Catenation of transition metal chalcogenide complexes

2008 Fiscal Year Final Research Report

• Project/Area Number: 18550063
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Inorganic chemistry
• Research Institution: Okayama University of Science
• Principal Investigator: AKASHI Haruo Okayama University of Science, 自然科学研究所, 教授 (30221708)
• Project Period (FY): 2006 – 2008
• Keywords: 金属錯体化学

Research Abstract

複数の金属原子がカルコゲン原子で架橋されてできている金属錯体を基本単位として、これらを鎖状につなぎ合わせることにより、基本単位となる錯体の構造を維持しつつ、より複雑な構造をもった遷移金属カルコゲニドクラスター錯体を合成する方法を開発する研究を行った。

Research Products

• [Journal Article] Bis[hexaaquacobalt(II)]25,26,27,28-tetrahydroxy-2,8,14,19-tetrathiacalix[4] arene-5,11,17,23-tetrasulfonate monohydrate (2008)
  • Author(s): H. Akashi, M. Ichikawa
  • Journal Title: Acta Crystallographica, Section E E64(6) Pages: m797-m798
  • Peer Reviewed
• [Journal Article] Synthesis, Structures, and Magnetic Properties of Face-Sharing Heterodinuclear Ni(II)-Ln(III) (Ln= Eu, Gd, Tb, Dy) Complexes (2008)
  • Author(s): T. Yamaguchi, Y. Sunatsuki, H. Ishida, M. Kojima, H. Akashi, N. Re, N. Matsumoto, A. Pochaba, J. Mrozinski
  • Journal Title: Inorganic Chemistry 47(13) Pages: 5736-5745
  • Peer Reviewed
• [Journal Article] Synthesis, structures, and magnetic properties of doubly face-sharing heterotrinuclear NiII-LnIII-NiII (Ln = Eu, Gd, Tb, and Dy) complexes (2008)
  • Author(s): T. Yamaguchi, Y. Sunatsuki, H. Ishida, M. Kojima, H. Akashi, N. Re, N. Matsumoto, A. Pochaba, J. Mrozinski
  • Journal Title: Bulletin of the Chemical Society of Japan 81(5) Pages: 598-605
  • Peer Reviewed
• [Journal Article] Enantiopure Anthrylene-Ethynylene Cyclic Tetramer and Racemization via Rotation of Anthracene Unit about Acetylenic Axes (2008)
  • Author(s): T. Ishikawa, T. Shimasaki, H. Akashi, S. Toyota
  • Journal Title: Organic Letters 10(3) Pages: 417-420
  • Peer Reviewed
• [Journal Article] Enantiomeric Resolution of Chiral 1,8-Anthrylene Cyclic Tetramers with Acetylene and Diacetylene Linkers (2007)
  • Author(s): M. Goichi, S. Yamasaki, H. Miyahara, K. Wakamatsu, H. Akashi, and S. Toyota
  • Journal Title: Chemistry Letters 36(3) Pages: 404-405
  • Peer Reviewed
• [Journal Article] Syntheses and characterization of oxygen/sulfur-bridged incomplete cubane-type clusters, [Mo_3S_4Tp_3]^+ and [Mo_3OS_3Tp_3]^+, and a mixed-metal cubane-type cluster, [Mo_3FeS_4ClTp3_]_- X-ray structures of [Mo_3S_4Tp_3]Cl, [Mo_3O_S3Tp_3]PF_6, and [Mo_3FeS_4ClTp_3]_- (2006)
  • Author(s): T. Yamauchi, H. Takagi, T. Shibahara, H. Akashi
  • Journal Title: Inorg. Chem. 45(14) Pages: 5429-5437
  • Peer Reviewed
• [Journal Article] Absolute configuration and chiroptical properties of an enantiopure [5-chloro-2-(dimethylaminomethyl)phenyl] phenylborane complex (2006)
  • Author(s): S. Toyota, F. Ito, T. Yamamoto, H. Akashi, T. Iwanaga
  • Journal Title: Bull. Chem. Soc. Jpn. 79(5) Pages: 796-798
  • Peer Reviewed
• [Journal Article] 4-Carboxypyridinium hydrogen chloranilate monohydrate (2006)
  • Author(s): K. Gotoh, Y. Tabuchi, H. Akashi, H. Ishida
  • Journal Title: Acta Cryst. Sect. E E62(10) Pages: o4420-o4421
  • Peer Reviewed
• [Presentation] Syntheses and characterization of the compounds with sulfur-bridged cubane-type mo3pds4 core and scorpionate ligands (2008)
  • Author(s): H. Akashi, R. Yoshida, T. Shibahara
  • Organizer: XV^<th> International Winter School on Coordination Chemistry
  • Place of Presentation: Karpacz (Poland)
  • Year and Date: 20081200
