2009 Fiscal Year Final Research Report
Synthesis of novel functional molecules based on small metallacycloalkynes
| Project/Area Number |
18550065
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | The Institute of Physical and Chemical Research |
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Principal Investigator |
SUZUKI Noriyuki The Institute of Physical and Chemical Research, 理工学部, 准教授 (90241231)
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| Project Period (FY) |
2006 – 2009
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| Keywords | 有機金属錯体 / ジルコニウム / 環状アルキン / クムレン |
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| Research Abstract |
We recently reported versatile synthesis of stable five-membered cycloalkyne comounds that include one transition metal atom in the cyclic structures. These compound are prepared from law-valent group 4 transition metal species and 1,2,3-butatriene derivatives. The chemical and physical properties of these novel compounds, however, have not been known. In this study we prepared conjugated system of the five-membered metallacycloalkyne compounds using highly cumulated polyenes, so that the resulted compounds showed redox characters and new functional properties.
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