka, K. Takeda, Y. Okano, M. Sudoh and C. Fukuhara
  • Organizer: Pecs
  • Place of Presentation: Hungary
  • Year and Date: 2008-09-16
• [Presentation] Deveolment of anion exchange membrane for direct methanol fuel cells (2008)
  • Author(s): N. Takaoka, S. Niimi, H. Tsuji and M. Sudoh
  • Organizer: ECS PRiME08
  • Place of Presentation: Hawaii
  • Year and Date: 2008-07-14
• [Presentation] Effect of surface characteristics of carbon electrode on oxygen reduction process of fuel cell cathode (2008)
  • Author(s): Ono, T., A. Yamamoto, A. Iwashige and M. Sudoh
  • Organizer: ECS PRiME08
  • Place of Presentation: Hawaii
  • Year and Date: 2008-07-14
• [Presentation] Surface modification of sheet electrodes by CO2 gas cold plasma treatment for high power capacitor (2008)
  • Author(s): Y. Serizawa, M. Watanabe, T. Takikawa and M. Sudoh
  • Organizer: ECS PRiME08
  • Place of Presentation: Hawaii
  • Year and Date: 2008-07-14
• [Presentation] New catalysts for a zero-gap type gas-diffusion electrode in chlor-alkaline membrane process (2008)
  • Author(s): M. Sudoh, Y. Izawa, T. Suzuki, M. Tanaka and Y. Nishiki
  • Organizer: ECS PRiME08
  • Place of Presentation: Hawaii
  • Year and Date: 2008-07-13
• [Presentation] ハイパワーキャパシタのためのシート状電極設計と構造評価 (2008)
  • Author(s): 渡邊、鈴木、滝川、芹沢、須藤
  • Organizer: 化学工学会第73年会
  • Place of Presentation: 浜松
  • Year and Date: 2008-03-19
• [Presentation] ハイパワーキャパシタのためのメソ細孔制御を可能とするテンプレート法の開発 (2008)
  • Author(s): 鈴木、滝川、芹沢、渡邊、須藤
  • Organizer: 化学工学会第73年会
  • Place of Presentation: 浜松
  • Year and Date: 2008-03-19
• [Presentation] 陰イオン交換膜を用いるアルカリ型DMFC発電 (2008)
  • Author(s): 辻、須藤
  • Organizer: 化学工学会第73年会
  • Place of Presentation: 浜松
  • Year and Date: 2008-03-18
• [Presentation] 燃料電池カソードの酸素還元プロセスに与える炭素電極表面特性の影響 (2008)
  • Author(s): 小野、須藤
  • Organizer: 化学工学会第73年会
  • Place of Presentation: 浜松
  • Year and Date: 2008-03-18
• [Presentation] 電子線照射によるDMFC 用伝導膜の表面改質効果 (2008)
  • Author(s): 尾関、辻、須藤
  • Organizer: 化学工学会第73年会
  • Place of Presentation: 浜松
  • Year and Date: 2008-03-18
• [Presentation] 改質ガス成分中の二酸化炭素が固体高分子形年流電池に及ぼす影響 (2008)
  • Author(s): 新井、星野、酒井、松本、須藤
  • Organizer: 化学工学会第73年会
  • Place of Presentation: 浜松
  • Year and Date: 2008-03-17
• [Presentation] 触媒量低減のためのPt-Ruスパッタ法DMFCアノードの設計法 (2008)
  • Author(s): 斎藤、中瀬、須藤
  • Organizer: 化学工学会第73年会
  • Place of Presentation: 浜松
  • Year and Date: 2008-03-17
• [Presentation] LCA of a safe operative system of the clean energy for mobile use (2007)
  • Author(s): S. Sugioka and K. Takeda
  • Organizer: Inter-Academia 2007
  • Place of Presentation: カリアック(浜松)
  • Year and Date: 2007-09-27
• [Presentation] Surface modification of Nafion membrane for DMFC by high density excitation beam (2007)
  • Author(s): H. Tuji, S. Tameda and M. Sudoh
  • Organizer: AMS4
  • Place of Presentation: Taipei