• [Presentation] Syntheses and characterization of oxygen/sulfur-bridged incomplete cubane-type molybdenum and tungsten complexes with tris(pyrazolyl)ethanol ligands (2008)
  • Author(s): R. Yoshida, H. Akashi, T. Shibahara
  • Organizer: XVI^<th> International Winter School on Coordination Chemistry
  • Place of Presentation: Karpacz (Poland)
  • Year and Date: 20081200
• [Presentation] Syntheses and characterization of cubane-type molybdenum-palladium complexes with scorpionate ligands (2008)
  • Author(s): H. Akashi, R. Yoshida, K. Moriwaki, T. Shibahara
  • Organizer: 15^<th> International SPACC-CSJ
  • Place of Presentation: Osaka (Japan)
  • Year and Date: 20081100
• [Presentation] トリスピラゾリルエタノールを配位子とするモリブデン-パラジウムクラスター錯体の合成と性質 (2008)
  • Author(s): 吉田 諒一 ・ 柴原 隆志 ・ 赤司 治夫
  • Organizer: 日本化学会西日本大会
  • Place of Presentation: 長崎
  • Year and Date: 20081100
• [Presentation] 硫黄/酸素架橋不完全キュバン型M_3OS_3(M=Mo,W)骨格をもつトリスピラゾリルエタノール錯体の合成と性質 (2008)
  • Author(s): 吉田 諒一 ・ 柴原 隆志 ・ 赤司 治夫
  • Organizer: 錯体化学討論会
  • Place of Presentation: 金沢
  • Year and Date: 20080900
• [Presentation] Syntheses and characterization of sulfur-bridged incomplete cubane-type molybdenum complexes with scorpionate ligands (2007)
  • Author(s): H. Akashi and T. Shibahara
  • Organizer: 14^<th> International SPACC-CSJ Symposium, 1042
  • Place of Presentation: Taipei (Taiwan)
  • Year and Date: 20071200
• [Presentation] Syntheses and Characterization of Oxygen/Sulfur-Bridged Incomplete Cubane-Type Molybdenum Complexes with Hydrotris(Pyrazolyl)Borate Ligands (2007)
  • Author(s): H. Akashi, T. Yamauchi and T. Shibahara
  • Organizer: XV Winter School on Coordination Chemistry
  • Place of Presentation: Karpacz (Poland)
  • Year and Date: 20071200
• [Presentation] DV-Xα法を用いたヒドロトリスピラゾリルボレートを配位子とするモリブデン(V)クラスター錯体の電子状態の計算 (2007)
  • Author(s): 下瀬さちえ・坂根弦太・柴原隆志・赤司治夫
  • Organizer: 第57回錯体化学討論会 1PB-034
  • Place of Presentation: 名古屋
  • Year and Date: 20070900
• [Presentation] Isostructural compounds with sulfur-bridged incomplete cubane-type M_3S_4 cores (M = Mo, W) and tris(pyrazolyl)ethanol ligands (2007)
  • Author(s): H. Akashi and T. Shibahara
  • Organizer: The first Asian Conference on Coordination Chemistry
  • Place of Presentation: Okazaki (Japan)
  • Year and Date: 20070800
• [Presentation] Synthesis and characterization of sulfur-bridged cubane-type molybdenum-nickel complex with hydrotris(pyrazolyl)borate ligands (2007)
  • Author(s): H. Akashi
  • Organizer: XXI. International Conference on Coordination and Bioinorganic Chemistry, 19
  • Place of Presentation: Smolenice (Slovakia)
  • Year and Date: 20070800
• [Presentation] X-ray Structures and Characterizations of Iron Complexes of Thiacalixarenetetrasulfonate (2006)
  • Author(s): S. Shimose and H. Akashi
  • Organizer: The joint conference of the Asian Crystallographic Association (AsCA) and the Crystallographic Society of Japan (CrSJ) P23-133
  • Place of Presentation: Tukuba (Japan)
  • Year and Date: 20061100
• [Presentation] ヒドロトリスピラゾリルボレートを配位子とするモリブデン(V)クラスター錯体の合成と性質 (2006)
  • Author(s): 下瀬さちえ・柴原隆志・赤司治夫
  • Organizer: 第56回錯体化学討論会 1Ab19
  • Place of Presentation: 広島
  • Year and Date: 20060900
• [Presentation] 三脚型配位子を含む第一遷移金属-希土類金属系多核錯体の合成、構造および磁気的性質 (2006)
  • Author(s): 山口友佳・砂月幸成・小島正明・赤司治夫・Nazzareno Re・松本尚英・J.-P. Costes、J.-P. Tuchagues
  • Organizer: 第56回錯体化学討論会 2Ac04
  • Place of Presentation: 広島
  • Year and Date: 20060900
• [Presentation] 三脚型六座配位子を用いた同種・異種金属三核錯体の構造と磁気的性質 (2006)
  • Author(s): 小林玉実・山口友佳・砂月幸成・小島正明・赤司治夫・Nazzareno Re・松本尚英
  • Organizer: 第56回錯体化学討論会 2Ac05
  • Place of Presentation: 広島
  • Year and Date: 20060900