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2007 Fiscal Year Final Research Report Summary

Magnetic field effects on the amount of active oxygen species released from semiconductor photocatalysts on light irradiation

Research Project

Project/Area Number 18550011
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionKanazawa University

Principal Investigator

NAKAGAKI Ryoichi  Kanazawa University, Graduate School of Natural Science and Technology, 教授 (20159057)

Co-Investigator(Kenkyū-buntansha) KOHTANI Shigeru  Hyogo University of Health Science, Faculty of Pharmaceutical Sciences, 講師 (00242529)
FUKUYOSHI Shuichi  Kanazawa University, Graduate School of Natural Science and Ibchnology, 助教 (10456410)
Project Period (FY) 2006 – 2007
KeywordsPhotofunctional material / Active oxygen species / Surface reactions / Magnetic field effects / Radical reactions / Chemiluminescence / Photocatalysts
Research Abstract

Superoxide anion radical (O_(2-)) and OH radical generations in suspensions of Ag metal^(-), Ag_(2)O^(-), or AgO-loaded TiO_(2) and BiVO_(4)photocatalysts in alkaline condition (at pH=12.0) were examined by means of luminal chemiluminescence(CL) and spin-trapping fluorescence technique where terephthalic acid reacts with an OH radical to afford the highly fluorescence 2-hydmxyterephthalic acie (TAOH). The observed luminal CL intensity was remarkably enhanced by the AgO loading on TiO_(2) and BiVO_(4), This can be explained in terms of augmentation of 0_(2-) production on the AgO-loaded photocatalysts due to synergetic effects on the thermocatlytic activity on the AgO surface and efficient electron-hole separation at the photocatalyst/Ag0 interface. On the other hand, the loading effects of AgO on the TAOH formation rates for the 1102 samples were much larger than those for the BiVO_(4) catalysts by ca. three orders of magnitude. The properties of 0_(2)-and OH radical generations on these photocatalysts are discussed on the basis of the luminal CL kinetids and approximate band edge positions of 710_(2), BiVO_(4), and silver oxides. No significant magnetic field effects were observed on the amount of active oxygen species released from semiconductor photocatalysts on light irradiation.

  • Research Products

    (12 results)

All 2008 2007

All Journal Article (7 results) (of which Peer Reviewed: 3 results) Presentation (4 results) Book (1 results)

  • [Journal Article] Loading effects of silver oxides upon generation of reactive oxygen Species in semiconductor photocatalysis2008

    • Author(s)
      S. Kohtani, K. Yoshida, R. Nakagaki, 他4名
    • Journal Title

      Physical Chemistry Chemical Physics 10

      Pages: 2986-2992

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Loading effects of silver oxides upon generation of reactive oxygen species in semiconductor photocatalysis2008

    • Author(s)
      S. Kohtani, K. Yoshida, T. Maekawa, A. Iwase, A. Kudo, H. Miyabe, R. Nakagaki
    • Journal Title

      10

      Pages: 2986-2992

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Magnetic field and methylene chain length effect on photochemistry of Bichromophoric chain species containing 7-nitro-2-fluorenyloxy and Anilino chromophores2007

    • Author(s)
      K. Takahashi, S. Kohtani, R. Nakagaki
    • Journal Title

      Journal of Photochemistry and Photobiology A: Chemistry 191

      Pages: 81-90

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Degradation of benzo[a]pyrene using TiO_2 and Ag-loaded BiVO_4 photo-Catalysts: Evaluation by the Ames mutagenicity assay2007

    • Author(s)
      S. Kohtani, Y. Inaoka, K. Hayakawa, R. Nakagaki
    • Journal Title

      Journal of Advanced Oxidation Technology 10

      Pages: 381-386

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Photobiol A : Chemistry, Magnetic field and methylene chain Length effects on photochemistry of bichromophoric chain Species containing 7-nitro-2-fluorenyloxy and aniline Chromophores2007

    • Author(s)
      K. Takahashi, S. Kohtani, R. Nakagaki, J. Photochem
    • Journal Title

      J. Photochem. Photobiol, A : Chemistry 191

      Pages: 81-90

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Technol., Deradation of benzo[a]pyrene using TiO_<2> and Ag-loaded BiVO_<4>2007

    • Author(s)
      S. Kohtani, Y. Inaoka, K. Hayakawa, R. Nakagaki J. Ad. Oxid
    • Journal Title

      photocatalysts : Evaluation by the Ames assay(J. Adv. Oxid. Technol) 10

      Pages: 381-386

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Synthesis, absorption, and Fluorescence properties and crystal structures of 7-amino-Coumarin derivatives, J. Photochem. Photobiol2007

    • Author(s)
      N. Kitamura, T. Fukagawa, S. Kohtani, S. Kitoh, K. Kunimoto, R. Nakagaki
    • Journal Title

      A : Chemistry 188

      Pages: 378-386

    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Time-dependent density functional theory calculation of Absorption spectra of 7-aminocoumarins2007

    • Author(s)
      K. Tokumura, N. Kitamura, S. Kohtani, R. Nakagaki
    • Organizer
      Annual Meeting on Photochemistry
    • Place of Presentation
      Shinshu University, Matsumoto
    • Year and Date
      20070926-28
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Photochemistry of 2- (ω-aminoalokoxy)-7-nitrofluorene : Photo-Smiles rearrangement revisited2007

    • Author(s)
      R. Nakagaki, T. Watanabe, K. Takahashi, T. Tago, S. Kohtani, S. Fukuyoshi, R. Nakagaki
    • Organizer
      Annual Meeting on Photochemistry
    • Place of Presentation
      Shinshu University, Matsumoto
    • Year and Date
      20070926-28
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Magnetic Field and Methylene Chain Length Effect on Photochemistry of Bichromophoric Chain Molecules Containing 7-Nitro-2-fluorenyloxy And Anilino Chromophores2007

    • Author(s)
      R. Nakagaki, K. Takahashi, S. Kohtani
    • Organizer
      XIII International Conference on Photochemistry
    • Place of Presentation
      University of Cologne Germany
    • Year and Date
      20070729-0803
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Magnetic and Methylene Chain Length Effects on Photochemistry of Bichromophoric Chain Molecules Containing 7-Nitro-2- Fluorenyloxy and Anilino Chromophores20072007

    • Author(s)
      R. Nakagaki, K. Takahashi, S. Kohtani
    • Organizer
      University of Cologne(III International Conference on Photochemistry)
    • Place of Presentation
      Germany
    • Year and Date
      20070729-0803
    • Description
      「研究成果報告書概要(欧文)」より
  • [Book] 物理系薬学IV演習編2008

    • Author(s)
      日本薬学会(分担執筆)
    • Total Pages
      280
    • Publisher
      東京化学同人
    • Description
      「研究成果報告書概要(和文)」より

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Published: 2010-02-04  

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