2010 Fiscal Year Final Research Report
Sequenced Precision Macromolecules : Interdisciplinary Creation of Novel Polymer Science
| Project/Area Number |
18GS0209
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| Research Category |
Grant-in-Aid for Creative Scientific Research
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| Allocation Type | Single-year Grants |
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| Research Institution | Kyoto University |
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Principal Investigator |
SAWAMOTO Mitsuo Kyoto University, 大学院・工学研究科, 教授 (90150325)
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| Co-Investigator(Kenkyū-buntansha) |
MAKOTO Ouchi 京都大学, 大学院・工学研究科, 准教授 (90394874)
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| Project Period (FY) |
2006 – 2010
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| Keywords | 高分子合成 / 連鎖制御 / 重合触媒 / 精密重合 / 機能性高分子 / 鋳型 / シークエンス / 配位子 |
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| Research Abstract |
The most fundamental in macromolecules (polymers) is "sequence", the placement and the order of functional groups (repeat units from monomers) along a backbone, as seen in proteins and DNA. Pioneering and unprecedented in polymer science, this project is to achieve the precision "sequence control" in synthetic macromolecules and has eventually led to novel catalysts and promising methodologies that enable placing multiple functional groups at specific positions in a specific order (i.e., sequence) in macromolecules.
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[Journal Article] Ethanol-Mediated Living Radical Homoand Copolymerizations with Cp*-Ruthenium Catalysts : Active, Robust, and Universal for Functionalized Methacrylates.2010
Author(s)
Yoda, H., Nakatani, K., Terashima, T., Ouchi, M., Sawamoto, M.
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Journal Title
Macromolecules 43
Pages: 5595-5601
Peer Reviewed
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[Journal Article] Bisphosphine Monoxide-Ligated Ruthenium Catalysts : Active, Versatile, Removable, and Cocatalyst-Free in Living Radical Polymerization.2010
Author(s)
Fukuzaki, Y., Tomita, Y., Terashima, T., Ouchi, M., Sawamoto, M.
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Journal Title
Macromolecules 43
Pages: 989-5995
Peer Reviewed
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