  • Year and Date: 2007-08-17
• [Presentation] Surface modification of activated carbon with cold plasma treatment for high power capacitor (2007)
  • Author(s): M.Sudoh, Y. Serizawa and Y. Suzuki
  • Organizer: ICAC2007
  • Place of Presentation: Kyoto
  • Year and Date: 2007-05-29
• [Presentation] DMFC に用いるナフィオン膜の高密度光による表面改質効果 (2007)
  • Author(s): 辻、為田、須藤
  • Organizer: 化学工学会第72年会
  • Place of Presentation: 京都
  • Year and Date: 2007-03-21
• [Presentation] バイオガス共存ガスの燃料電池性能への影響 (2007)
  • Author(s): 星野、酒井、松本、須藤
  • Organizer: 化学工学会第72年会
  • Place of Presentation: 京都
  • Year and Date: 2007-03-21
• [Presentation] 燃料電池劣化要因としての過酸化水素生成に与える炭素材料の影響 (2007)
  • Author(s): 小野、辻、須藤
  • Organizer: 化学工学会第72年会
  • Place of Presentation: 京都
  • Year and Date: 2007-03-21
• [Presentation] パッシブ形DMFCのMEA 設計と水輸送 (2007)
  • Author(s): 田内、中瀬、山路、須藤
  • Organizer: 化学工学会第72年会
  • Place of Presentation: 京都
  • Year and Date: 2007-03-19
• [Presentation] Water transport phenomena of cathode in direct methanol fuel cell (2006)
  • Author(s): M. Tauchi and M. Sudoh
  • Organizer: ACEPS-1
  • Place of Presentation: Kyoto
  • Year and Date: 2006-11-16
• [Presentation] The activated carbon electrode with CO2/Ar cold plasma treatment for high power capacitor in non-aqueous electrolyte (2006)
  • Author(s): Y. Suzuki and M. Sudoh
  • Organizer: ACEPS-1
  • Place of Presentation: Kyoto
  • Year and Date: 2006-11-16
• [Presentation] Performance of thin-layered sputter-deposited platinum cathode for direct methanol fuel cells (2006)
  • Author(s): K. Nakase, M. Tauchi and M. Sudoh
  • Organizer: ACEPS-1
  • Place of Presentation: Kyoto
  • Year and Date: 2006-11-16
• [Presentation] Effect of water-proofing treatment of gas-diffusion layer on liquid water flooding in DMFC cathode (2006)
  • Author(s): M. Tauchi, A. Kanada, K. Furukawa and M. Sudoh
  • Organizer: 209 ECS
  • Place of Presentation: Denver
  • Year and Date: 2006-05-10
• [Book] 朝倉書店 (2008)
  • Author(s): 須藤雅夫(共著)
  • Total Pages: 355
  • Publisher: 化学工学-解説と演習-(改定第3版)
• [Book] テクノシステム (2007)
  • Author(s): 須藤雅夫(分担)
  • Total Pages: 800
  • Publisher: ナノテクノロジー時代の含浸技術の基礎と応用
• [Remarks]
  • URL: http://cheme.eng.shizuoka.ac.jp/sudohlab/
• [Patent(Industrial Property Rights)] 電気二重層キャパシタ電極 (2009)
  • Industrial Property Number: 特願2009-64993
  • Filing Date: 20090000
• [Patent(Industrial Property Rights)] 活性炭 (2008)
  • Inventor(s): その製造法
  • Industrial Property Rights Holder: および電気二重層キャパシタ
  • Industrial Property Number: 特願2009-287561
  • Filing Date: 20080000
• [Patent(Industrial Property Rights)] 炭素繊維織布を用いた固体高分子型燃料電池用膜電極接合体 (2008)
  • Industrial Property Number: 申請中
  • Filing Date: 20080000
• [Patent(Industrial Property Rights)] 固体高分子型燃料電池用電極 (2006)
  • Inventor(s): 膜電極接合体及び個体高分子型燃料電池
  • Patent Publication Number: 特開2007-242250
  • Filing Date: 20060000