2019 Fiscal Year Annual Research Report
Project/Area Number |
18F18333
|
Research Institution | Institute of Physical and Chemical Research |
Principal Investigator |
侯 召民 国立研究開発法人理化学研究所, 開拓研究本部, 主任研究員 (10261158)
|
Co-Investigator(Kenkyū-buntansha) |
MO ZHENBO 国立研究開発法人理化学研究所, 開拓研究本部, 外国人特別研究員
|
Project Period (FY) |
2018-11-09 – 2021-03-31
|
Keywords | titanium / N2 activation / N2 transformation / rigid ligands |
Outline of Annual Research Achievements |
Studies on N2 activation by transition metal hydride complexes are of particular interest and importance, but studies on well-defined N2 metal hydride complexes are still very limited. We report the synthesis and diverse transformations of a N2 dititanium hydride complex bearing the rigid acridane-based acriPNP-pincer ligands. This complex enabled N2 cleavage and hydrogenation even without additional reagents. Furthermore, diverse transformations of the N2 unit with a variety of organometallic compounds have been well established at the rigid acriPNP-ligated dititanium framework. This work has revealed many unprecedented aspects of N2 reaction chemistry, and may help open a new avenue for the design and synthesis of well-defined metal hydride complexes for N2 fixation and transformation.
|
Research Progress Status |
翌年度、交付申請を辞退するため、記入しない。
|
Strategy for Future Research Activity |
翌年度、交付申請を辞退するため、記入しない。
|
Research Products
(6 results)