• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

2010 Fiscal Year Final Research Report

Unraveling the structure of water-bearing mantle minerals by multi-nuclear and multi-dimensional NMR spectroscopy

Research Project

  • PDF
Project/Area Number 19204053
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Petrology/Mineralogy/Science of ore deposit
Research InstitutionOkayama University

Principal Investigator

XUE Xianyu  Okayama University, 地球物質科学研究センター, 准教授 (70362986)

Co-Investigator(Kenkyū-buntansha) KANZAKI Masami  岡山大学, 地球物質科学研究センター, 教授 (90234153)
ITO Eiji  岡山大学, 地球物質科学研究センター, 名誉教授 (00033259)
Project Period (FY) 2007 – 2010
Keywords地球惑星物質 / 鉱物構造 / 核磁気共鳴法 / 高圧 / 水 / 欠陥
Research Abstract

In this research program, we have unraveled the detailed structure (water content and speciation, cation order/disorder, defect, etc) for a number of important water-bearing mantle minerals and related compounds using advanced multi-nuclear and multi-dimensional NMR spectroscopy. We have also discovered several new high-pressure phases and have determined their crystal structures. Such information is indispensible for understanding the physical properties of minerals at the earth's interior and for modeling the dynamics and evolution of the earth.

  • Research Products

    (35 results)

All 2011 2010 2009 2008 2007 Other

All Journal Article (14 results) (of which Peer Reviewed: 14 results) Presentation (20 results) Remarks (1 results)

  • [Journal Article] Structures of two new high-pressure forms of AlPO_4 by X-ray powder diffraction and NMR spectroscopy.2011

    • Author(s)
      Kanzaki, M., Xue, X., Reibstein, S., Berryman, E., Namgung, S.
    • Journal Title

      Acta Crystallographica B 67

      Pages: 30-40

    • Peer Reviewed
  • [Journal Article] The nature of hydroxyl groups in aluminosilicate glasses : quantifying Si-OH and Al-OH abundances along the SiO_2-NaAlSiO_4 join by ^1H, ^<27>Al-^1H and ^<29>Si-^1H NMR spectroscopy.2010

    • Author(s)
      Malfait, W.J., Xue, X.
    • Journal Title

      Geochimica et Cosmochimica Acta 74

      Pages: 719-737

    • Peer Reviewed
  • [Journal Article] The partial ^1H NMR spectra of Al-OH and molecular H_2O in hydrous aluminosilicate glasses : Component-Resolved analysis of ^<27>Al-^1H cross polarization and ^1H spin-echo MAS NMR spectra.2010

    • Author(s)
      Malfait, W.J., Xue, X.
    • Journal Title

      Solid State Nuclear Magnetic Resonance 37

      Pages: 60-68

    • Peer Reviewed
  • [Journal Article] Determination of J coupling constants between spin-1/2 and quadrupolar nuclei in inorganic solids from spin echo and refocused INEPT experiments : A case study on AlPO_4 berlinite.2010

    • Author(s)
      薛献宇
    • Journal Title

      Solid State Nuclear Magnetic Resonance 38

      Pages: 62-73

    • Peer Reviewed
  • [Journal Article] Unique crystal chemistry of two polymorphs of topaz-OH : a multi-nuclear NMR and Raman study.2010

    • Author(s)
      Xue, X., Kanzaki, M., Fukui, H.
    • Journal Title

      American Mineralogist 95

      Pages: 1276-1293

    • Peer Reviewed
  • [Journal Article] Crystal structure of a new high-pressure polymorph of topaz-OH.2010

    • Author(s)
      神崎正美
    • Journal Title

      American Mineralogist 95

      Pages: 1349-1352

    • Peer Reviewed
  • [Journal Article] Proton distributions and hydrogen bonding in crystalline and glassy hydrous silicates and related inorganic materials : insights from high-resolution solid-state NMR spectroscopy.2009

    • Author(s)
      薛献宇, 神崎正美
    • Journal Title

      Journal of the American Ceramic Society 92

      Pages: 2803-2830

    • Peer Reviewed
  • [Journal Article] Si-Al distribution in high-pressure CaAl_4Si_2O_<11> phase : a ^<29>Si and ^<27>Al NMR study.2009

    • Author(s)
      Xue, X., Zhai, S., Kanzaki, M.
    • Journal Title

      American Mineralogist 94

      Pages: 1739-1742

    • Peer Reviewed
  • [Journal Article] Water speciation in hydrous silicate and aluminosilicate glasses : Direct evidence from ^<29>Si-^1H and ^<27>Al-^1H double-resonance NMR.2009

    • Author(s)
      薛献宇
    • Journal Title

      American Mineralogist 94(2-3)

