Exploitation of Organic Electronic Materials of Potential Dynamic Switches for Non-equilibrium Condensed Matter Sciences

2010 Fiscal Year Final Research Report

• Project/Area Number: 18GS0208
• Research Category: Grant-in-Aid for Creative Scientific Research
• Allocation Type: Single-year Grants
• Research Institution: Kyoto University
• Principal Investigator: TANAKA Koichiro Kyoto University, 物質ー細胞統合システム拠点, 教授 (90212034)
• Co-Investigator(Kenkyū-buntansha): YAMOCHI Hideki 京都大学, 低温物質科学研究センター, 教授 (20182660) ; KOSHIHARA Shinya 東京工業大学, 理工学研究科物質科学専攻, 教授 (10192056) ; MISAKI Yohji 愛媛大学, 理工学研究科, 教授 (90202340) ; NAGAI Masaya 大阪大学, 大学院・基礎工学研究科, 准教授 (30343239)
• Co-Investigator(Renkei-kenkyūsha): MAVANI Krushna 京都大学, 物質-細胞統合システム, 拠点・研究員 (10452260) ; OSTROVSKI Denis 京都大学, 大学院・理学研究科, 研究員 ; HIRORI Hideki 京都大学, 物質-細胞統合システム, 拠点・助教 (00512469) ; OTSUKA Akihiro 京都大学, 低温物質科学研究センター, 助教 (90233171) ; MAESATO Mitsuhiko 京都大学, 大学院・理学研究科, 助教 (60324604) ; NAKANO Yoshiaki 京都大学, 低温物質科学研究センター, 助教 (60402757) ; OKIMOTO Yoichi 東京工業大学, 理工学研究科物質科学専攻, 准教授 (50356705) ; ISHIKAWA Tadahiko 東京工業大学, 理工学研究科火山流体センター, 助教 (70313327) ; ONDA Ken 東京工業大学, 総合理工学研究科化学環境学専攻, 特任准教授 (60272712) ; HISAKAZU Miyamoto 久留米工業高等専門学校, 一般理科, 教授 (30229893) ; SHIRAHATA Takashi 愛媛大学, 理工学研究科, 助教 (40360565)
• Project Period (FY): 2006 – 2010
• Keywords: 非平衡物性科学 / テラヘルツ / 有機電子材料 / 光誘起相転移

Research Abstract

We have explored organic materials that show dynamic switching phenomena in electronic properties by light irradiation. Non-equilibrium dynamics of quasi-equilibrium states has been studied by time-resolved spectroscopies and time-resolved X-ray diffraction techniques. Especially, novel light sources and experimental techniques have been developed in terahertz frequency region. In spin-crossover complexes and (EDO-TTF)_2PF_6, we found that hidden symmetry breaking should take place in the dynamical process. A simple phenomenological model was proposed to describe non-equilibrium dynamics.

Research Products

• [Journal Article] (2011)
  • Author(s): H.Hirori, A.Doi, F.Blanchard, K.Tanaka
  • Journal Title: Appl.Phys.Lett. 98 Pages: 091106 doi:10.1063/1.3560062
  • Peer Reviewed
• [Journal Article] (2011)
  • Author(s): Y.Okimoto, M.Kurashima, K.Seko, T.Ishikawa, K.Onda, S.Koshihara, T.Kyomen, M.Itoh
  • Journal Title: Phys.Rev.B 83 Pages: 161101(R)
  • Peer Reviewed
• [Journal Article] (2011)
  • Author(s): M.Nishiwaki, K.Nakamura, T.Shirahata, Y.Misaki
  • Journal Title: Chem.Lett. 40 Pages: 452-454
  • Peer Reviewed
• [Journal Article] (2011)
  • Author(s): T.Ito, K.Nakamura, T.Shirahata, T.Kawamoto, T.Mori, Y.Misaki
  • Journal Title: Chem.Lett. 40 Pages: 81-83
  • Peer Reviewed
• [Journal Article] (2010)
  • Author(s): N.Brefuel, E.Collet, H.Watanabe, M.Kojima, N.Matsumoto, L.Toupet, K.Tanaka, J.-P. Tuchagues
  • Journal Title: Chemistry-A European Journal 16 Pages: 14060
  • Peer Reviewed
• [Journal Article] (2010)
  • Author(s): K.Shinokita, H.Hirori, M.Nagai, N.Satoh, Y.Kadoya, K.Tanaka
  • Journal Title: App.Phys.Lett. 97 Pages: 211902
  • Peer Reviewed
• [Journal Article] (2010)
  • Author(s): M.Jewariya, M.Nagai, K.Tanaka
  • Journal Title: Phys.Rev.Lett. 105 Pages: 203003
  • Peer Reviewed
• [Journal Article] (2010)
  • Author(s): A.Doi, F.Blanchard, H.Hirori, K.Tanaka
  • Journal Title: Opt.Express 18 Pages: 18419
  • Peer Reviewed
• [Journal Article] (2010)
  • Author(s): T.Okada, S.Tsuji, K.Tanaka, K.Hirao, K.Tanaka
  • Journal Title: Appl.Phys.Lett. 97 Pages: 261111
  • Peer Reviewed
• [Journal Article] Excitonic Interactions with Intense Terahertz Pulses in ZnSe/ZnMgSSe Multiple Quantum Wells (2010)
  • Author(s): H.Hirori, M.Nagai, K.Tanaka
  • Journal Title: Phys.Rev.B 81 Pages: 081305(R)
  • Peer Reviewed
• [Journal Article] (2010)
  • Author(s): Y.Nakano, Y.Misaki, M.Uruichi, K.Yakushi, H.Yamochi
  • Journal Title: Physica B 405 Pages: S198-S201
  • Peer Reviewed
• [Journal Article] (2010)
  • Author(s): X.F.Shao, Y.Nakano, G.Saito, K.Yakushi, S.Koshihara, K.Tanaka, H.Yamochi
  • Journal Title: Physica B 405 Pages: S75-S78
  • Peer Reviewed
• [Journal Article] (2010)
  • Author(s): T.Murata, X.F.Shao, Y.Nakano, H.Yamochi, M.Uruichi, K.Yakushi, G.Saito, K.Tanaka
  • Journal Title: Chem.Mater. 22 Pages: 3121-3132
  • Peer Reviewed
• [Journal Article] (2010)
  • Author(s): K.Onda, M.Shimizu, F.Sakaguchi, S.Ogihara, T.Ishikawa, Y.Okimoto, S.Koshihara, X.F. Shao, Y.Nakano, H.Yamochi, G.Saito
  • Journal Title: Physica B 405 Pages: S350-S352
  • Peer Reviewed
• [Journal Article] (2010)
  • Author(s): A.Tomita, U.Kreutzer, S.Adachi, S.Koshihara, T.Jue
  • Journal Title: J.Exp.Biol. 213 Pages: 2748-2754
  • Peer Reviewed
• [Journal Article] (2010)
  • Author(s): M.Ashizawa, K.Ishidzu., M.Watanabe, T.Tanahashi, T.Shirahata, T.Kawamoto, T.Mori, Y.Misaki
