2007 Fiscal Year Final Research Report Summary
Study of liquid phase reforming of methanol by water for production of high purity hydrogen
| Project/Area Number |
18560742
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Kanagawa University |
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Principal Investigator |
MIYAO Toshihiro Kanagawa University, Department of material and life chemistry, Assistant professor (90312090)
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| Co-Investigator(Kenkyū-buntansha) |
NAITO Shuichi Kanagawa Univeristy, Department of material and life chemistry, Professor (20011710)
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| Project Period (FY) |
2006 – 2007
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| Keywords | Hydrogen production / Liquid phase reforming of methanol / High purity hydrogen / supported metal catalyst |
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| Research Abstract |
A liquid phase reforming of methanol is one of the promising solutions for designing new process of hydrogen production. As compared with the usual steam reforming reaction, the advantages of liquid phase reforming are making more compact and simple reaction equipment and needless of the evaporation energy of methanol aqueous solution. In this study, the liquid phase reforming of methanol with water over various supported metal catalyst in the batch reactor with suspended powder catalyst around boiling point of solution was studied. The main purpose of our study is the development of more simple and compact system for production of pure hydrogen. In our study on the methanol reforming reaction, Transition metal added Pt group catalyst exhibited much higher activity than non-modified Pt catalysts. Highly dispersed Pt species on the monolayer of added transition metal oxide exhibited excellent activity for the reforming reaction. Support effect for the catalytic activity of liquid phase reforming of methanol with water was investigated over various supported Pt-Ru bimetallic catalysts. The SiO2, TiO2, Al2O3, MgO, CeO2 and ZrO2 were used as support materials by conventional impregnation method. Basic oxide supports improved the selectivity to CO2, whereas acidic supports suppressed the catalytic activity and selectivity.
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[Journal Article] Performance and characterization of NiO-MgO solid solution modified with noble metals in oxidative steam reforming of methane under pressurized conditions2007
Author(s)
S.Kado, N.Mohammad, Y.Mukainakano, Y.Miyazawa, K.Nakao, K.Okumura, T.Miyao, S.Naito, K.Suzuki, K.Fujimoto, K.Kunimori, K.Tomishige
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Journal Title
ACS Symposium Series, Ultraclean Transportation Fuels 959
Pages: 59-72
Description
「研究成果報告書概要(和文)」より
Peer Reviewed
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[Journal Article] Performance and characterization of NiO-MgO solid solution modified with noble metals in oxidative steam reforming of methane under pressurized conditions2007
Author(s)
S. Kado, N. Mohammad, Y. Mukainakano, Y. Miyazawa, K. Nakao, K. Okumura, T. Miyao, S. Naito, K. Suzuki, K. Fujimoto, K. Kunimori, K. Tomishige
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Journal Title
ACS Symposium Series, Ultraclean Transportation Fuels 959
Pages: 59-72
Description
「研究成果報告書概要(欧文)」より
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[Journal Article] Oxidative steam reforming of methane under atmospheric and pressurized conditions over Pd/NiO-MgO solid solution catalysts2006
Author(s)
M.Nurunnabi, Y.Mukainakano, S.Kado;T.Miyazawa, K.Okumura, T.Miyao, S.Naito, K.Suzuki, K.Fujimoto, K.Kunimori, K.Tomishige
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Journal Title
Applied Catalysis, A:General 308
Pages: 1-12
Description
「研究成果報告書概要(和文)」より
Peer Reviewed
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[Journal Article] Oxidative steam reforming of methane under atmospheric and pressurized conditions over Pd/NiO-MgO solid solution catalysts.2006
Author(s)
M. Nurunnabi, Y. Mukainakano, S. Kado ; T. Miyazawa, K. Okumura, T. Miyao, S. Naito, K. Suzuki, K. Fujimoto, K. Kunimori, K. Tomishige
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Journal Title
Appl. Catal., A : General 308
Pages: 1-12
Description
「研究成果報告書概要(欧文)」より
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