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2011 Fiscal Year Final Research Report

Understanding and Control of Electronic Properties of Nanometer-thick Dielectric Films

Research Project

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Project/Area Number 19106005
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Research Field Electronic materials/Electric materials
Research InstitutionThe University of Tokyo

Principal Investigator

TORIUMI Akira  東京大学, 大学院・工学系研究科, 教授 (50323530)

Co-Investigator(Kenkyū-buntansha) KITA Koji  東京大学, 大学院・工学系研究科, 准教授 (00343145)
NISHIMURA Tomonori  東京大学, 大学院・工学系研究科, 技術専門職員 (10396781)
Co-Investigator(Renkei-kenkyūsha) KITA Koji  東京大学, 大学院・工学系研究科, 准教授 (00343145)
NISHIMURA Tomonori  東京大学, 大学院・工学系研究科, 技術専門職員 (10396781)
Project Period (FY) 2007 – 2011
Keywords電気・電子材料 / 誘電体物性 / 超薄膜 / 表面・界面物性
Research Abstract

The gate insulator thickness is required to be thinned for enhancing semiconductor device performances. This project has aimed at the thinning the insulator thickness electrically by increasing the dielectric constant of the films instead of thinning the physical thickness. Through this research, the energy barrier heights of the insulator films with regard to Si have been obtained systematically. In addition, the stability of dielectric constant, the dipoles formed at interfaces between such films and conventional insulator(SiO_2) have been deeply investigated and modeled in terms of atom kinetics in the bulk films and at the interfaces. Furthermore, hygroscopic properties of rare-earth metal oxides have been characterized thermodynamically and the defect generation origin in GeO_2 which will be a new insulator for new semiconductor(Ge) has been also experimentally clarified.

  • Research Products

    (36 results)

All 2012 2011 2010 2009 2008 2007 Other

All Journal Article (15 results) (of which Peer Reviewed: 15 results) Presentation (19 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Counter Dipole Layer Formation in Multi-layer High-k Gate Stacks2012

    • Author(s)
      S. Hibino, T. Nishimura, K. Nagashio, K. Kita, and A. Toriumi
    • Journal Title

      Jpn. J. Appl. Phys

    • Peer Reviewed
  • [Journal Article] Higher-k Scalability and Leakage Current Reduction of SiO_2-Doped HfO_2 in Direct Tunneling Regime2011

    • Author(s)
      K. Tomida, K. Kita, and A. Toriumi
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 50 Pages: 111502

    • Peer Reviewed
  • [Journal Article] Opportunity for Phase-controlled Higher-k HfO_22011

    • Author(s)
      A. Toriumi, Y. Nakajima, and K. Kita
    • Journal Title

      ECS-Trans.

      Volume: 41(7) Pages: 125-136

    • Peer Reviewed
  • [Journal Article] Interfacial Dipole at High-k Dielectric/SiO_2 Interface : X-ray PhotoelectronSpectroscopy Characteristics2011

    • Author(s)
      L. Q. Zhu, K. Kita, T. Nishimura, K. Nagashio, S. K. Wang, and A. Torium
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 50 Pages: 031502

    • Peer Reviewed
  • [Journal Article] Observation of Dipole Layer Formed at High-k Dielectrics/SiO_2 Interface with X-ray Photoelectron Spectroscopy2010

    • Author(s)
      L. Q. Zhu, K. Kita, T. Nishimura, K. Nagashio, S. K. Wang, and A. Toriumi
    • Journal Title

      Appl. Phys. Exp.

      Volume: 3 Pages: 061501

    • Peer Reviewed
  • [Journal Article] Thermodynamic analysis of moistureabsorption phenomena in high-permittivity oxides as gate dielectrics of advanced complementary-metal-oxide-semiconductor devices2010

    • Author(s)
      Y. Zhao, K. Kita, and A. Toriumi
    • Journal Title

      Appl. Phys. Lett.

      Volume: 96 Pages: 242901

    • Peer Reviewed
  • [Journal Article] Thermodynamics and kinetics for suppression of GeO desorption by high pressure oxidation of Ge2009

    • Author(s)
      K. Nagashio, C. H. Lee, T. Nishimura, K. Kita, and A. Toriumi
    • Journal Title

      MRS Symp. Proc.

      Volume: 1155 Pages: 06-02

    • Peer Reviewed
  • [Journal Article] Dielectric and electrical properties of amorphous La_<1-x> Ta_xO_y films as higher-k gate insulators2009

    • Author(s)
      Y. Zhao, K. Kita, K. Kyuno, and A. Toriumi
    • Journal Title

      J. Appl. Phys.

      Volume: 105 Pages: 34103

    • Peer Reviewed
  • [Journal Article] Band gap enhancement and electrical properties of La_2O_3 films doped with Y_2O_3 as high-k gate insulators2009

    • Author(s)
      Y. Zhao, K. Kita, K. Kyuno, and A. Toriumi
    • Journal Title

      Appl. Phys. Lett.