  • Journal Title: Chem.Lett. 39 Pages: 1093-1095
  • Peer Reviewed
• [Journal Article] (2010)
  • Author(s): T.Shirahata, T.Morikawa, H.Miyamoto, Y.Nakano, H.Yamochi, Y.Misaki
  • Journal Title: Physica B : Condensed Matter 405 Pages: S61-S64
  • Peer Reviewed
• [Journal Article] (2009)
  • Author(s): M.Nagai, M.Jewariya, Y.Ichikawa, H.Ohtake, T.Sugiura, Y.Uehara, K.Tanaka
  • Journal Title: Opt.Express 17 Pages: 11543-11549
  • Peer Reviewed
• [Journal Article] (2009)
  • Author(s): M.Jewariya, M.Nagai, K.Tanaka
  • Journal Title: Journal of Optical Society of America B 26(9) Pages: A101
  • Peer Reviewed
• [Journal Article] (2009)
  • Author(s): T.Arikawa, M.Nagai, K.Tanaka
  • Journal Title: Chemical Physics Letters 477 Pages: 95-101
  • Peer Reviewed
• [Journal Article] (2009)
  • Author(s): N.O.Moussa, D.Ostrovskii, V.M.Garcia, G.Molnar, K.Tanaka, A.B.Gaspar, J.A.Real, A.Bousseksou
  • Journal Title: Chemical Physics Letters 477(1-3) Pages: 156-159
  • Peer Reviewed
• [Journal Article] (2009)
  • Author(s): H.Watanabe, H.Hirori, G.Molnar, A.Bousseksou, K.Tanaka
  • Journal Title: Phys.Rev.B Rapid Comm. in press
  • Peer Reviewed
• [Journal Article] (2009)
  • Author(s): Nicolas Brefuel, Hiroshi Watanabe, Loic Toupet, Jeremy Come, Naohide Matsumoto, Eric Collet, Koichiro Tanaka, Jean-Pierre Tuchagues
  • Journal Title: Angew.Chem.Int.Ed. 48 Pages: 9304-9307
  • Peer Reviewed
• [Journal Article] (2009)
  • Author(s): H.Yada, M.Nagai, K.Tanaka
  • Journal Title: Chemical Physics Letter 473 Pages: 279-283
  • Peer Reviewed
• [Journal Article] (2009)
  • Author(s): H.Yamochi, S.Koshihara
  • Journal Title: Sci.Technol.Adv.Mater. 10(http://iopscience.iop.org/1468-6996/10/2/024305/pdf/1468-6996_10_2_024305.pdf) Pages: 024305/1-6
  • Peer Reviewed
• [Journal Article] (2009)
  • Author(s): Y.Nakano, M.Takahashi, M.Sakata, H.Yamochi, G.Saito, K.Tanaka
  • Journal Title: Synth.Met. 159 Pages: 2381-2383
  • Peer Reviewed
• [Journal Article] (2009)
  • Author(s): Y.Nakano, H.Yamochi, G.Saito, M.Uruichi, K.Yakushi
  • Journal Title: J.Phys. : Conf.Ser. 148 Pages: 012007/1-4
  • Peer Reviewed
• [Journal Article] (2009)
  • Author(s): X.F.Shao, Y.Yoshida, Y.Nakano, H.Yamochi, M.Sakata, M.Maesato, A.Otsuka, G.Saito, S.Koshihara
  • Journal Title: Chem.Mater. 21 Pages: 1085-1095
  • Peer Reviewed
• [Journal Article] (2009)
  • Author(s): T.Ishikawa, N.Fukazawa, Y.Matsubara, R.Nakajima, K.Onda, Y.Okimoto, S.Koshihara, M.Lorenc, E.Collet, M.Tamura, R.Kato
  • Journal Title: Phys.Rev.B 80 Pages: 115108
  • Peer Reviewed
• [Journal Article] (2009)
  • Author(s): A.Tomita, T.Sato, K.Ichiyanagi, S.Nozawa, H.Ichikawa, M.Chollet, F.Kawai, S-Y.Park, T.Tsuduki, T.Yamamoto, S.Koshihara, S.Adachi
  • Journal Title: PNAS 106 Pages: 2612-2616
  • Peer Reviewed
• [Journal Article] (2008)