      Pages: 395-398

    • Peer Reviewed
  • [Journal Article] 多核種・多次元固体NMR分光法の魅力-含水高圧鉱物・含水アルミノケイ酸塩ガラスを例に-2008

    • Author(s)
      薛献宇、神崎正美
    • Journal Title

      地球化学 42

      Pages: 133-155

    • Peer Reviewed
  • [Journal Article] Dense hydrous magnesium silicates, phase D and superhydrous B : New structural constraints from one- and two- dimensional ^<29>Si and ^1H NMR.2008

    • Author(s)
      Xue, X., Kanzaki, M., Shatskiy, A.
    • Journal Title

      American Mineralogist 93

      Pages: 1099-1111

    • Peer Reviewed
  • [Journal Article] Structure of hydrous aluminosilicate glasses along the diopside - anorthite join : a comprehensive one- and two- dimensional ^1H and ^<27>Al NMR2008

    • Author(s)
      薛献宇, 神崎正美
    • Journal Title

      study Geochimica et Cosmochimica Acta 72(9)

      Pages: 2331-2348

    • Peer Reviewed
  • [Journal Article] High-pressure δ-Al(OH)_3 and δ-AlOOH phases and isostructural hydroxides/oxyhydroxides : New structural insights from high-resolution ^1H and ^<27>Al NMR.2007

    • Author(s)
      薛献宇, 神崎正美
    • Journal Title

      Journal of Physical Chemistry B 111

      Pages: 13156-13166

    • Peer Reviewed
  • [Journal Article] Al coordination and water speciation in hydrous aluminosilicate glasses : direct evidence from high-resolution heteronuclear ^1H-^<27>Al correlation NMR.2007

    • Author(s)
      薛献宇, 神崎正美
    • Journal Title

      Solid State Nuclear Magnetic Resonance 31

      Pages: 10-27

    • Peer Reviewed
  • [Presentation] Topaz-OHの相転移と結晶化学的特徴日本鉱物科学会2010

    • Author(s)
      薛献宇・神崎正美
    • Organizer
      2010年度年会
    • Place of Presentation
      島根大学(松江)
    • Year and Date
      2010-09-23
  • [Presentation] Water speciation in hydrous (alumino)silicate melts/glasses and quasi-chemical modeling, Goldschmist Conf. 20102010

    • Author(s)
      X.Xue, M.Kanzaki, W.Malfait
    • Organizer
      Knoxville Convention Center
    • Place of Presentation
      Knoxville, Tennessee(米国)
    • Year and Date
      2010-06-15
  • [Presentation] AlPO_4の相関係と高圧相の結晶構造2010

    • Author(s)
      神崎正美・薛献宇
    • Organizer
      日本地球惑星科学連合2010年大会
    • Place of Presentation
      幕張メッセ国際会議場(千葉)
    • Year and Date
      2010-05-23
  • [Presentation] 新しいAlPO_4高圧相における高分解能NMRと粉末X線回折による構造決定及び^<31>P-^<27>Alと^<31>P-^<31>P間のJ結合を用いたNMRピークの帰属2010

    • Author(s)
      薛献宇・神崎正美
    • Organizer
      第47回固体NMR・材料フォーラム
    • Place of Presentation
      (株)神戸製鋼所 神戸総合技術研究所(神戸)
    • Year and Date
      2010-05-10
  • [Presentation] 含水ケイ酸塩メルト・ガラスにおける含水種の分布と準化学モデリング2009

    • Author(s)
      薛献宇
    • Organizer
      日本鉱物科学会2009年度年会
    • Place of Presentation
      北海道大学(札幌)
    • Year and Date
      2009-09-10
  • [Presentation] NMRと粉末X線回折法によるAlPO_4高圧相の構造解析2009

    • Author(s)
      神崎正美・薛献宇
    • Organizer
      日本鉱物科学会2009年度年会
    • Place of Presentation
      北海道大学(札幌)
    • Year and Date
      2009-09-10
  • [Presentation] (逆検知)^<27>Al→^1H及び^1H→^<29>Si→^1H CPMAS NMR法による含水ケイ酸塩・アルミノ珪酸塩ガラス中の含水種の解明2008

    • Author(s)
      薛献宇
    • Organizer
      第44回/9回固体NMR・材料フォーラム
    • Place of Presentation
      三井化学(千葉県袖ヶ浦市)
    • Year and Date
      2008-10-31
  • [Presentation] Structures of high-pressure hydrous minerals : Insights from one- and two dimensional NMR spectroscopy2008

    • Author(s)
      薛献宇,神崎正美
    • Organizer
      4^<th> Asian Conference on High Pressure Research(招待講演)
    • Place of Presentation
      ソウル国立大学、ソウル(韓国)
    • Year and Date
      2008-10-15
  • [Presentation] phase Dの水素結合について:ラマン分光法による研究2008