      Volume: 94 Pages: 042901

    • Peer Reviewed
  • [Journal Article] Control of high-k/germanium interface properties through selection of high-k materials and suppression of GeO volatilization2008

    • Author(s)
      K. Kita, T. Takahashi, H. Nomura, S. Suzuki, T. Nishimura and A. Toriumi
    • Journal Title

      Appl. Surf. Sci.

      Volume: 254 Pages: 6100-6105

    • Peer Reviewed
  • [Journal Article] A Significant Shift of Schottky Barrier Heights at Strongly Pinned Metal/Germanium Interface by Inserting an Ultra-Thin Insulating Film2008

    • Author(s)
      T. Nishimura, K. Kita, and A. Toriumi
    • Journal Title

      Appl. Phys. Exp.

      Volume: 1 Pages: 51406-1-51406-3

    • Peer Reviewed
  • [Journal Article] Internal Photoemission over HfO_2 and Hf_<1-x> Si_xO_2 High-k Insulating Barriers : Band Offset and Interfacial Dipole Characterization2008

    • Author(s)
      J. Widiez, K. Kita, K. Tomida, T. Nishimura, and A. Toriumi
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 47 Pages: 2410-2414

    • Peer Reviewed
  • [Journal Article] Study of La-Induced Flat band Voltage Shift in Metal/HfLaO_x/SiO_2/Si Capacitors2007

    • Author(s)
      Y. Yamamoto, K. Kita, K. Kyuno and A. Toriumi
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 46(11) Pages: 7251-7255

    • Peer Reviewed
  • [Journal Article] Evidence for strong Fermi-level pinning due to metal-induced gap states at metal/germanium interface2007

    • Author(s)
      T. Nishimura, K. Kita, and A. Toriumi
    • Journal Title

      Appl. Phys. Lett.

      Volume: 91 Pages: 123123

    • Peer Reviewed
  • [Journal Article] Mechanisms of and Solutions to Moisture Absorption of Lanthanum Oxide as High k Gate Dielectric2007

    • Author(s)
      Y. Zhao, K. Kita, K. Kyuno and A. Toriumi
    • Journal Title

      ECS-Trans.

      Volume: 6(1) Pages: 141-148

    • Peer Reviewed
  • [Presentation] Counter Dipole Layer Formation in SiO_2/High-k/SiO_2/Si Gate Stacks2012

    • Author(s)
      S. Hibino, T. Nishimura, K. Nagashio, K. Kita and A. Toriumi
    • Organizer
      Silicon Nanoelectronics Workshop(2012)
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2012-06-10
  • [Presentation] Control of Ge/High-k Interface for Ge CMOS Technology(invited)2012

    • Author(s)
      K. Kita, S. K. Wang, T. Tabata, C. H. Lee, T. Nishimura, K. Nagashio and A. Toriumi
    • Organizer
      39th Conf. Physics and Chemistry of Surfaces and Interfaces,(PCSI-39)
    • Place of Presentation
      Santa Fe, USA
    • Year and Date
      2012-01-25
  • [Presentation] Material Potential and Scalability Challenges of Germanium CMOS2011

    • Author(s)
      A. Toriumi, C. H. Lee, S. K. Wang, T. Tabata, M. Yoshida, D. D. Zhao, T. Nishimura, K. Kita, and K. Nagashio
    • Organizer
      2011 IEEE International Electron Device Mtg.(IEDM2011)
    • Place of Presentation
      Washington DC, USA
    • Year and Date
      2011-12-07
  • [Presentation] Phase Transformation Kinetics of HfO_2 Polymorphs in Ultra-Thin Region2011

    • Author(s)
      Y. Nakajima, K. Kita, T. Nishimura, K. Nagashio, and A. Toriumi
    • Organizer
      2011 Symposia on VLSI Technology
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2011-06-15
  • [Presentation] Direct LaLuO3/Ge Gate Stack Formation by Interface Layer Scavenging and Subsequent Low Temperature O2 Annealing2010

    • Author(s)
      T. Tabata, C. H. Lee, K. Kita, and A. Toriumi
    • Organizer
      218th ECS Mtg.
    • Place of Presentation
      Las Vegas, USA
    • Year and Date
      2010-10-13
  • [Presentation] Formation of Dipole Layers at Oxide Interfaces in High-k Gate Stacks2010

    • Author(s)
      K. Kita, L. Q. Zhu, T. Nishimura, K. Nagashio, and A. Toriumi
    • Organizer
      218th ECS Mtg.
    • Place of Presentation
      Las Vegas, USA
    • Year and Date
      2010-10-12
  • [Presentation] Experimental Demonstration of Higher-k Phase HfO2 through non-equilibrium Thermal Treatment2010

    • Author(s)
      Y. Nakajima, K. Kita, T. Nishimura, K. Nagashio, and A. Toriumi
    • Organizer
      217th ECS Mtg.
    • Place of Presentation
      Vancouver, Canada
    • Year and Date
      2010-04-27
  • [Presentation] Anomalous VFB Shift in High-k Gate Stacks-Is its origin at the top or bottom interface?2009

    • Author(s)
      A. Toriumi and T. Nabatame
    • Organizer
      216th ECS Mtg.
    • Place of Presentation
      Vienna, Austria
    • Year and Date
      2009-10-05
  • [Presentation] On the Origin of Anomalous VTH Shift in high-k MOSFETs2009

    • Author(s)
      A. Toriumi and K. Kita
    • Organizer
      215th ECS Mtg.
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2009-05-27
  • [Presentation] Intrinsic Origin of Electric Dipoles Formed at High-k/SiO_2 Interface2008

    • Author(s)
      K. Kita and A. Toriumi
    • Organizer
      2010 IEEE International Electron Device Mtg.(IEDM)
    • Place of Presentation
      San Diego, USA
    • Year and Date
      2008-12-15
  • [Presentation] Application of Advanced Atomic Layer Deposition for Understanding and Control of VTH and EOT in Metal/High-k Gate Stacks2008

    • Author(s)
      A. Toriumi, T. Nabatame and H. Ota
    • Organizer
      Pacific Rim Mtg. on Electrochemical and Solid-State Science
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2008-10-14
  • [Presentation] Phase Controlled HfO_2 for Higher-k Dielectrics2008

    • Author(s)
      A. Toriumi, K. Kita, S. Migita and Y. Watanabe
    • Organizer
      Higher-k Workshop
    • Place of Presentation
      Stanford Univ., USA
    • Year and Date
      2008-08-22
  • [Presentation] Materials Science-based Device Performance Engineering for Metal Gate High-k CMOS2007

    • Author(s)
      A. Toriumi, K. Kita, K. Tomida, Y. Zhao, J. Widiez, T. Nabatame, H. Ota and M. Hirose
    • Organizer
      2007 International Electron Device Mtg.(IEDM)
    • Place of Presentation
      Washington DC, USA
    • Year and Date
      2007-12-12
  • [Presentation] A Significant Shift of Strongly Pinned Charge Neutrality Level at Metal/Germanium Interface by Inserting Ultra-thin Oxides2007

    • Author(s)
      T. Nishimura, K. Kita, A. Toriumi
    • Organizer
      38th IEEE Semiconductor Interface Specialists Conference(SISC2007)
    • Place of Presentation
      Arlington, USA
    • Year and Date
      2007-12-10
  • [Presentation] Current Status and Perspective of High-k Gate Stack Materials Engineering for Further Scaled CMOS2007

    • Author(s)
      A. Toriumi
    • Organizer
      212th ECS Mtg.
    • Place of Presentation
      Washington DC, USA
    • Year and Date
      2007-10-10
  • [Presentation] High-k dielectric films for advanced microelectronics2007

    • Author(s)
      A. Toriumi
    • Organizer
      International Conf.<Micro-and Nanoelectronics 2007>
    • Place of Presentation
      Washington DC, USA
    • Year and Date
      2007-10-02
  • [Presentation] High-k dielectric films for advanced microelectronics2007

    • Author(s)
      A. Toriumi
    • Organizer
      International Conf.<Micro-and Nanoelectronics 2007>
    • Place of Presentation
      Moscow, Russia
    • Year and Date
      2007-10-02
  • [Presentation] High-k Dielectrics and Metals on Germanium2007

    • Author(s)
      A. Toriumi, K. Kita and T. Nishimura
    • Organizer
      International Workshop on High-k Dielectrics on High Electron Mobility Channel Materials
    • Place of Presentation
      Taiwan
    • Year and Date
      2007-05-25
  • [Presentation] Ternary High-k Dielectrics for Advanced CMOS2007

    • Author(s)
      A. Toriumi and K. Kita
    • Organizer
      International Workshop on High-k Dielectrics on High Electron Mobility Channel Materials
    • Place of Presentation
      Taiwan
    • Year and Date
      2007-05-25
  • [Book] Chap. 11 :"Interface Properties of High-k Dielectrics on Germanium Advanced Gate Stacks for High-Mobility Semiconductors2007

    • Author(s)
      A. Toriumi, K. Kita, M. Toyama and H. Nomura
    • Total Pages
      257-267
    • Publisher
      Springer
  • [Remarks]

    • URL

      http://www.adam.t.u-tokyo.ac.jp/top.html

URL: 

Published: 2013-07-31  

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