  • Author(s): T.Arikawa, M.Nagai, K.Tanaka
  • Journal Title: Chemical Physics Letters 457 Pages: 12-17
  • Peer Reviewed
• [Journal Article] (2008)
  • Author(s): H.Yada, M.Nagai, K.Tanaka
  • Journal Title: Chemical Physics Letters 464 Pages: 166-170
  • Peer Reviewed
• [Journal Article] (2008)
  • Author(s): K.R.Mavani, M.Nagai, D.S.Raa, H.Yada, I.Kawayama, M.Tonouchi, K.Tanaka
  • Journal Title: Applied Physics Letters 93 Pages: 231908
  • Peer Reviewed
• [Journal Article] (2008)
  • Author(s): S.Mouri, K.Tanaka, S.Bonhommeau, N.Ould Moussa, G.Molnar, A.Bousseksou
  • Journal Title: Phys.Rev.B 78(17) Pages: 174308
  • Peer Reviewed
• [Journal Article] (2008)
  • Author(s): X.F.Shao, Y.Nakano, M.Sakata, H.Yamochi, Y.Yoshida, M.Maesato, M.Uruichi, K.Yakushi, T.Murata, A.Otsuka, G.Saito, S.Koshihara, K.Tanaka
  • Journal Title: Chem.Mater. 20 Pages: 7551-7562
  • Peer Reviewed
• [Journal Article] (2008)
  • Author(s): Y.Nakano, K.Balodis, H.Yamochi, G.Saito, M.Uruichi, K.Yakushi
  • Journal Title: Solid State Sci. 10 Pages: 1780-1785
  • Peer Reviewed
• [Journal Article] (2008)
  • Author(s): X.F.Shao, Y.Nakano, H.Yamochi, A.D.Dubrovskiy, A.Otsuka, T.Murata, Y.Yoshida, G.Saito, S.Koshihara
  • Journal Title: J.Mater.Chem. 18 Pages: 2131-2140
  • Peer Reviewed
• [Journal Article] (2008)
  • Author(s): K.Onda, S.Ogihara, K.Yonemitsu, N.Maeshima, T.Ishikawa, Y.Okimoto, X.Shao, Y.Nakano, H.Yamochi, G.Saito, S.Koshihara
  • Journal Title: Phys.Rev.Lett. 101 Pages: 067403
  • Peer Reviewed
• [Journal Article] (2008)
  • Author(s): K.Ishizu, M.Watanabe, T.Tanahashi, Y.Misaki, M.Ashizawa, T.Mori
  • Journal Title: Journal of Physics : Conference Series 132 Pages: 012021-1-5
  • Peer Reviewed
• [Journal Article] (2007)
  • Author(s): A.Bousseksou, G.Molner, J.A.Real, K.Tanaka
  • Journal Title: Coordination Chemistry Reviews 251 Pages: 1822-1833
  • Peer Reviewed
• [Journal Article] (2007)
  • Author(s): N.Ould Moussa, E.Trzop, S.Mouri, S.Zein, G.Molnar, A.B.Gaspar, E.Collet, M.Buron-Le Cointe, J.A.Real, S.Borshch, K.Tanaka, H.Cailleau, A.Bousseksou
  • Journal Title: Phys.Rev.B 75 Pages: 054101
  • Peer Reviewed
• [Presentation] Enhancement of carrier scattering rate near the Mott density in photo-excited semiconductors (2010)
  • Author(s): K.Tanaka
  • Organizer: EOS 2010
  • Place of Presentation: Parc floral de Paris, France.
  • Year and Date: 20101025-20101028
• [Presentation] Dynamics of cooperative lattice-charge (spin) coupled phenomena induced by fs laser light irradiation studied by 100 ps time-resolved X-ray diffraction (2009)
  • Author(s): S.Koshihara, H.Ichikawa, S.Nozawa, T.Sato, A.Tomita, K.Ichiyanagi, M.Chollet, L.Guerin S.Adachi, K.Miyano
  • Organizer: Ultrafast x-ray methods for studying transient electronic structure and unclear dynamics
  • Place of Presentation: Bonn in Germany.
  • Year and Date: 20090928-20091001
• [Presentation] Dynamics of cooperative lattice-charge(spin) coupled phenomena under far equilibrium condition induced by fs laser light irradiation (2009)
  • Author(s): S.Koshihara
  • Organizer: 3rd Conference"Statistical Physics : Modern Trends and Applications"
  • Place of Presentation: Lviv, Ukraine.
  • Year and Date: 20090623-20090625
• [Presentation] Dynamical separation of two coupled order parameters in the relaxation process from the photo-induced state (2009)
  • Author(s): K.Tanaka
  • Organizer: 5^<th> International Symposium on Molecular Magnetism
  • Place of Presentation: Rennes, France
  • Year and Date: 2009-09-28
• [Presentation] Structural Feature of Peculiar Metal-Insulator Transition Observed in (EDO-TTF)_2PF_6 (2008)
  • Author(s): H.Yamochi
  • Organizer: The 21st International Union of Crystallography Satellite Meeting "Molecular Crystals Exhibiting Exotic Functions"
  • Place of Presentation: Osaka, Senri-Life Science Center, Japan.
  • Year and Date: 20080821-20080822
• [Presentation] Terahertz Attenuated Total Reflection Spectroscopy for materials Sciences (2008)
  • Author(s): K.Tanaka
  • Organizer: International Symposium on Molecular Materials (MOLMAT)
  • Place of Presentation: Toulouse, France.
  • Year and Date: 20080708-20080711
• [Presentation] Terahertz time-domain attenuated total reflection spectroscopy for photo-induced phase transition (2008)
  • Author(s): K.Tanaka
  • Organizer: 3rd International Conference on Photo-Induced Phase Transitions and Cooperative Phenomena (PIPT2008)
  • Place of Presentation: Osaka, Japan.
  • Year and Date: 2008-11-12
• [Presentation] Dynamical Aspects of the Photo-induced Spin transition in the Spin-crossover complex (2007)
  • Author(s): K.Tanaka, H.Watanabe, S.Mouri, S.Yokoyama, G.Molnar, A.Bousseksou
  • Organizer: 4^<th> Japan-France Symposium on Molecular Materials, Electronics, Photonics, and Spintoronics
  • Place of Presentation: Tokyo, Japan.
  • Year and Date: 2007-03-09
• [Book] 固体物理(動的構造観測技術のもたらす光誘起協同現象研究の発展)Vol.44、No.519 (2009)
  • Author(s): 腰原伸也、足立伸一、野澤俊介、一柳光平、佐藤篤志、富田文菜、市川広彦、田崎遼子、M.Chollet、L.Guerin、河田洋、大門正博
  • Total Pages: 13-25
• [Book] 化学と工業(光で強誘電相転移を操る)Vol.62、8 (2009)
  • Author(s): 腰原伸也
• [Book] 応用物理(「テラヘルツ時間領域分光の基礎と応用」)75(2) (2007)
  • Author(s): 永井正也、田中耕一郎
  • Total Pages: 179-187
• [Book] セラミック(「テラヘルツ分光で何が見えるか」)42、4月号 (2007)
  • Author(s): 田中耕一郎
• [Book] 月刊オプトロニクス(「テラヘルツ分光が切り開く材料科学」)26、2月号 (2007)
  • Author(s): 田中耕一郎
• [Book] 学術月報 59巻"分子性結晶における金属-絶縁体転移系の超高速・高効率光制御" (2006)
  • Author(s): 腰原伸也、矢持秀起
  • Total Pages: 804-809
  • Publisher: 日本学術振興会
• [Book] 「光誘起相転移」、「光物性の基礎と応用」分担執筆光物性研究会編 (2006)
  • Author(s): 田中耕一郎
  • Publisher: オプトロニクス社
• [Remarks] ホームページ 学術創成プロジェクト
  • URL: http://www.hikari.scphys.kyoto-u.ac.jp/jp/index.php?