    • Author(s)
      神崎正美・薛献宇
    • Organizer
      日本地球惑星科学連合2008年大会
    • Place of Presentation
      幕張メッセ国際会議場(千葉)
    • Year and Date
      2008-05-25
  • [Presentation] Structures of high-pressure hydrous minerals and aluminosilicate melts (glasses) : Insights from one- and two dimensional NMR spectroscopy2008

    • Author(s)
      薛献宇
    • Organizer
      第3回COE21三朝国際シンポジウム
    • Place of Presentation
      三朝町総合文化ホール(鳥取県三朝町)
    • Year and Date
      2008-03-21
  • [Presentation] 高圧含水鉱物中の水素とSi-Mg-Al分布の秩序性:高度なNMR分光法による情報2007

    • Author(s)
      薛献宇・神崎正美
    • Organizer
      第48回高圧討論会
    • Place of Presentation
      倉吉未来中心(鳥取県倉吉市)
    • Year and Date
      2007-11-20
  • [Presentation] 1・2次元高分解能^1Hと^<27>Al NMRによる各種低圧・高圧オキシ水酸化物・水酸化物相の構造解明2007

    • Author(s)
      薛献宇・神崎正美
    • Organizer
      第42回/7回固体NMR・材料フォーラム
    • Place of Presentation
      京都平安会館(京都)
    • Year and Date
      2007-11-06
  • [Presentation] 高圧含水マグネシウムケイ酸塩D相及びsuperhydrous B相の構造:1・2次元^1H、^<29>Si NMRによる情報2007

    • Author(s)
      薛献宇
    • Organizer
      日本鉱物学会2007年度年会
    • Place of Presentation
      東京大学(東京)
    • Year and Date
      2007-09-23
  • [Presentation] 多核種・多次元固体NMR分光法の鉱物・メルトへの応用2007

    • Author(s)
      薛献宇
    • Organizer
      日本地球化学会2007年度年会(招待講演)
    • Place of Presentation
      岡山大学(岡山)
    • Year and Date
      2007-09-21
  • [Presentation] 高圧delta-Al(OH)_3とdelta-AlOOH相及び同一構造型In(OH)_3とInOOH相中の水素:高分解能^1H CRAMPS NMRとRaman分光法からの情報2007

    • Author(s)
      薛献宇・神崎正美
    • Organizer
      日本セラミックス協会第20回秋季シンポジウム
    • Place of Presentation
      名古屋工業大学(名古屋)
    • Year and Date
      2007-09-12
  • [Presentation] Structure of hydrous silicate and aluminosilicate melts (glasses) : Insights from one- and two-dimensional ^1H and ^<27>Al NMR2007

    • Author(s)
      薛献宇, 神崎正美
    • Organizer
      Frontiers in Mineral Sciences
    • Place of Presentation
      Cambridge大学、Cambridge (英国)
    • Year and Date
      2007-06-27
  • [Presentation] Proton distributions in high-pressure hydrous phases in the Al_2O_3-SiO_2-H_2O system : New insights from high-resolution ^1H NMR spectroscopy2007

    • Author(s)
      X.Xue, M.Kanzaki, H.Fukui, E.Ito
    • Organizer
      Frontiers in Mineral Sciences
    • Place of Presentation
      Cambridge大学,Cambridge (英国)
    • Year and Date
      2007-06-26
  • [Presentation] 高圧高温その場X線回折実験によるtopaz-OHの相関係2007

    • Author(s)
      神崎正美
    • Organizer
      日本地球惑星科学連合2007年大会
    • Place of Presentation
      幕張メッセ国際会議場(千葉)
    • Year and Date
      2007-05-20
  • [Presentation] 含水アルミノ珪酸塩メルト(ガラス)の構造:高度な1・2次元^1H及び^<27>Alによる情報2007

    • Author(s)
      薛献宇・神崎正美
    • Organizer
      日本地球惑星科学連合2007年大会
    • Place of Presentation
      幕張メッセ国際会議場(千葉)
    • Year and Date
      2007-05-20
  • [Presentation] 金属と水の水熱反応を使った酸素同位体濃縮酸化物の合成2007

    • Author(s)
      神崎正美
    • Organizer
      日本地球惑星科学連合2007年大会
    • Place of Presentation
      幕張メッセ国際会議場(千葉)
    • Year and Date
      2007-05-20
  • [Remarks] ホームページ等

    • URL

      http://www.misasa.okayama-u.ac.jp/~xianyu/xianyu_j.shtml

URL: 

Published: 2012-01-26   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi